Enzyme and photoredox sequential catalysis for the synthesis of 1,3-oxazine derivatives in one pot

2017 ◽  
Vol 7 (9) ◽  
pp. 1937-1942 ◽  
Author(s):  
Guo-Yan Zhang ◽  
Yang Xiang ◽  
Zhi Guan ◽  
Yan-Hong He

A novel strategy combining visible-light and enzyme catalysis for the synthesis of 1,3-oxazine derivatives is described for the first time.

2015 ◽  
Vol 17 (35) ◽  
pp. 22977-22984 ◽  
Author(s):  
Yawen Liu ◽  
Qianli Ma ◽  
Xiangting Dong ◽  
Wensheng Yu ◽  
Jinxian Wang ◽  
...  

Novel photoluminescent–electrical–magnetic trifunctional flexible Eu(BA)3phen/PANI/Fe3O4/PVP hollow nanofibers were constructed using a one-pot coaxial electrospinning process for the first time.


2021 ◽  
Author(s):  
Tianai Tang ◽  
Kai Tu ◽  
Xiang Xu ◽  
Jian Xie ◽  
Duo Zhang ◽  
...  

A novel strategy for preparing micron-size Janus particles with easily-functionalized surfaces was established by one-pot W/O/W-type suspension polymerization for the first time.


Crystals ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 401 ◽  
Author(s):  
Yuxiang Lu ◽  
Yazhou Qin ◽  
Dongdong Yu ◽  
Jianguang Zhou

In this work, we have synthesized hexapods AgCl crystals with mace pods for the first time. Diallyldimethylammonium chloride (DDA)-controlled stepwise evolution of AgCl crystals from octahedron to hexapods with mace pods are achieved by one-pot method. The intermediates have been captured which show the basic process of crystal growth. In this process, octahedra AgCl crystals firstly grow along the <100> direction and then change to grow in the <110> direction. At the same time, the size of AgCl grow from 2 μm to 20 μm. Due to the poor absorption of visible light by AgCl, sodium borohydride(NaBH4) is used to reduce AgCl hexapods with mace pods crystals. By changing the mole ratio(R) of NaBH4 to AgCl, the new structure was reduced to obtain a series of Ag@AgCl microstructures. Visible light catalysis effects of the Ag@AgCl microstructures on degradation of methyl orange (MO) were investigated. The Ag@AgCl microstructures with R = 0.02 have a high photocatalytic performance, which completely degrades MO in 40 minutes.


2020 ◽  
Vol 23 (23) ◽  
pp. 2626-2634
Author(s):  
Saiedeh Kamalifar ◽  
Hamzeh Kiyani

: An efficient and facial one-pot synthesis of 4-aryl-3,4-dihydrobenzo[g]quinoline- 2,5,10(1H)-triones was developed for the first time. The process proceeded via the three-component cyclocondensation of 2-amino-1,4-naphthoquinone with Meldrum’s acid and substituted benzaldehydes under green conditions. The fused 3,4-dihydropyridin-2(1H)- one-ring naphthoquinones have been synthesized with good to high yields in refluxing ethanol as a green reaction medium. This protocol is simple and effective as well as does not involve the assistance of the catalyst, additive, or hazardous solvents.


Sensors ◽  
2021 ◽  
Vol 21 (3) ◽  
pp. 920
Author(s):  
Neha Chaudhary ◽  
Othman Isam Younus ◽  
Luis Nero Alves ◽  
Zabih Ghassemlooy ◽  
Stanislav Zvanovec ◽  
...  

The accuracy of the received signal strength-based visible light positioning (VLP) system in indoor applications is constrained by the tilt angles of transmitters (Txs) and receivers as well as multipath reflections. In this paper, for the first time, we show that tilting the Tx can be beneficial in VLP systems considering both line of sight (LoS) and non-line of sight transmission paths. With the Txs oriented towards the center of the receiving plane (i.e., the pointing center F), the received power level is maximized due to the LoS components on F. We also show that the proposed scheme offers a significant accuracy improvement of up to ~66% compared with a typical non-tilted Tx VLP at a dedicated location within a room using a low complex linear least square algorithm with polynomial regression. The effect of tilting the Tx on the lighting uniformity is also investigated and results proved that the uniformity achieved complies with the European Standard EN 12464-1. Furthermore, we show that the accuracy of VLP can be further enhanced with a minimum positioning error of 8 mm by changing the height of F.


RSC Advances ◽  
2021 ◽  
Vol 11 (34) ◽  
pp. 21097-21103
Author(s):  
Mikhail Yu. Belikov ◽  
Mikhail Yu. Ievlev

The temperature effect on the thermal stability of both the initial and photoinduced forms of nitrile-rich T-type photochromes was studied for the first time.


2020 ◽  
pp. 104607
Author(s):  
Zeng-Jie Yang ◽  
Qing-Tian Gong ◽  
Yuan Yu ◽  
Wei-Fan Lu ◽  
Zhe-Ning Wu ◽  
...  

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