An ab initio anharmonic approach to study vibrational spectra of small ammonia clusters

2016 ◽  
Vol 18 (44) ◽  
pp. 30498-30506 ◽  
Author(s):  
Kun-Lin Ho ◽  
Lo-Yun Lee ◽  
Marusu Katada ◽  
Asuka Fujii ◽  
Jer-Lai Kuo
Keyword(s):  
Ab Initio ◽  
Vibrational Spectra ◽  
Fermi Resonance ◽  
Ammonia Clusters

Fermi resonance between the N–H stretching (ν1 and ν3) and the overtone of N–H bending (2ν4) in ammonia has hindered the interpretation and assignments of experimental spectra of small ammonia clusters.

Vibrational spectra of small methylamine clusters accessed by an ab initio anharmonic approach

2018 ◽  
Vol 20 (11) ◽  
pp. 7653-7660 ◽  
Author(s):  
Qian-Rui Huang ◽  
Ying-Cheng Li ◽  
Kun-Lin Ho ◽  
Jer-Lai Kuo
Keyword(s):  
Ab Initio ◽  
Vibrational Spectra ◽  
Fermi Resonance

Anharmonic vibrational calculations on Methylamine (MMA) clusters suggest that the origin of the complexity between 2800 and 3000 cm–1 is caused by Fermi resonance (FR) between the stretching and bending overtones of the CH3 group. In trimer and tetramer, FR also causes complex spectra pattern in the NH2 group.

Anharmonic Coupling Revealed by the Vibrational Spectra of Solvated Protonated Methanol: Fermi Resonance, Combination Bands, and Isotope Effect

2021 ◽  
Vol 125 (9) ◽  
pp. 1910-1918
Author(s):  
Chih-Kai Lin ◽  
Qian-Rui Huang ◽  
Ying-Cheng Li ◽  
Ha-Quyen Nguyen ◽  
Jer-Lai Kuo ◽  
...  
Keyword(s):  
Isotope Effect ◽  
Vibrational Spectra ◽  
Fermi Resonance ◽  
Anharmonic Coupling ◽  
Combination Bands

Vibrational spectra of stannane: Harmonic force field, Raman and IR intensities from ab initio correlated wavefunctions

1989 ◽  
Vol 130 (1-3) ◽  
pp. 451-456 ◽  
Author(s):  
Javier Fernandez Sanz ◽  
Antonio Marquez ◽  
Claude Pouchan
Keyword(s):  
Force Field ◽  
Ab Initio ◽  
Vibrational Spectra ◽  
Harmonic Force ◽  
Ir Intensities

Conformational stability, vibrational spectra and ab initio calculations for chloromethyl methyl silane and chloromethyl methyl difluorosilane

1999 ◽  
Vol 480-481 ◽  
pp. 147-151 ◽  
Author(s):  
Gamil A. Guirgis ◽  
Yasser E. Nashed ◽  
James B. Robb II ◽  
Peter Klaeboe ◽  
Pengqian Zhen ◽  
...  
Keyword(s):  
Ab Initio Calculations ◽  
Ab Initio ◽  
Vibrational Spectra ◽  
Conformational Stability

Structural stabilities and transformations in cationized asparagine at finite temperatures: An ab initio molecular dynamics study

2014 ◽  
Vol 13 (04) ◽  
pp. 1450024
Author(s):  
Shoutian Sun ◽  
Jianwen Liu ◽  
Zhi-Feng Liu
Keyword(s):  
Molecular Dynamics ◽  
Ab Initio ◽  
Structural Transformation ◽  
Vibrational Spectra ◽  
Room Temperature ◽  
Ab Initio Molecular Dynamics ◽  
And Shifts ◽  
Torsional Angles

The cationic complexes of Asparagine (Asn), M +( Asn ), with M + = Li +, Na +, K +, Cs +, and H +, are models for studying the interaction between cations and Asn. Ab initio molecular dynamics (AIMD) method is employed to simulate their behavior at finite temperatures. Structural transformation between conformers is observed, which becomes progressively easier as the cation varies from Li +, to Na +, K +, Cs +, and H +. The fluctuation of the M +– N and M +– O distances and rotation of torsional angles are significant even at room temperature for K +, Cs + and H +. Vibrational profiles based on AIMD trajectories provide insights into the broadening and shifts in relative intensities observed in the vibrational spectra measured by infrared multi-photon dissociation (IRMPD) experiments.

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