Hydrogenation/oxidation triggered highly efficient reversible color switching of organic molecules

2017 ◽  
Vol 7 (6) ◽  
pp. 1379-1385 ◽  
Author(s):  
Xiao Zhou ◽  
Yi-Fan Jiang ◽  
Hong-Li Guo ◽  
Xin Wang ◽  
Ya-Nan Liu ◽  
...  

The reversible hydrogenation/oxidative dehydrogenation process of TH+/LTH over a highly active Pd–ZnO1−x hybrid catalyst under ambient conditions.

2017 ◽  
Vol 53 (4) ◽  
pp. 705-708 ◽  
Author(s):  
Zi-Cheng Fu ◽  
Yong Xu ◽  
Sharon Lai-Fung Chan ◽  
Wei-Wei Wang ◽  
Fang Li ◽  
...  

An anion-assisted hydrolytic H2-releasing ultra-high performance system involving ammonia borane and a CoP nanoparticle catalyst has been established under ambient conditions.


Nanomaterials ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 929 ◽  
Author(s):  
Sajjad Hussain ◽  
Kamran Akbar ◽  
Dhanasekaran Vikraman ◽  
Rana Afzal ◽  
Wooseok Song ◽  
...  

To find an effective alternative to scarce, high-cost noble platinum (Pt) electrocatalyst for hydrogen evolution reaction (HER), researchers are pursuing inexpensive and highly efficient materials as an electrocatalyst for large scale practical application. Layered transition metal dichalcogenides (TMDCs) are promising candidates for durable HER catalysts due to their cost-effective, highly active edges and Earth-abundant elements to replace Pt electrocatalysts. Herein, we design an active, stable earth-abundant TMDCs based catalyst, WS(1−x)Sex nanoparticles-decorated onto a 3D porous graphene/Ni foam. The WS(1−x)Sex/graphene/NF catalyst exhibits fast hydrogen evolution kinetics with a moderate overpotential of ~−93 mV to drive a current density of 10 mA cm−2, a small Tafel slope of ~51 mV dec−1, and a long cycling lifespan more than 20 h in 0.5 M sulfuric acid, which is much better than WS2/NF and WS2/graphene/NF catalysts. Our outcomes enabled a way to utilize the TMDCs decorated graphene and precious-metal-free electrocatalyst as mechanically robust and electrically conductive catalyst materials.


Author(s):  
Yafeng Chen ◽  
Guimin Jiang ◽  
Xiangzhi Cui ◽  
Zuotai Zhang ◽  
Xinmei Hou

The highly active Pd/CeO2 nanocube interface guarantees a high percentage of metallic Pd and the surface active O species is responsible for the complete decomposition of formaldehyde.


Author(s):  
Monika Srivastava ◽  
Karan Surana ◽  
Shruti Singh ◽  
P.K. Singh ◽  
Ram Chandra Singh

2020 ◽  
Vol 9 (1) ◽  
Author(s):  
Sangeun Cho ◽  
Sungwoo Kim ◽  
Jongmin Kim ◽  
Yongcheol Jo ◽  
Ilhwan Ryu ◽  
...  

Abstract Compared with solid scintillators, liquid scintillators have limited capability in dosimetry and radiography due to their relatively low light yields. Here, we report a new generation of highly efficient and low-cost liquid scintillators constructed by surface hybridisation of colloidal metal halide perovskite CsPbA3 (A: Cl, Br, I) nanocrystals (NCs) with organic molecules (2,5-diphenyloxazole). The hybrid liquid scintillators, compared to state-of-the-art CsI and Gd2O2S, demonstrate markedly highly competitive radioluminescence quantum yields under X-ray irradiation typically employed in diagnosis and treatment. Experimental and theoretical analyses suggest that the enhanced quantum yield is associated with X-ray photon-induced charge transfer from the organic molecules to the NCs. High-resolution X-ray imaging is demonstrated using a hybrid CsPbBr3 NC-based liquid scintillator. The novel X-ray scintillation mechanism in our hybrid scintillators could be extended to enhance the quantum yield of various types of scintillators, enabling low-dose radiation detection in various fields, including fundamental science and imaging.


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