Vapour adsorption kinetics: statistical rate theory and zeta adsorption isotherm approach

2016 ◽  
Vol 18 (36) ◽  
pp. 25538-25545 ◽  
Author(s):  
Seyed Hadi Zandavi ◽  
C. A. Ward

The zeta adsorption isotherm may be combined with statistical rate theory to formulate an expression for vapour adsorption kinetics that is in terms of a rate constant. For heptane adsorbing on silica, the rate constant is experimentally shown to depend only on temperature.

1997 ◽  
Vol 106 (13) ◽  
pp. 5667-5676 ◽  
Author(s):  
J. A. W. Elliott ◽  
C. A. Ward

Author(s):  
Xiang Wei ◽  
Chunmei Wu ◽  
Yourong Li

The kinetics behavior of vapor adsorption on solid surface in an isobaric-isothermal system are investigated by means of molecular dynamics simulations combined with theoretical studies through statistical rate theory approach....


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