Entrapment of a pyridine derivative within a copper–palladium alloy: a bifunctional catalyst for electrochemical reduction of CO2 to alcohols with excellent selectivity and reusability

2016 ◽  
Vol 6 (17) ◽  
pp. 6490-6494 ◽  
Author(s):  
Heng-Pan Yang ◽  
Sen Qin ◽  
Ying-Na Yue ◽  
Li Liu ◽  
Huan Wang ◽  
...  

A highly stable and recyclable catalyst, [PYD]@Cu–Pd, was demonstrated to have dual activity for electro-reduction of CO2 in aqueous solution.

2018 ◽  
Vol 86 (4) ◽  
pp. 121-128
Author(s):  
Junyu Liu ◽  
Yue Zhou ◽  
Luwei Peng ◽  
Jinli Qiao ◽  
Joey Jung

RSC Advances ◽  
2020 ◽  
Vol 10 (30) ◽  
pp. 17572-17581
Author(s):  
Nusrat Rashid ◽  
Mohsin Ahmad Bhat ◽  
U. K. Goutam ◽  
Pravin Popinand Ingole

Herein, we present fabrication of graphene oxide supported Cu/CuxO nano-electrodeposits which efficiently and selectively can electroreduce CO2 into ethylene with a faradaic efficiency of 34% and conversion rate of 194 mmol g−1 h−1 at −0.985 V vs. RHE.


2019 ◽  
Vol 21 (28) ◽  
pp. 15297-15301 ◽  
Author(s):  
Prastika Krisma Jiwanti ◽  
Yasuaki Einaga

Electrochemical reduction of CO2 produced CO on PdBDD electrode at potential −1.6 V (vs. Ag/AgCl) in NaCl aqueous solution.


2015 ◽  
Vol 17 (39) ◽  
pp. 26072-26078 ◽  
Author(s):  
Jun Tamura ◽  
Akihiko Ono ◽  
Yoshitsune Sugano ◽  
Chingchun Huang ◽  
Hideyuki Nishizawa ◽  
...  

The IL-based SAMs-modified Au electrodes have high selectivity of products from CO2 to ethylene glycol (a maximum of 87%).


2017 ◽  
Vol 9 (38) ◽  
pp. 32782-32789 ◽  
Author(s):  
Yuecheng Peng ◽  
Tian Wu ◽  
Libo Sun ◽  
Jean M. V. Nsanzimana ◽  
Adrian C. Fisher ◽  
...  

2019 ◽  
Author(s):  
Sahithi Ananthaneni ◽  
Rees Rankin

<div>Electrochemical reduction of CO2 to useful chemical and fuels in an energy efficient way is currently an expensive and inefficient process. Recently, low-cost transition metal-carbides (TMCs) are proven to exhibit similar electronic structure similarities to Platinum-Group-Metal (PGM) catalysts and hence can be good substitutes for some important reduction reactions. In this work, we test graphenesupported WC (Tungsten Carbide) nanocluster as an electrocatalyst for the CO2 reduction reaction. Specifically, we perform DFT studies to understand various possible reaction mechanisms and determine the lowest thermodynamic energy landscape of CO2 reduction to various products such as CO, HCOOH, CH3OH, and CH4. This in-depth study of reaction energetics could lead to improvements and develop more efficient electrocatalysts for CO2 reduction.<br></div>


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