New approach for understanding experimental NMR relaxivity properties of magnetic nanoparticles: focus on cobalt ferrite

2016 ◽  
Vol 18 (48) ◽  
pp. 32981-32991 ◽  
Author(s):  
Anne-Laure Rollet ◽  
Sophie Neveu ◽  
Patrice Porion ◽  
Vincent Dupuis ◽  
Nadine Cherrak ◽  
...  

Relaxivities r1 and r2 of cobalt ferrite magnetic nanoparticles (MNPs) have been investigated in the aim of improving the models of NMR relaxation induced by magnetic nanoparticles.

2019 ◽  
Vol 43 (5) ◽  
pp. 1425-1435
Author(s):  
Ronak EISAVI ◽  
Fatemeh AHMADI ◽  
Behzad ZEYNIZADEH ◽  
Mehri KOUHKAN

2015 ◽  
Vol 87 ◽  
pp. 64-71 ◽  
Author(s):  
Gülfem Aygar ◽  
Murat Kaya ◽  
Necati Özkan ◽  
Semra Kocabıyık ◽  
Mürvet Volkan

Author(s):  
Miguel MARTINEZ-MORENO ◽  
Claudia L. GÁMEZ-DUEÑAS ◽  
Rosalba FUENTES-RAMÍREZ ◽  
David CONTRERAS-LOPEZ

Metal corrosion affects various sectors: construction, ships, pipes in the chemical industry, etc. Organic materials have been used as coatings to counteract it; recently improvements have been observed when magnetic polymers are used. These are materials formed by a polymeric matrix and a metal with magnetic properties, such as magnetic nanoparticles. The metal is sacrificed, preventing contact with the surface. Here we show the results of composites formed by magnetic nanoparticles of cobalt ferrite and magnetite obtained by coprecipitation, immersed in polystyrene, butyl polyacrylate and styrene-butyl acrylate copolymer matrices. The nanoparticles were incorporated by ultrasonic bath using different weights of nanoparticles (0.05%, 0.25%, 0.5% and 1%) using toluene as solvent. There is an acceptable dispersion of the nanoparticles in the polyacrylate and copolymer after 4 hours of cavitation, the styrene had acceptable dispersion after 5 hours. The composites were tested on a 316 Cal. 14 stainless steel film of 6 cm2 area, the specimens were dipped in acid to evaluate the corrosion protection with electrochemical techniques, having good results in the ferrite and magnetite composites where the protection capacity was better in the styrene-butyl acrylate copolymer.


2021 ◽  
pp. 8-13
Author(s):  
Miguel Martinez-Moreno ◽  
Rosalba Fuentes-Ramírez ◽  
David Contreras-Lopez ◽  
Rosario Galindo-Gonzalez

Magnetic nanoparticles have been used to confer better properties to materials, particularly to polymers. Due the properties of the polymer, such as flexibility and lightness, combined, white nanoparticles provide other properties such as microhardness, corrosion resistance, among others. In this study, three types of nanoparticles were elaborated: magnetite, cobalt ferrite and nickel ferrite, through the coprecipitation method used in the elaboration of skin-like polyurethane (PU) -based composites. Specimens were made at different nanoparticle weights (0.1%, 0.3%, 0.5% and 1.0%). Likewise, the hardness was measured by means of a phase II Model PHT-2500 portable digital hardness tester and the tension tests were carried out on an Autograph Shimadzu universal machine. The stress results were plotted using the Jupyter Notebook for interpretation. Finding some improvements in the materials manufactured using the different ferrites already mentioned.


2020 ◽  
Vol 193 ◽  
pp. 105663 ◽  
Author(s):  
A.S. Aguiar ◽  
L. Michels ◽  
F.G. da Silva ◽  
C. Kern ◽  
G. Gomide ◽  
...  

2019 ◽  
Vol 10 (1) ◽  
pp. 4908-4913

There are several methods available for magnetic nanoparticles (MNP) synthesis, and in this study the coprecipitation method is employed. The cobalt ferrites (CF) were prepared using aqueous solutions of Co2+ and Fe3+ chloride with a stoichiometry proportion of Co:Fe = 1:2. Thus, the aging temperatures were 27, 27/98, 60, 80 and 98 ºC, during which the precipitation occurred at 27 °C and the aging one at 98 °C for the FC27/98 sample. As a result, the study showed that a single crystal phase material was obtained at the aging temperature of 98 °C during 1 h and with a mean particle size of 42 nm ± 7.4 nm and degree of polydispersity of 18%. The FC98/SiOH coated nanoparticle had a surface area of 11 m2 g-1, saturation magnetization of 10.05 emu g-1 a mean particle size of 773.4 nm ± 131.1 nm and a degree of polydispersity of 17 %. It was possible to confirm that it had a silica coating of cobalt ferrite nanoparticles by DRIFT and EDX indicated the presence of silica.


2010 ◽  
Vol 25 (5) ◽  
pp. 1008-1013 ◽  
Author(s):  
Fredrik Öisjöen ◽  
Justin F. Schneiderman ◽  
Andrea Prieto Astalan ◽  
Alexey Kalabukhov ◽  
Christer Johansson ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document