scholarly journals Tandem dissolution of UO3 in amide-based acidic ionic liquid and in situ electrodeposition of UO2 with regeneration of the ionic liquid: a closed cycle

2016 ◽  
Vol 45 (25) ◽  
pp. 10151-10154 ◽  
Author(s):  
Eranda Wanigasekara ◽  
John W. Freiderich ◽  
Xiao-Guang Sun ◽  
Roberta A. Meisner ◽  
Huimin Luo ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Closed Cycle ◽  
Acidic Ionic Liquid

A closed cycle is demonstrated for the tandem dissolution and electroreduction of UO3 to UO2 with regeneration of the acidic ionic liquid.

scholarly journals Corrigendum: Functionalization of Carbon Materials by Reduction of Diazonium Cations Produced In Situ in a Brønsted Acidic Ionic Liquid

2020 ◽  
Vol 7 (21) ◽  
pp. 4440-4440
Author(s):  
Janine Carvalho Padilha ◽  
Jean‐Marc Noël ◽  
Jean‐Franҫois Bergamini ◽  
Joёlle Rault‐Berthelot ◽  
Corinne Lagrost
Keyword(s):  
Ionic Liquid ◽  
Carbon Materials ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid

scholarly journals Efficient Hydrolysis of Polysaccharides in Bagasse by in Situ Synthesis of an Acidic Ionic Liquid after Pretreatment

2016 ◽  
Vol 5 (1) ◽  
pp. 708-713 ◽  
Author(s):  
Heri Satria ◽  
Kosuke Kuroda ◽  
Takatsugu Endo ◽  
Kenji Takada ◽  
Kazuaki Ninomiya ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
In Situ Synthesis ◽  
Acidic Ionic Liquid ◽  
Hydrolysis Of

Functionalization of Carbon Materials by Reduction of Diazonium Cations Produced in Situ in a Brønstedt Acidic Ionic Liquid

2016 ◽  
Vol 3 (4) ◽  
pp. 572-580 ◽  
Author(s):  
Janine Carvalho Padilha ◽  
Jean-Marc Noël ◽  
Jean-François Bergamini ◽  
Joëlle Rault-Berthelot ◽  
Corinne Lagrost
Keyword(s):  
Ionic Liquid ◽  
Carbon Materials ◽  
Acidic Ionic Liquid

1, 1’-Sulfinyldiethylammonium Bis (Hydrogen Sulfate) as a Recyclable Dicationic Ionic Liquid Catalyst for the Efficient Solvent-free Synthesis of 3, 4-Dihydropyrimidin-2(1H)-ones via Biginelli Reaction

2020 ◽  
Vol 23 (2) ◽  
pp. 157-167
Author(s):  
Zainab Ehsani-Nasab ◽  
Ali Ezabadi
Keyword(s):  
Ionic Liquid ◽  
Biginelli Reaction ◽  
Aromatic Aldehydes ◽  
Solvent Free ◽  
Hydrogen Sulfate ◽  
One Pot ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid ◽  
Solvent Free Conditions ◽  
Dicationic Ionic Liquid

Objective: A facile and efficient method for synthesis of 3, 4-dihydropyrimidin-2(1H)-ones via Biginelli reaction catalyzed by a novel dicationic Brönsted acidic ionic liquid, [(EtNH2)2SO][HSO4]2, has been successfully developed. Material and Method:: 3, 4-Dihydropyrimidin-2(1H)-ones were synthesized through one-pot condensation of aromatic aldehydes, ethyl acetoacetate, and urea under solvent-free conditions using [(EtNH2)2SO][HSO4]2 as a novel catalyst. The progress of the reaction was monitored by thin-layer chromatography (ethyl acetate / n-hexane = 1 / 5). The products have been characterized by IR, 1H NMR, 13C NMR, and also by their melting points. Results: In this research, a library of dihydropyrimidinone derivatives was synthesized via Biginelli reaction under solvent-free conditions at 120oC using [(EtNH2)2SO][HSO4]2 as a catalyst. Various aromatic aldehydes, as well as heteroaromatic aldehydes, were employed, affording good to high yields of the corresponding products and illustrating the substrate generality of the present method. In addition, the prepared dicationic Brönsted acidic ionic liquid can be easily recovered and reused. Conclusion: 1, 1’-Sulfinyldiethylammonium bis (hydrogen sulfate), as a novel dicationic ionic liquid, can act as a highly efficient catalyst for the synthesis of 3, 4-dihydropyrimidin-2(1H)-ones under solvent-free conditions.

Synthesis and Characterization of a Novel Ionic Liquid Based on N,N,N,N-tetramethylethylenediamine and its Application in the Synthesis of 1,8-dioxo-octahydro Xanthenes

2018 ◽  
Vol 21 (7) ◽  
pp. 526-532 ◽  
Author(s):  
Zahra Abdi Piralghar ◽  
Mohammad Mahmoodi Hashemi ◽  
Ali Ezabadi
Keyword(s):  
Ionic Liquid ◽  
Chlorosulfonic Acid ◽  
Solvent Free ◽  
Aryl Aldehydes ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid ◽  
Solvent Free Conditions ◽  
Aryl Aldehyde ◽  
High Yields

Aim and Objective: In this work, we synthesized and characterized a novel Brönsted acidic ionic liquid from the reaction of N, N, N’, N’-tetramethylethylenediamine with chlorosulfonic acid and explored its catalytic activity in 1, 8-dioxo-octahydroxanthenes synthesis. Materials and Methods: Dimedone, aryl aldehydes, and the ionic liquid as the catalyst were reacted under solvent-free conditions. The progressive of the reaction was monitored by a thin layer of chromatography (ethyl acetate/n-hexane = 1/5). All products were characterized as the basis of their spectra data and melting point by comparison with those reported in the literature. Results: The prepared ionic liquid was successfully applied in the synthesis of 1, 8-dioxooctahydroxanthenes in good to high yields on the reaction of aryl aldehyde and dimedone at 120oC under solvent-free conditions. Conclusion: This research demonstrates that the catalyst is impressive for 1, 8-dioxo-octahydroxanthenes synthesis under solvent-free conditions.

scholarly journals Improved biorefinery pathways of marine diatoms using a water miscible ionic liquid and its colloidal solution: efficient lipid extraction and in situ synthesis of fluorescent carbon dots for bio-imaging applications

RSC Advances ◽  
2021 ◽  
Vol 11 (35) ◽  
pp. 21207-21215
Author(s):  
Paidi Murali Krishna ◽  
Veerababu Polisetti ◽  
Krishnaiah Damarla ◽  
Subir Kumar Mandal ◽  
Arvind Kumar
Keyword(s):  
Ionic Liquid ◽  
Colloidal Solution ◽  
Polar Solvent ◽  
Lipid Extraction ◽  
In Situ Synthesis ◽  
Marine Diatoms ◽  
Bio Imaging ◽  
Partition Method ◽  
Fluorescent Carbon Dots

In this study, a water-miscible ionic liquid (IL), 1-ethyl-3-methylimidazoliumacetate ([EMIM][Ac]), has been used for lipid extraction from marine diatoms Thalassiosira lundiana CSIR-CSMCRI 001 by following a non-polar solvent partition method.

Ionic liquid‐based in situ product removal ( ISPR ) design exemplified for an ABE fermentation

2021 ◽  
Author(s):  
Yuqiu Chen ◽  
Nipun Garg ◽  
Hao Luo ◽  
Georgios M. Kontogeorgis ◽  
John M. Woodley
Keyword(s):  
Ionic Liquid ◽  
Abe Fermentation ◽  
In Situ Product Removal ◽  
Product Removal
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