Thermodynamic and molecular origin of interfacial rate enhancements and endo-selectivities of a Diels–Alder reaction

2017 ◽  
Vol 19 (6) ◽  
pp. 4297-4306 ◽  
Author(s):  
Vijay Beniwal ◽  
Anil Kumar
Keyword(s):  
Ionic Liquid ◽  
Alder Reaction ◽  
Diels Alder ◽  
Organic Reactions ◽  
Liquid Interfaces ◽  
Interfacial Conditions ◽  
Diels Alder Reaction ◽  
Molecular Origin

Organic reactions in general display large rate accelerations when performed under interfacial conditions, such as on water or at ionic liquid interfaces.

ChemInform Abstract: Chiral Ionic Liquid Mediated Diels-Alder Reaction Between Anthrone Enolate and Maleimides.

ChemInform ◽  
2010 ◽  
Vol 41 (40) ◽  
pp. no-no
Author(s):  
Nitin A. Mirgane ◽  
Mohammed Hasan H. Akhtar ◽  
Anil V. Karnik
Keyword(s):  
Ionic Liquid ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Chiral Ionic Liquid

Reactivity and Efficient Recycling of a Chiral Pd-BINAP Catalyst for Catalytic Asymmetric Diels-Alder Reaction in Ionic Liquid

Heterocycles ◽  
2009 ◽  
Vol 77 (2) ◽  
pp. 1323 ◽  
Author(s):  
Hiroto Nakano ◽  
Mitsuhiro Takeshita ◽  
Yasuhiro Nishiuchi ◽  
Yuta Araki ◽  
Reiko Fujita ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Catalytic Asymmetric

scholarly journals Ionic-Liquid-Mediated MacMillan’s Catalyst for Diels-Alder Reaction

2013 ◽  
Vol 2013 ◽  
pp. 1-5 ◽  
Author(s):  
Vivek Srivastava
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction

Ionic liquids were used to enhance as well as recycle the MacMillan's catalyst1for the Diels-Alder reaction. Using our developed protocol, Diels-Alder adducts were obtained in good yields and selectivities along the 6 times recycling of MacMillan's imidazolidinone catalyst1. Synthesis of steroid4is the major outcome of our developed protocol.

scholarly journals Efficient Organocatalyst Supported on a Simple Ionic Liquid as a Recoverable System for the Asymmetric Diels-Alder Reaction in the Presence of Water

ChemCatChem ◽  
2015 ◽  
Vol 7 (5) ◽  
pp. 830-835 ◽  
Author(s):  
Antonio De Nino ◽  
Loredana Maiuolo ◽  
Pedro Merino ◽  
Monica Nardi ◽  
Antonio Procopio ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction

scholarly journals Ionic liquid promoted Diels-Alder Reaction between anthrone and maleimides

2010 ◽  
Vol 8 (2) ◽  
pp. 356-360 ◽  
Author(s):  
Nitin Mirgane ◽  
Sandip Kotwal ◽  
Anil Karnik
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Room Temperature ◽  
Alder Reaction ◽  
Dual Role ◽  
Diels Alder ◽  
Environmentally Benign ◽  
Green Solvents ◽  
Imidazolium Ionic Liquid ◽  
Diels Alder Reaction

AbstractIonic liquids (IL) are gaining importance as green solvents. Imidazolium ionic liquid [bmim]+[Cl]−, an environmentally benign solvent, was found to promote the Diels-Alder reaction between anthrone and maleimides at room temperature with excellent yields. The ionic liquid played a dual role as solvent and catalyst.

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