Electrocatalytic hydrogenation of pyridinium enabled by surface proton transfer reactions

2017 ◽  
Vol 7 (4) ◽  
pp. 831-837 ◽  
Author(s):  
C. X. Kronawitter ◽  
Z. Chen ◽  
P. Zhao ◽  
X. Yang ◽  
B. E. Koel
Keyword(s):  
Carbon Dioxide ◽  
Proton Transfer ◽  
Formic Acid ◽  
Selective Reduction ◽  
Transfer Reactions ◽  
Electrocatalytic Hydrogenation ◽  
Pt Electrodes ◽  
Proton Transfer Reactions ◽  
First Time

It is observed for the first time that pyridinium is hydrogenated at Pt electrodes in electrochemical conditions consistent with those previously shown to yield selective reduction of carbon dioxide to methanol and formic acid.

Proton Transfer Reactions between Methanol and Formic Acid Deposited on Free ArN Nanoparticles

2019 ◽  
Vol 123 (33) ◽  
pp. 7201-7209 ◽  
Author(s):  
Andriy Pysanenko ◽  
Francisco Gámez ◽  
Karolína Fárníková ◽  
Eva Pluhařová ◽  
Michal Fárník
Keyword(s):  
Proton Transfer ◽  
Formic Acid ◽  
Transfer Reactions ◽  
Proton Transfer Reactions

Concertedness and solvent effects in multiple proton transfer reactions: The formic acid dimer in solution

2000 ◽  
Vol 112 (21) ◽  
pp. 9498-9508 ◽  
Author(s):  
J. Kohanoff ◽  
S. Koval ◽  
D. A. Estrin ◽  
D. Laria ◽  
Y. Abashkin
Keyword(s):  
Proton Transfer ◽  
Formic Acid ◽  
Solvent Effects ◽  
Transfer Reactions ◽  
Proton Transfer Reactions

Ion-molecule reactions of formic acid. I. Proton-transfer reactions

1978 ◽  
Vol 31 (10) ◽  
pp. 2157 ◽  
Author(s):  
CG Freeman ◽  
PW Harland ◽  
MJ McEwan
Keyword(s):  
Proton Transfer ◽  
Formic Acid ◽  
General Equation ◽  
Reasonable Agreement ◽  
Transfer Reactions ◽  
Rate Coefficients ◽  
Collision Rate ◽  
Dipole Orientation ◽  
Ion Molecule Reactions ◽  
Proton Transfer Reactions

Rate coefficients are reported for a number of proton-transfer reactions with formic acid. These reactions can be represented by the general equation �������������������������� XH++HCOOH → (HCOOH)H+ +X : (X = CH4, H2O, N2, CO, HCN, HCHO, CH3OH and H2S). Reasonable agreement was obtained between our observed results and predictions based on the average-dipole-orientation (ADO) model except that ADO theory may slightly underestimate the collision rate.

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