scholarly journals Synthesis and characterization of mixed ligand chiral nanoclusters

2016 ◽  
Vol 45 (28) ◽  
pp. 11297-11300 ◽  
Author(s):  
Zekiye P. Guven ◽  
Burcin Ustbas ◽  
Kellen M. Harkness ◽  
Hikmet Coskun ◽  
Chakra P. Joshi ◽  
...  

Chiral mixed ligand silver nanoclusters were synthesized in the presence of a chiral and an achiral ligand. While the chiral ligand led mostly to the formation of nanoparticles, the presence of the achiral ligand drastically increased the yield of nanoclusters with enhanced chiral properties.

Langmuir ◽  
2012 ◽  
Vol 28 (24) ◽  
pp. 8915-8919 ◽  
Author(s):  
Sherry Huang ◽  
Christian Pfeiffer ◽  
Jana Hollmann ◽  
Sebastian Friede ◽  
Justin Jin-Ching Chen ◽  
...  

2014 ◽  
Vol 7 (4) ◽  
pp. 24-29
Author(s):  
Mahesh K. Singh ◽  
◽  
Ranajoy Laskar ◽  
Sanjit Sutradhar ◽  
Bijaya Paul ◽  
...  

2004 ◽  
Vol 59 (5) ◽  
pp. 554-558 ◽  
Author(s):  
Amar Srivastava ◽  
A.K. Shrimal ◽  
Amar Nath

Abstract Reactions of five sym-diarylthioureas (L), viz,, sym-diphenylthiourea (dptu), sym-di-o-tolylthiourea (dottu), sym-di-p-tolylthiourea (dpttu), sym-di-o-anisylthiourea (doatu) and sym-di-α- naphthylthiourea (dαntu) with W(CO)6 have been performed both by reflux and ultra-violet irradiation methods in which only monosubstituted products [(L)W(CO)5] are obtained. Several mixed ligand tungsten carbonyl derivatives, viz., [(o-phen or 2,2’-bipy)(L)W(CO)3] and [(Ph3P or Ph3As)(L)W(CO)4] have also been synthesized. Halogenation of [(L)W(CO)5] yielded heptacoordinated [(L)W(CO)4X2] (X = Br or I). The complexes have been characterized by microanalytical data, conductivity and IR measurements. The C-O stretching force constants and CO-CO stretch-stretch interaction constants of [(L)W(CO)5] derivatives have also been evaluated from the IR spectra.


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