High yield production of HMF from carbohydrates over silica–alumina composite catalysts

2016 ◽  
Vol 6 (20) ◽  
pp. 7586-7596 ◽  
Author(s):  
Xiangcheng Li ◽  
Qineng Xia ◽  
Van Chuc Nguyen ◽  
Kaihao Peng ◽  
Xiaohui Liu ◽  
...  

Mesoporous AlSiO catalysts have been prepared by a facile sol–gel method with tunable acidity for highly efficient production of HMF.

2005 ◽  
Vol 235 (1-2) ◽  
pp. 194-199 ◽  
Author(s):  
Wendong Wang ◽  
Philippe Serp ◽  
Philippe Kalck ◽  
Joaquim Luís Faria

2006 ◽  
Vol 510-511 ◽  
pp. 66-69 ◽  
Author(s):  
Yan Fang Chen ◽  
Yun Soo Lim

Carbon nanotubes (CNTs) in a high yield were synthesized by the decomposition of the methane gas with CCVD, in which two different reaction routes of sol-gel method prepared Fe-Mo- Mg-O catalyst. The two different routs influenced the wall number and defects of CNTs and the formation of CNTs. The concentration of Mo in the catalyst played a very important role in the yield of CNTs.


Catalysts ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 71
Author(s):  
Yuxin Chen ◽  
Dan Dang ◽  
Binhang Yan ◽  
Yi Cheng

Composite catalysts of mixed metal oxides were prepared by mixing a phase-pure M1 MoVNbTeOx with anatase-phase TiO2. Two methods were used to prepare the composite catalysts (the simple physically mixed or sol-gel method) for the improvement of the catalytic performance in the oxidative dehydrogenation of ethane (ODHE) process. The results showed that TiO2 particles with a smaller particle size were well dispersed on the M1 surface for the sol-gel method, which presented an excellent activity for ODHE. At the same operating condition (i.e., the contact time of 7.55 gcat·h/molC2H6 and the reaction temperature of 400 °C), the M1-TiO2-SM and M1-TiO2-PM achieved the space time yields of 0.67 and 0.52 kgC2H4/kgcat/h, respectively, which were about ~76% and ~35% more than that of M1 catalyst (0.38 kgC2H4/kgcat/h), respectively. The BET, ICP, XRD, TEM, SEM, H2-TPR, C2H6-TPSR, and XPS techniques were applied to characterize the catalysts. It was noted that the introduction of TiO2 raised the V5+ abundance on the catalyst surface as well as the reactivity of active oxygen species, which made contribution to the promotion of the catalytic performance. The surface morphology and crystal structure of used catalysts of either M1-TiO2-SM or M1-TiO2-PM remained stable as each fresh catalyst after 24 h time-on-stream tests.


2008 ◽  
Vol 587-588 ◽  
pp. 849-853 ◽  
Author(s):  
Cláudia G. Silva ◽  
Wen Dong Wang ◽  
Joaquim L. Faria

Carbon nanotube-TiO2 composites and pure TiO2 are prepared by a modified sol-gel method. The nanoscaled materials obtained are extensively characterized by spectroscopic, microscopic and calorimetric techniques. Their photoactivity is tested in the degradation of phenol under visible illumination. A correlation between the CNT content and the changes in the UV–vis absorption properties was found. The effect induced by CNT on the composite catalysts is explained in terms of an interphase interaction between CNT and TiO2 in the composite catalysts.


RSC Advances ◽  
2016 ◽  
Vol 6 (63) ◽  
pp. 58813-58822 ◽  
Author(s):  
K. A. Manjumol ◽  
S. Sankar ◽  
Balagopal N. Nair ◽  
M. Midhun ◽  
Peer A. Mohamed ◽  
...  

Anatase rich titanium dioxide ultrafiltration membranes with high filtration rates have been successfully developed on multi-channel tubular alumina substrates via aqueous sol–gel method from titania–alumina composite precursors.


2006 ◽  
Vol 352 (32-35) ◽  
pp. 3697-3704 ◽  
Author(s):  
G. Gonçalves ◽  
M.K. Lenzi ◽  
O.A.A. Santos ◽  
L.M.M. Jorge

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