scholarly journals Dipolar dissociation dynamics in electron collisions with carbon monoxide

2016 ◽  
Vol 18 (48) ◽  
pp. 32973-32980 ◽  
Author(s):  
Dipayan Chakraborty ◽  
Pamir Nag ◽  
Dhananjay Nandi

Fragmentation dynamics of ion-pair states of carbon monoxide in electron collisions through direct and indirect excitation.

2017 ◽  
Vol 875 ◽  
pp. 062008
Author(s):  
Dipayan Chakraborty ◽  
Pamir Nag ◽  
Dhananjay Nandi

1. In an earlier paper I showed that the radiations excited in certain light elements by the bombardment of α -particles consist, at least in part, of particles which have a mass about the same as that of the proton but which have no electric charge. These particles, called neutrons, have some very interesting properties. Some of the more striking were described in the paper I have mentioned and in those of Dr. Feather and Mr. Dee which accompanied it. The most obvious properties of the neutron are its ability to set in motion the atoms of matter through which it passes and its great penetrating power. From measurements of the momenta transferred to different atoms the mass of the neutron was estimated and shown to be nearly the same as the mass of the proton, while the penetrating power shows that the neutron can have no nett electric charge. The loss of energy of a neutron in passing through matter is due to the collisions with the atomic nuclei and not with the electrons. The experiments of Dee showed that the primary ionization along the track of a neutron in air was less than 1 ion pair in 3 metres path, while Massey has calculated that it may be as low as 1 ion pair per 105 km. This behaviour is, of course, very different from that of a charged particle such as a proton, which dissipates its energy almost entirely in electron collisions. The contrast between the rate of loss of energy of a proton and a neutron of the same initial velocity is most striking. A proton of velocity 3 X 109 cm./sec. travels about 1 foot in air, while a neutron of the same initial velocity will on the average make a close collision with a nitrogen nucleus only once in 300 to 400 yards’ path and it may a distance of a few miles before losing all its energy. His collision of a neutron with an atomic nucleus, although much more frequent than with an electron, is also a rare event, tor tire electric field between a neutron and a nucleus is small except at distances of the order of 10 -12 cm. In such a close collision the neutron will be defected from its path and the struck nucleus may acquire sufficient energy to produce ions. Thus the nuclei recoiling from encounters with neutrons can be detected by ionisation measurements, using an ionisation chamber with a sensitive electrometer or with an electrical counting apparatus, or by their ionised traces when produced in an expansion chamber. Neutrons can thus be detected only in an indirect way, by the observation of the recoil atoms. For this reason, and also because they are produced as a result of a similar collision process only partly under our control, the study of their properties in detail has proved both difficult and tedious.


2008 ◽  
Vol 112 (36) ◽  
pp. 8263-8272 ◽  
Author(s):  
Chang Zhou ◽  
Yusong Hao ◽  
Yuxiang Mo

2000 ◽  
Vol 62 (4) ◽  
Author(s):  
Å. Larson ◽  
N. Djurić ◽  
W. Zong ◽  
C. H. Greene ◽  
A. E. Orel ◽  
...  

Author(s):  
Alexandre Faure ◽  
Laurent Wiesenfeld ◽  
Pierre Valiron ◽  
Jonathan Tennyson

Electrons are known to be efficient in rotationally exciting molecular ions in low-density astrophysical plasmas. Rotational excitation of molecular ions has also been shown to affect the measured values of dissociative recombination (DR) rate coefficients. Thus, electron collisions with are expected to play a significant role in thermalization and dissociation dynamics of this ion, both in the laboratory and in space. Using the molecular R -matrix method combined with the adiabatic-nuclei-rotation approximation, we have computed new rate coefficients for the rotational excitation of by electrons at temperatures from 10 to 10 000 K. De-excitation rates are found to amount to a few 10 −7  cm 3  s −1 below 1000 K, i.e. comparable in magnitude to that of DR. In astrophysical environments where the electron fraction exceeds 10 −4 , electron collisions are thus expected to contribute to the non-thermal rotational distribution of . The competition between electron and neutral collisions is discussed in the context of recent observations of towards Galactic centre sources.


2015 ◽  
Vol 92 (6) ◽  
Author(s):  
Enliang Wang ◽  
Xu Shan ◽  
Zhenjie Shen ◽  
Xingyu Li ◽  
Maomao Gong ◽  
...  

Author(s):  
Åsa Larson ◽  
Johanna Roos ◽  
Ann E Orel

The process of resonant ion-pair formation following electron collisions with is studied. The relevant diabatic potential energy surfaces and the electronic couplings between these surfaces are calculated. The reaction is then described using a time-dependent approach with wave packets propagating on the coupled potentials. In order to describe the reaction, it is found necessary to include at least two dimensions in the model. The effects of the Rydberg states on the cross-section for this process are discussed.


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