scholarly journals U(v) in metal uranates: a combined experimental and theoretical study of MgUO4, CrUO4, and FeUO4

2016 ◽  
Vol 45 (11) ◽  
pp. 4622-4632 ◽  
Author(s):  
Xiaofeng Guo ◽  
Eitan Tiferet ◽  
Liang Qi ◽  
Jonathan M. Solomon ◽  
Antonio Lanzirotti ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Solid State ◽  
Theoretical Study ◽  
Pentavalent Uranium

Although pentavalent uranium can exist in aqueous solution, its presence in the solid state is uncommon.

Separation of phenylenediamine isomers by using decamethylcucurbit[5]uril

2021 ◽  
Author(s):  
Long Cao ◽  
Han-Ling Guo ◽  
Rui Lian Lin ◽  
Li-Fei Tian ◽  
Zhi-Hua Zhang ◽  
...  
Keyword(s):  
Experimental Data ◽  
Aqueous Solution ◽  
Solid State ◽  
Phenylenediamine Isomers

Using multiple techniques, this work studied the binding behaviors of decamethylcucurbit[5]uril (Me10Q[5]) with o-, m- and p-phenylenediamine (PDA) isomers both in solid state and in aqueous solution. Experimental data indicate...

scholarly journals Electrochemiluminescence Study of Europium (III) Complex with Coumarin3-Carboxylic Acid

2008 ◽  
Vol 2008 ◽  
pp. 1-6 ◽  
Author(s):  
Stefan Lis ◽  
Krzysztof Staninski ◽  
Tomasz Grzyb
Keyword(s):  
Aqueous Solution ◽  
Spectral Analysis ◽  
Energy Transfer ◽  
Solid State ◽  
Carboxylic Acid ◽  
Elemental Analysis ◽  
Aluminium Electrode ◽  
The Eu

The europium (III) complex of coumarin-3-carboxylic acid (C3CA) has been prepared and characterized on the basis of elemental analysis, IR, and emission (photoluminescence and electrochemiluminescence) spectroscopy. The synthesised complex having a formula Eu was photophysically characterized in solution and in the solid state. Electrochemiluminescence, ECL, of the system containing the Eu(III)/C3CA complex was studied using an oxide-covered aluminium electrode. The goal of these studies was to show the possibility of the use of electrochemical excitation of the Eu(III) ion in aqueous solution for emission generation. The generated ECL emission was very weak, and therefore its measurements and spectral analysis were carried out with the use of cut-off filters method. The studies proved a predominate role of the ligand-to-metal energy transfer (LMET) in the generated ECL.

Enhanced adsorption removal of methyl orange from aqueous solution by nanostructured proton-containing δ-MnO2

2015 ◽  
Vol 3 (10) ◽  
pp. 5674-5682 ◽  
Author(s):  
Yan Liu ◽  
Chao Luo ◽  
Jian Sun ◽  
Haizhen Li ◽  
Zebin Sun ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Methyl Orange ◽  
Solid State ◽  
Solid State Reaction ◽  
Proton Exchange ◽  
Precipitation Method ◽  
Homogeneous Precipitation ◽  
Adsorption Removal ◽  
Homogeneous Precipitation Method ◽  
Enhanced Adsorption

Two nanostructured proton-containing δ-MnO2 (H-δ-MnO2) materials were synthesized through proton exchange for K-containing δ-MnO2 (K-δ-MnO2) nanosheets and nanoparticles prepared by the hydrothermal homogeneous precipitation method and solid-state reaction.

Mechanistic studies on the decomposition of sodium cyanide in aqueous solution and in the solid state

2005 ◽  
Vol 153 (2-3) ◽  
pp. 125-131 ◽  
Author(s):  
Hiroshi Nishioka ◽  
Mayumi Nishikawa ◽  
Munehiro Katagi ◽  
Hitoshi Tsuchihashi ◽  
Osamu Muraoka
Keyword(s):  
Aqueous Solution ◽  
Solid State ◽  
Sodium Cyanide ◽  
Mechanistic Studies

A fluorescence study on the complexation of Sm(iii), Eu(iii) and Tb(iii) with tetraalkyldiglycolamides (TRDGA) in aqueous solution, in solid state, and in solvent extraction

2016 ◽  
Vol 45 (46) ◽  
pp. 18484-18493 ◽  
Author(s):  
Fei Kou ◽  
Suliang Yang ◽  
Hongjuan Qian ◽  
Lihua Zhang ◽  
Christine M. Beavers ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Solid State ◽  
Solvent Extraction ◽  
Lanthanide Ions ◽  
Tridentate Ligand ◽  
Fluorescence Study ◽  
Trivalent Lanthanide

Trivalent lanthanide ions form 1 : 1, 1 : 2, and 1 : 3 complexes with tridentate ligand TMDGA in 1 M H/NaNO3 and form 1 : 3 extracted complexes with DMDODGA during solvent extraction.

Encapsulation of haloalkane 1-(3-chlorophenyl)-4-(3-chloropropyl)-piperazinium in symmetrical α,α′,δ,δ′-tetramethyl-cucurbit[6]uril

2015 ◽  
Vol 17 (14) ◽  
pp. 8618-8621 ◽  
Author(s):  
Xin Xiao ◽  
Zhong-Zheng Gao ◽  
Cheng-Long Shan ◽  
Zhu Tao ◽  
Qian-Jiang Zhu ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Solid State

The haloalkane guest PZ+was encapsulated into the host TMeQ[6] both in aqueous solution and solid state, presenting the first example of haloalkanes encapsulated inside the cavities of Q[n]s.

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