Transition-metal-free B–B and B–interelement reactions with organic molecules

2017 ◽  
Vol 46 (2) ◽  
pp. 415-430 ◽  
Author(s):  
Ana B. Cuenca ◽  
Ryosuke Shishido ◽  
Hajime Ito ◽  
Elena Fernández
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Organic Molecules ◽  
Transition Metal Complex ◽  
Metal Free ◽  
Guided Tour

This review is a guided tour along the activation modes and reactivity of B–B, B–Si, B–N, B–S, B–Se and B–P reagents, in the absence of any transition metal complex.

Unsymmetrical 1,1-diborated multisubstituted sp3-carbons formed via a metal-free concerted-asynchronous mechanism

2015 ◽  
Vol 13 (37) ◽  
pp. 9659-9664 ◽  
Author(s):  
Ana B. Cuenca ◽  
Jessica Cid ◽  
Diego García-López ◽  
Jorge J. Carbó ◽  
Elena Fernández
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex ◽  
Diazo Compounds ◽  
Cyclic Ketones ◽  
Metal Free

We have experimentally proved and computationally rationalized the unsymmetrical 1,1-diboration of diazo compounds, formed in situ from aldehydes and cyclic and non-cyclic ketones, in the absence of any transition metal complex.

A transition metal complex containing pyrazine-2,5-dicarboxylato bridging ligands: a novel three-dimensional manganese(II) compound

2003 ◽  
Vol 6 (9) ◽  
pp. 1224-1227 ◽  
Author(s):  
Garikoitz Beobide ◽  
Oscar Castillo ◽  
Antonio Luque ◽  
Urko Garcı́a-Couceiro ◽  
Juan P. Garcı́a-Teran ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex ◽  
Three Dimensional ◽  
Bridging Ligands

Two large ionic crystals: Both their anions and cations constructed by Anderson-type POM-supported transition metal complex

2011 ◽  
Vol 14 (2) ◽  
pp. 384-388 ◽  
Author(s):  
Rui–Kang Tan ◽  
Shu–Xia Liu ◽  
Wei Zhang ◽  
Shu–Jun Li ◽  
Yuan–Yuan Zhang
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex ◽  
Ionic Crystals ◽  
Anions And Cations
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