Solubility product difference-guided synthesis of Co3O4–CeO2 core–shell catalysts for CO oxidation

2016 ◽  
Vol 6 (19) ◽  
pp. 7273-7279 ◽  
Author(s):  
Guozhu Chen ◽  
Qihui Xu ◽  
Yong Wang ◽  
Guolong Song ◽  
Cuncheng Li ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Ion Exchange ◽  
Co Oxidation ◽  
Solubility Product ◽  
Core Shell ◽  
Calcination Step ◽  
Product Difference

Co3O4–CeO2 core–shell catalysts are successfully fabricated by an ion exchange procedure between Co(CO3)0.35Cl0.2(OH)1.1 nanorods and Ce3+ aqueous solution, followed by a calcination step.

Removal of Toxic Dyestuffs from Aqueous Solution by Amphoteric Bioadsorbent

2020 ◽  
Vol 16 ◽  
Author(s):  
Reda M. El-Shishtawy ◽  
Abdullah M. Asiri ◽  
Nahed S. E. Ahmed
Keyword(s):  
Aqueous Solution ◽  
Ion Exchange ◽  
Dye Removal ◽  
Exchange Process ◽  
Cationic Dyes ◽  
Carboxyl Groups ◽  
Maximum Adsorption Capacity ◽  
Equilibrium Isotherm ◽  
Ion Exchange Process ◽  
Dyes And Pigments

Background: Color effluents generated from the production industry of dyes and pigments and their use in different applications such as textile, paper, leather tanning, and food industries, are high in color and contaminants that damage the aquatic life. It is estimated that about 105 of various commercial dyes and pigments amounted to 7×105 tons are produced annually worldwide. Ultimately, about 10–15% is wasted into the effluents of the textile industry. Chitin is abundant in nature, and it is a linear biopolymer containing acetamido and hydroxyl groups amenable to render it atmospheric by introducing amino and carboxyl groups, hence able to remove different classes of toxic organic dyes from colored effluents. Methods: Chitin was chemically modified to render it amphoteric via the introduction of carboxyl and amino groups. The amphoteric chitin has been fully characterized by FTIR, TGA-DTG, elemental analysis, SEM, and point of zero charge. Adsorption optimization for both anionic and cationic dyes was made by batch adsorption method, and the conditions obtained were used for studying the kinetics and thermodynamics of adsorption. Results: The results of dye removal proved that the adsorbent was proven effective in removing both anionic and cationic dyes (Acid Red 1 and methylene blue (MB)), at their respective optimum pHs (2 for acid and 8 for cationic dye). The equilibrium isotherm at room temperature fitted the Freundlich model for MB, and the maximum adsorption capacity was 98.2 mg/g using 50 mg/l of MB, whereas the equilibrium isotherm fitted the Freundlich and Langmuir model for AR1 and the maximum adsorption capacity was 128.2 mg/g. Kinetic results indicate that the adsorption is a two-step diffusion process for both dyes as indicated by the values of the initial adsorption factor (Ri) and follows the pseudo-second-order kinetics. Also, thermodynamic calculations suggest that the adsorption of AR1 on the amphoteric chitin is an endothermic process from 294 to 303 K. The result indicated that the mechanism of adsorption is chemisorption via an ion-exchange process. Also, recycling of the adsorbent was easy, and its reuse for dye removal was effective. Conclusion: New amphoteric chitin has been successfully synthesized and characterized. This resin material, which contains amino and carboxyl groups, is novel as such chemical modification of chitin hasn’t been reported. The amphoteric chitin has proven effective in decolorizing aqueous solution from anionic and cationic dyes. The adsorption behavior of amphoteric chitin is believed to follow chemical adsorption with an ion-exchange process. The recycling process for few cycles indicated that the loaded adsorbent could be regenerated by simple treatment and retested for removing anionic and cationic dyes without any loss in the adsorbability. Therefore, the study introduces a new and easy approach for the development of amphoteric adsorbent for application in the removal of different dyes from aqueous solutions.

Controlled Synthesis of Sintering-Resistant Pd@CeO2 Core–Shell Nanotube Catalysts for CO Oxidation

2019 ◽  
Vol 58 (48) ◽  
pp. 21972-21982
Author(s):  
Jingrui Ye ◽  
Dang-guo Cheng ◽  
Fengqiu Chen ◽  
Xiaoli Zhan
Keyword(s):  
Co Oxidation ◽  
Core Shell ◽  
Controlled Synthesis

A facile room temperature chemical transformation approach for binder-free thin film formation of Ag2Te and lithiation/delithiation chemistry of the film

2016 ◽  
Vol 45 (43) ◽  
pp. 17312-17318 ◽  
Author(s):  
Eun-Kyung Kim ◽  
Dasom Park ◽  
Nabeen K. Shrestha ◽  
Jinho Chang ◽  
Cheol-Woo Yi ◽  
...  
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Aqueous Solution ◽  
Ion Exchange ◽  
Chemical Transformation ◽  
Room Temperature ◽  
Film Formation ◽  
Synthetic Method ◽  
Binder Free ◽  
Thin Film Formation

An aqueous solution based synthetic method for binder-free Ag2Te thin films using ion exchange induced chemical transformation of Ag/AgxO thin films.

Novel Fe3O4@lignosulfonate/phenolic core-shell microspheres for highly efficient removal of cationic dyes from aqueous solution

2019 ◽  
Vol 127 ◽  
pp. 110-118 ◽  
Author(s):  
Guanhua Wang ◽  
Qingjun Liu ◽  
Minmin Chang ◽  
Jinmyung Jang ◽  
Wenjie Sui ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Cationic Dyes ◽  
Core Shell ◽  
Efficient Removal ◽  
Highly Efficient

scholarly journals ADSORBATIVE SEPARATION OF DOXYCYCLINE FROM AQUEOUS SOLUTION WITH N,N-DIETHYL N-METHYL CHITOSAN, GUM AND POLYACRYLIC ACID BASED HYDROGELS

2021 ◽  
Vol 11 (07) ◽  
pp. 44-53
Author(s):  
Mirvari Hasanova Mirvari Hasanova
Keyword(s):  
Aqueous Solution ◽  
Ion Exchange ◽  
Zeta Potential ◽  
Polyacrylic Acid ◽  
Inorganic Materials ◽  
Biologically Active ◽  
Cross Linking ◽  
Separation And Purification ◽  
Inorganic Substances ◽  
The Cross

The separation and purification of antibiotics with sorption by ion-exchange materials, as well as their delivery in biological processes by immobilization, are now widely used in biotechnology. There are many scientific studies in the literature on the sorption of antibiotics by polymer-based sorbents and inorganic materials, as well as the study of thermodynamics and kinetics of the process. In the literature, the acquisition of biologically active systems from the sorption of antibiotics by ion-exchange fibers based on various polymers and inorganic substances was carried out. However, the synthesis of selective gels for the effective separation of doxycycline and its delivery in different pH mediums by sorption with biodegradable, biocompatible polysaccharide-containing composites is one of the topical issues. Gel was synthesized from the cross-linking of N,N-diethyl N-methyl derivative of a natural polyaminosaccharide of chitosan by glutaric aldehyde. Also, pH-sensitive hydrogels that can swollen in water were synthesized from the cross-linking of a graft copolymer of cherry source gummiarabic with N-vinylpyrrolidone, as well as synthetic polymer polyacrylic acid with N,N-methylene-bis-acrylamide. The structure of the gels were identified by FTIR and NMR spectroscopy, and the sorption of doxycycline antibiotic from an aqueous solution was investigated. According to the values of zeta potential, the protonation of functional groups in the main macromolecule in an acidic medium leads to a value of zeta potential of 40÷80 mV on the surface of chitosan-based gel and others. Although the chemical structure is different, the isoelectric point is set around pH=6÷8 for all three hydrogels. The dependences of the sorption process on the amount of gels, antibiotic concentration, temperature, and pH medium were studied. The experimental data were analyzed using two adsorption models, Langmuir and Freundlich, with the later system providing the best fit. Doxycycline is adsorbed on the surface of chitosan, gummiarabic and polyacrylic acid based hydrogel composite through by physical interactions. Also, the results of thermodynamic parameters ΔG40 kJ/mol show that the nature of the adsorption process is physical, and spontaneous, too. Keywords: Chitosan, Gummiarabic-arabinogalactane, polyacrylic acid, hydrogel, sorption isoterms, doxycycline, thermodynamica.

scholarly journals Movement of zinc sulphate in a calcium-saturated soil: cation exchange and precipitation of gypsum.

1987 ◽  
Vol 35 (3) ◽  
pp. 295-313
Author(s):  
K. Harmsen
Keyword(s):  
Ion Exchange ◽  
Transition Zone ◽  
Zinc Sulphate ◽  
Solubility Product ◽  
Mass Conservation ◽  
Saturated Soil ◽  
Adsorption Complex ◽  
Dimensional Model ◽  
One Dimensional ◽  
Leaching Solution

A one-dimensional model for the movement of zinc sulphate through calcium-saturated soil is presented. Processes considered include mass flow, ion exchange, precipitation and dissolution. Precipitation occurs when the solubility product of gypsum is exceeded. In the presence of gypsum, ion exchange takes place at two separate interfaces, which move with different velocities through the soil. At the first interface precipitation of gypsum takes place in conjunction with ion exchange, and at the second interface the gypsum dissolves again and ion exchange proceeds until equilibrium is reached with the leaching solution. The composition of the transition zone between the two interfaces is calculated from the conditions of mass conservation and electroneutrality, the solubility product of gypsum and assuming a linear ion exchange equation. It is shown that the concentration of sulphate in the transition zone is higher than in the leaching solution, due to dissolution of gypsum at the second interface. In the presence of gypsum, zinc penetrates deeper into the soil than in its absence, but the fraction of the adsorption complex saturated with zinc is smaller. (Abstract retrieved from CAB Abstracts by CABI’s permission)

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