Catalytic hydrogenation and one step hydrogenation-esterification to remove acetic acid for bio-oil upgrading: model reaction study

2016 ◽  
Vol 6 (21) ◽  
pp. 7783-7792 ◽  
Author(s):  
Minghao Zhou ◽  
Peng Liu ◽  
Kui Wang ◽  
Junming Xu ◽  
Jianchun Jiang
Keyword(s):  
Acetic Acid ◽  
Catalytic Activity ◽  
Catalytic Hydrogenation ◽  
Model Reaction ◽  
Reaction Study ◽  
Bio Oil ◽  
One Step

NiMo/CNT catalysts exhibited satisfactory catalytic activity for the conversion of acetic acid by either hydrogenation or hydrogenation-esterification with acetaldehyde.

scholarly journals Acid-Alkaline Treatment of Mordenite and Its Catalytic Activity in the Hydrotreatment of Bio-Oil

2020 ◽  
Vol 21 (1) ◽  
pp. 37
Author(s):  
Febi Yusniyanti ◽  
Wega Trisunaryanti ◽  
Triyono Triyono
Keyword(s):  
Acetic Acid ◽  
Catalytic Activity ◽  
Surface Area ◽  
Acid Treatment ◽  
Room Temperature ◽  
Alkaline Treatment ◽  
Bet Analysis ◽  
Bio Oil ◽  
Acetic Acid Treatment ◽  
Xrd Patterns

Acid-alkaline treatment using acetic acid and sodium hydroxide (NaOH) were applied on mordenite (MOR) to increase the Si/Al ratio and surface area properties. Various time treatment (3, 6, and 9 h) and concentration of acetic acid (6, 9, and 12 M) were used to treat MOR, and followed by the treatment with NaOH (0.1 M) under room temperature. The MOR and treated mordenite were applied as a catalyst for hydrotreatment of cellulose-derived bio-oil. The acetic acid treatment caused the increase of the Si/Al ratio of mordenite up to 27.03. The Si/Al ratio was determined using ICP-AES analysis which was also confirmed using FT-IR analysis. The acidity was determined using NH3 vapors adsorption. The acidity test revealed that as the Si/Al ratio increased the acidity of mordenite decreased. The advantage of using acetic acid for acid treatment was that the XRD patterns of mordenite can be preserved with a little decrease of the intensity. On the other hand, the NaOH treatment under room temperature decreased the crystallinity down to 68%, which was calculated using XRD. The acid-alkaline treatment of mordenite succeeded to increase the surface area 2 times larger than the parent mordenite. The surface area was obtained from BET analysis. The acid-alkaline treated mordenite exhibited better catalytic activity upon hydrotreatment of biomass-derived bio-oil compared to the parent mordenite which corresponded to its highest surface area.

One-step hydrogenation–esterification of furfural and acetic acid over bifunctional Pd catalysts for bio-oil upgrading

2011 ◽  
Vol 102 (17) ◽  
pp. 8241-8246 ◽  
Author(s):  
Wanjin Yu ◽  
Yang Tang ◽  
Liuye Mo ◽  
Ping Chen ◽  
Hui Lou ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Pd Catalysts ◽  
Bio Oil ◽  
One Step

scholarly journals Hydrotreating of Guaiacol and Acetic Acid Blends over Ni2P/ZSM-5 Catalysts: Elucidating Molecular Interactions during Bio-Oil Upgrading

ACS Omega ◽  
2019 ◽  
Vol 4 (25) ◽  
pp. 21516-21528 ◽  
Author(s):  
Santiago Gutiérrez-Rubio ◽  
Inés Moreno ◽  
David P. Serrano ◽  
Juan M. Coronado
Keyword(s):  
Acetic Acid ◽  
Molecular Interactions ◽  
Bio Oil

Catalytic activity of CuGHK peptide-based porous material

2021 ◽  
Author(s):  
Francisco G. Cirujano ◽  
Nuria Martin ◽  
Neyvis Almora-Barrios ◽  
Carlos Martí-Gastaldo
Keyword(s):  
Catalytic Activity ◽  
Porous Material ◽  
Active Sites ◽  
Room Temperature ◽  
Side Chain ◽  
Periodic Distribution ◽  
Lysine Side Chain ◽  
One Step

Room temperature one-step synthesis of the peptide-based porous material with a periodic distribution of pockets decorated with lysine side chain active sites behaves as a heterogeneous organocatalyst. The pockets are...

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