scholarly journals Surface heterogeneity and inhomogeneous broadening of vibrational line profiles

2017 ◽  
Vol 19 (11) ◽  
pp. 7990-7995 ◽  
Author(s):  
Skandar Taj ◽  
Diane Baird ◽  
Alexander Rosu-Finsen ◽  
Martin R. S. McCoustra

The surface heterogeneity of amorphous silica (aSiO2) has been probed using coverage dependent temperature programmed desorption (TPD) of a simple probe molecule, carbon monoxide (CO), and is used to explain the inhomogeneous broadening of the CO stretching vibration in the infrared.

2019 ◽  
Vol 21 (38) ◽  
pp. 21663-21664
Author(s):  
Skandar Taj ◽  
Diane Baird ◽  
Alexander Rosu-Finsen ◽  
Martin R. S. McCoustra

Correction for ‘Surface heterogeneity and inhomogeneous broadening of vibrational line profiles’ by Skandar Taj et al., Phys. Chem. Chem. Phys., 2017, 19, 7990–7995.


2015 ◽  
Vol 5 (2) ◽  
pp. 738-742 ◽  
Author(s):  
Mausumi Mahapatra ◽  
Wilfred T. Tysoe

The chemistry of S-glycidol is studied on a Pd(111) surface using temperature-programmed desorption and reflection–absorption infrared spectroscopy to explore its suitability as a chiral probe molecule and to follow its reaction pathway.


2015 ◽  
Vol 17 (5) ◽  
pp. 3081-3114 ◽  
Author(s):  
Surajit Maity ◽  
Ralf I. Kaiser ◽  
Brant M. Jones

The radiation induced chemical processing of methanol and methanol–carbon monoxide ices at 5.5 K exposed to ionizing radiation in the form of energetic electrons and subsequent temperature programmed desorption is reported in this study.


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