Non-covalent π–π stacking interactions turn off non-adiabatic effects in proton-coupled electron transfer reactions

2017 ◽  
Vol 19 (10) ◽  
pp. 6969-6972 ◽  
Author(s):  
Leonardo Muñoz-Rugeles ◽  
Annia Galano ◽  
J. Raúl Alvarez-Idaboy
Keyword(s):  
Electron Transfer ◽  
Excited States ◽  
Transition States ◽  
Transfer Reactions ◽  
Stacking Interactions ◽  
Electron Transfer Reactions ◽  
Proton Coupled Electron Transfer ◽  
Π Stacking

Stacked transition states correspond to a PCET mechanism, albeit ground and first-excited states are separated by more than 20 kcal mol−1. The latter is usually attributed to HAT.

REACTIVITY OF EXCITED STATES OF FLAVIN AND 5-DEAZAFLAVIN IN ELECTRON TRANSFER REACTIONS

1981 ◽  
Vol 33 (1) ◽  
pp. 41-48 ◽  
Author(s):  
Rainer Traber ◽  
Ekehardt Vogelmann ◽  
Siegfried Schreiner ◽  
Tilmann Werner ◽  
Horst E. A. Kramer
Keyword(s):  
Electron Transfer ◽  
Excited States ◽  
Transfer Reactions ◽  
Electron Transfer Reactions

Excited states and electron transfer reactions of C60(OH)18in aqueous solution

1998 ◽  
Vol 94 (3) ◽  
pp. 359-363 ◽  
Author(s):  
Hari Mohan ◽  
D. K. Palit ◽  
Jai P. Mittal ◽  
L. Y. Chiang ◽  
Klaus-Dieter Asmus ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Electron Transfer ◽  
Excited States ◽  
Transfer Reactions ◽  
Electron Transfer Reactions

Effect of Pressure on Proton-Coupled Electron Transfer Reactions of Seven-Coordinate Iron Complexes in Aqueous Solutions

2005 ◽  
Vol 44 (21) ◽  
pp. 7624-7633 ◽  
Author(s):  
David Sarauli ◽  
Roland Meier ◽  
Gao-Feng Liu ◽  
Ivana Ivanović-Burmazović ◽  
Rudi van Eldik
Keyword(s):  
Electron Transfer ◽  
Aqueous Solutions ◽  
Iron Complexes ◽  
Transfer Reactions ◽  
Electron Transfer Reactions ◽  
Effect Of Pressure ◽  
Proton Coupled Electron Transfer

scholarly journals Concerted proton-electron transfer reactions in the Marcus inverted region

Science ◽  
2019 ◽  
Vol 364 (6439) ◽  
pp. 471-475 ◽  
Author(s):  
Giovanny A. Parada ◽  
Zachary K. Goldsmith ◽  
Scott Kolmar ◽  
Belinda Pettersson Rimgard ◽  
Brandon Q. Mercado ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Rate Constants ◽  
Charge Recombination ◽  
Transfer Reactions ◽  
Inverted Region ◽  
Electron Transfer Reactions ◽  
Proton Coupled Electron Transfer ◽  
Marcus Inverted Region ◽  
A Charge ◽  
Theory Yield

Electron transfer reactions slow down when they become very thermodynamically favorable, a counterintuitive interplay of kinetics and thermodynamics termed the inverted region in Marcus theory. Here we report inverted region behavior for proton-coupled electron transfer (PCET). Photochemical studies of anthracene-phenol-pyridine triads give rate constants for PCET charge recombination that are slower for the more thermodynamically favorable reactions. Photoexcitation forms an anthracene excited state that undergoes PCET to create a charge-separated state. The rate constants for return charge recombination show an inverted dependence on the driving force upon changing pyridine substituents and the solvent. Calculations using vibronically nonadiabatic PCET theory yield rate constants for simultaneous tunneling of the electron and proton that account for the results.

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