Reaction of stannylene phosphorus Lewis pairs with dichlorides of germanium, tin and lead – the formation of base stabilized stannyl stannylenes/germylenes and redox reaction with PbCl2

2016 ◽  
Vol 45 (19) ◽  
pp. 8081-8088 ◽  
Author(s):  
K. M. Krebs ◽  
J.-J. Maudrich ◽  
L. Wesemann
Keyword(s):  
Redox Reaction ◽  
Group 14 ◽  
Germanium Tin ◽  
Lewis Pairs

The reaction of intramolecular stannylene phosphorus Lewis pairs with heavier dichlorides of group 14 (GeCl2, SnCl2, PbCl2) is reported.

Diverse Activation Modes in the Hydroboration of Aldehydes and Ketones with Germanium, Tin, and Lead Lewis Pairs

2016 ◽  
Vol 56 (1) ◽  
pp. 333-337 ◽  
Author(s):  
Julia Schneider ◽  
Christian P. Sindlinger ◽  
Sarah M. Freitag ◽  
Hartmut Schubert ◽  
Lars Wesemann
Keyword(s):  
Germanium Tin ◽  
Aldehydes And Ketones ◽  
Lewis Pairs
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