The role of π-linkers in tuning the optoelectronic properties of triphenylamine derivatives for solar cell applications – A DFT/TDDFT study

2017 ◽  
Vol 19 (8) ◽  
pp. 6153-6163 ◽  
Author(s):  
Murugesan Panneerselvam ◽  
Arunkumar Kathiravan ◽  
Rajadurai Vijay Solomon ◽  
Madhavan Jaccob
Author(s):  
Mailde S. Ozório ◽  
Malladi Srikanth ◽  
Rafael Besse ◽  
Juarez L. F. Da Silva

Tin-based ASnI3 perovskites have been considered an excellent candidate for lead-free perovskites solar cell applications, however, our atomistic understanding of the role of A-cations in the physical chemistry properties is...


2020 ◽  
Vol 92 (2) ◽  
pp. 20901
Author(s):  
Abdul Kuddus ◽  
Md. Ferdous Rahman ◽  
Jaker Hossain ◽  
Abu Bakar Md. Ismail

This article presents the role of Bi-layer anti-reflection coating (ARC) of TiO2/ZnO and back surface field (BSF) of V2O5 for improving the photovoltaic performance of Cadmium Sulfide (CdS) and Cadmium Telluride (CdTe) based heterojunction solar cells (HJSCs). The simulation was performed at different concentrations, thickness, defect densities of each active materials and working temperatures to optimize the most excellent structure and working conditions for achieving the highest cell performance using obtained optical and electrical parameters value from the experimental investigation on spin-coated CdS, CdTe, ZnO, TiO2 and V2O5 thin films deposited on the glass substrate. The simulation results reveal that the designed CdS/CdTe based heterojunction cell offers the highest efficiency, η of ∼25% with an enhanced open-circuit voltage, Voc of 0.811 V, short circuit current density, Jsc of 38.51 mA cm−2, fill factor, FF of 80% with bi-layer ARC and BSF. Moreover, it appears that the TiO2/ZnO bi-layer ARC, as well as ETL and V2O5 as BSF, could be highly promising materials of choice for CdS/CdTe based heterojunction solar cell.


Solar Energy ◽  
2019 ◽  
Vol 194 ◽  
pp. 716-723
Author(s):  
Alapan Dutta ◽  
Ranveer Singh ◽  
Sanjeev Kumar Srivastava ◽  
Tapobrata Som

2011 ◽  
Vol 116 (1) ◽  
pp. 727-737 ◽  
Author(s):  
Xiaogang Liu ◽  
Jacqueline M. Cole ◽  
Paul G. Waddell ◽  
Tze-Chia Lin ◽  
Jignesh Radia ◽  
...  

Solar Energy ◽  
2021 ◽  
Vol 225 ◽  
pp. 851-862
Author(s):  
Z. Hussein ◽  
A. Laref ◽  
H.R. Alqahtani ◽  
Eman.A. Alghamdi ◽  
Mohammed El Amine Monir ◽  
...  

2021 ◽  
Vol 10 (1) ◽  
Author(s):  
Ting-Xiao Qin ◽  
En-Ming You ◽  
Mao-Xin Zhang ◽  
Peng Zheng ◽  
Xiao-Feng Huang ◽  
...  

AbstractOrganic–inorganic halide perovskites are emerging materials for photovoltaic applications with certified power conversion efficiencies (PCEs) over 25%. Generally, the microstructures of the perovskite materials are critical to the performances of PCEs. However, the role of the nanometer-sized grain boundaries (GBs) that universally existing in polycrystalline perovskite films could be benign or detrimental to solar cell performance, still remains controversial. Thus, nanometer-resolved quantification of charge carrier distribution to elucidate the role of GBs is highly desirable. Here, we employ correlative infrared-spectroscopic nanoimaging by the scattering-type scanning near-field optical microscopy with 20 nm spatial resolution and Kelvin probe force microscopy to quantify the density of electrons accumulated at the GBs in perovskite polycrystalline thin films. It is found that the electron accumulations are enhanced at the GBs and the electron density is increased from 6 × 1019 cm−3 in the dark to 8 × 1019 cm−3 under 10 min illumination with 532 nm light. Our results reveal that the electron accumulations are enhanced at the GBs especially under light illumination, featuring downward band bending toward the GBs, which would assist in electron-hole separation and thus be benign to the solar cell performance.


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