Insight into the reaction mechanisms for oxidative addition of strong σ bonds to an Al(i) center

2016 ◽  
Vol 45 (25) ◽  
pp. 10355-10365 ◽  
Author(s):  
Xiangfei Zhang ◽  
Zexing Cao
Keyword(s):  
Reaction Mechanisms ◽  
Oxidative Addition ◽  
Oxidative Additions ◽  
Insight Into

The oxidative additions of σ X–H bonds to an Al(i) center follow different mechanisms depending on their bonding features and local structural environments.

scholarly journals Oxidative additions of alkynyl/vinyl iodides to gold and gold-catalyzed vinylation reactions triggered by the MeDalphos Ligand

2021 ◽  
Author(s):  
Jessica Rodriguez ◽  
Alexis Tabey ◽  
Sonia Ladeira ◽  
Didier Bourissou
Keyword(s):  
Oxidative Addition ◽  
Oxidative Additions ◽  
Vinyl Iodides

The hemilabile Ad2P(o-C6H4)NMe2 ligand promotes fast, quantitative and irreversible oxidative addition of alkynyl and vinyl iodides to gold. The reaction is general. It works with a broad range of substrates...

The emerging molecular structure of the nitrogen cycle: an introduction to the proceedings of the 10th annual N-cycle meeting

2005 ◽  
Vol 33 (1) ◽  
pp. 113-118 ◽  
Author(s):  
C.S. Butler ◽  
D.J. Richardson
Keyword(s):  
Structural Biology ◽  
Nitrogen Cycle ◽  
Reaction Mechanisms ◽  
Spectroscopic Analysis ◽  
Three Dimensional ◽  
Chemical Transformations ◽  
Redox Active ◽  
Active Metal ◽  
Insight Into ◽  
Redox Active Metal

Over the last 10 years, during the lifetime of the nitrogen cycle meetings, structural biology, coupled with spectroscopy, has had a major impact of our understanding enzymology of the nitrogen cycle. The three-dimensional structures for many of the key enzymes have now been resolved and have provided a wealth of information regarding the architecture of redox active metal sites, as well as revealing novel structural folds. Coupled with structure-based spectroscopic analysis, this has led to new insight into the reaction mechanisms of the diverse chemical transformations that together cycle nitrogen in the biosphere. An overview of the some of the key developments in field over the last decade is presented.

scholarly journals Arenium cation or radical cation? An insight into the cyclodehydrogenation reaction of 2-substituted binaphthyls mediated by Lewis acids

RSC Advances ◽  
2020 ◽  
Vol 10 (37) ◽  
pp. 21974-21985
Author(s):  
Patricia Camargo Solórzano ◽  
María T. Baumgartner ◽  
Marcelo Puiatti ◽  
Liliana B. Jimenez
Keyword(s):  
Radical Cation ◽  
Lewis Acid ◽  
Reaction Mechanisms ◽  
Lewis Acids ◽  
Acid Synthesis ◽  
Theoretical Studies ◽  
Insight Into

Cyclodehydrogenation reactions of 2-substituted binaphthyls induced by a Lewis acid. Synthesis and theoretical studies of the reaction mechanisms.

scholarly journals A theoretical insight into the reaction mechanisms of a 2,4,6-trinitrotoluene nitroso metabolite with thiols for toxic effects

2019 ◽  
Vol 8 (2) ◽  
pp. 270-276 ◽  
Author(s):  
Yang Zhou ◽  
Xiaoqiang Liu ◽  
Weidong Jiang ◽  
Yuanjie Shu ◽  
Guojun Xu
Keyword(s):  
Environmental Protection ◽  
Environmental Protection Agency ◽  
Reaction Mechanisms ◽  
Toxic Effects ◽  
Protection Agency ◽  
Class C ◽  
Theoretical Insight ◽  
Insight Into

2,4,6-Trinitrotoluene (TNT) is a class C carcinogen as rated by the Environmental Protection Agency.

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