Linear coordination polymers based on aluminum phosphates: synthesis, crystal structure and morphology

2016 ◽  
Vol 45 (19) ◽  
pp. 8008-8020 ◽  
Author(s):  
M. Dębowski ◽  
K. Łokaj ◽  
A. Wolak ◽  
K. Żurawski ◽  
A. Plichta ◽  
...  

The synthesis and properties of coordination polymers with the formula Al[O2P(OR)2]3[R = Me, Et,nPr,iPr,nBu, CH2CH(Et)(CH2)3CH3or Ph] are reported.

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Runmei Ding ◽  
Zixin He ◽  
Meilin Wang ◽  
Danian Tian ◽  
Peipei Cen

AbstractBased on 2-(4-pyridyl)-terephthalate (H2pta) and oxalate ligands, two new lanthanide-containing coordination polymers (CPs), [Tb(pta)(C2O4)0.5(H2O)2)]·2H2O (1) and [Sm(pta)(C2O4)0.5(H2O)2)]·2H2O (2), have been synthesized under solvothermal conditions. The structures of both 1 and 2 have been determined by single-crystal X-ray diffraction. Infrared, elemental analysis, powder X-ray diffraction and thermogravimetric analysis data are also presented. The crystals of 1 and 2 exhibit isostructural layer-like networks, crystallizing in the triclinic space group P$‾{1}$. The layers are further stabilized and associated into 3D architectures through hydrogen bonding. Remarkably, the CPs 1 and 2 exhibit excellent water stability and remarkable thermostability with thermal decomposition temperatures of more than 420 °C.


Polyhedron ◽  
2015 ◽  
Vol 91 ◽  
pp. 52-58 ◽  
Author(s):  
Sa-Sa Shen ◽  
Xiaofang Wang ◽  
Huai-Ming Hu ◽  
Fei Yuan ◽  
Fa-Xin Dong ◽  
...  

2004 ◽  
Vol 16 (14) ◽  
pp. 1173-1177 ◽  
Author(s):  
D. Shah ◽  
P. Maiti ◽  
E. Gunn ◽  
D. F. Schmidt ◽  
D. D. Jiang ◽  
...  

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