Efficient charge transfer and utilization of near-infrared solar spectrum by ytterbium and thulium codoped gadolinium molybdate (Gd2(MoO4)3:Yb/Tm) nanophosphor in hybrid solar cells

2016 ◽  
Vol 18 (44) ◽  
pp. 30837-30844
Author(s):  
Weifu Sun ◽  
Zihan Chen ◽  
Qin Zhang ◽  
Junli Zhou ◽  
Feng Li ◽  
...  

The novel design of incorporation of Gd2(MoO4)3 into TiO2 film leads to the enhanced charge transport and higher power conversion efficiency of hybrid solar cell.

Author(s):  
Sakshi Tyagi ◽  
Pawan Kumar Singh ◽  
Arun Kumar Tiwari

In today's era, a lot of interest is gained by solar cell formed by combination of organic and inorganic nano-particle semiconductors mainly because of its major features such as scalable solar power conversion and cost effectiveness, which makes the cell a desirable photovoltaic device. This piece of work is an attempt to make a solar cells by the combination of zinc oxide (ZnO) and graphite. ZnO is a good n-type material for the application in photovoltaic (PV) devices due to its better optical, electrical, structural, and environmentally friendly properties, and on the other hand, graphite, an organic semiconductor, enhances the rate of charge transfer in the device. These materials are so designed to help bring in more understanding in a wider range of the solar spectrum. This work focuses on developing solid-state polymer and hybrid solar cells.


2006 ◽  
Vol 129 (3) ◽  
pp. 272-276 ◽  
Author(s):  
L. H. Slooff ◽  
R. Kinderman ◽  
A. R. Burgers ◽  
N. J. Bakker ◽  
J. A. M. van Roosmalen ◽  
...  

One of the major loss mechanisms in state of the art photovoltaic cells is spectral loss resulting from inefficient use of ultraviolet photons and the lack of absorption of infrared photons by the solar cell. For a Si solar cell, e.g., spectral losses alone result in over 55% loss of the energy of the solar spectrum. Converting the spectrum of the incoming light such that it has a better match with the absorption spectrum of the solar cell can reduce spectral losses, especially in the case of a small absorption band, such as for dye sensitized solar cells and polymer solar cells. In this paper it is shown that the ultraviolet response of a multicrystalline silicon solar cell and polymer solar cell can be enhanced by application of a polymer coating doped with a luminescent dye. An increase in the power conversion efficiency is obtained for coatings with luminescent dyes with an absorption onset <450 nm. Coatings with luminescent dyes that absorb at higher wavelengths give rise to lower power conversion efficiencies. When applied to a dye sensitized solar cell, a decrease in the cell performance is observed.


2015 ◽  
Vol 2015 ◽  
pp. 1-10
Author(s):  
Ningning Zhang ◽  
Xiaoping Zou ◽  
Yanyan Gao

Doped films of TiO2/PbS/CdS have been prepared by successive ionic layer adsorption and reaction (SILAR) method. Bi- and Ag-doped-PbS quantum dot (QD) were produced by admixing Bi3+or Ag+during deposition and the existing forms of the doping element in PbS QD were analyzed. The results show that Bi3+entered the cube space of PbS as donor yielding interstitial doping Bi-doped-PbS QD, while Ag+replaced Pb2+of PbS as acceptor yielding substitutional doping Ag-doped-PbS QD. The novel Bi-doped-PbS/CdS and Ag-doped-PbS/CdS quantum dot cosensitized solar cell (QDCSC) were fabricated and power conversion efficiency (PCE) of 2.4% and 2.2% was achieved, respectively, under full sun illumination.


2019 ◽  
Vol 3 (6) ◽  
pp. 1439-1447 ◽  
Author(s):  
Jiadong Qian ◽  
Marco Ernst ◽  
Nandi Wu ◽  
Andrew Blakers

Perovskite/silicon two-junction tandem solar cells have achieved higher power conversion efficiency than silicon cells. However, the long-term performance of tandem modules strongly depends on the degradation of perovskite top cells.


2012 ◽  
Vol 1442 ◽  
Author(s):  
Chung-Te Liu ◽  
Ying-Chiao Wang ◽  
Rui-Xuan Dong ◽  
Kuo-Chuan Ho ◽  
Jiang-Jen Lin

ABSTRACTA novel polymer dispersant, poly(oxyethylene)-segment imide (POEM) in the structure was incorporated in the nanocrystalline TiO2 film as the electrode. The uses of the dispersants could disperse TiO2 by decreasing the van der waals force among the nanoparticles, observed by TEM. The resultant TiO2/POEM film as the photoanode rendered the dye-sensitized solar cell (DSSC) with enhanced performance. By comparing to the traditional photoanode composing of polyethylene glycol (PEG) dispersed TiO2, the POEM dispersed TiO2 provided large surface area and high roughness in the dye adsorbed film. Furthermore, the fabricated TiO2/POEM photoanode has a better light-scattering property which contributes to the improvement for the short-circuit current density (Jsc) and the power-conversion efficiency (_) of the DSSC to be 19.1 mA cm-2 and 8.7%, respectively. The performance is superior to 13.2 mA cm-2 and 7.34% for a DSSC with the photoanode containing TiO2/PEG.


2014 ◽  
Vol 1667 ◽  
Author(s):  
Kamil Mielczarek ◽  
Anvar A. Zakhidov

ABSTRACTRecently, major advances have been made in electrolytic and solid state DSSCs through the use of perovskite nanocrystals as a sensitizing agent where power conversion efficiencies of over 12% have been realized [1–3]. Moreover the planar DSSC/PV devices with perovskites used as photoactive absorbers sandwiched between selective electron and hole transport layers have demonstrated record performances. Additionally, the uses of carbon nanotubes (CNTs) as a flexible, transparent, lightweight and robust electrode material have been demonstrated in both DSSC as well as OPV devices. The application of CNTs as a charge collector with perovskite sensitized solid state planar PV and DSSCs is discussed. Performance characteristics of CNTs within perovskite based hybrid OPVs are investigated and the role of CNTs as an efficient charge collector is extended to the inverted geometry.


2019 ◽  
Vol 8 (4) ◽  
pp. 10142-10147

Solar energy is one in all few sources to renewable power and it is considerably critical in our each day lifestyles usage thus resulted to ensure the practicality and usefulness of the devices which regularly used to capture and manipulate solar energy. In this work, studies the effect of conjugated chlorophyll (iCHLO) on power conversion efficiency with relation of iCHLO where optical and electrical properties were investigated. These hybrid solar cells consist of combination of organic (Poly (3, 4-ethylenedioxythiophene): poly (styrenesulfonate) and iCHLO) and inorganic (Titanium Dioxide, TiO2) materials. These hybrid solar cells were fabricated bilayer of ITO/TiO2/PEDOT: PSS/iCHLO/Al. Chlorophyll compound (CHLO) was extracted from the Pandanus amaryllifolius leaves. CHLO undergoes conjugate process by oxidation polymerization using Ferric Chloride (FeCl3) as catalyst. Different percentage of FeCl3 was varied by 5%, 10% and 15% of CHLO molecular weight. Result shows that UV-Vis absorption spectra of CHLO was absorbed in the range of 400 nm – 600 nm (CHLO-PA) and 240 nm - 360 nm (iCHLO-PA). The highest power conversion efficiency (PCE) was obtained at 1.33% and electrical conductivity is 0.135 Scm1 for ITO/TiO2/PEDOT: PSS/iCHLO-PA 10% hybrid solar cell.


RSC Advances ◽  
2016 ◽  
Vol 6 (27) ◽  
pp. 23048-23057 ◽  
Author(s):  
Mansoor Ani Najeeb ◽  
Shahino Mah Abdullah ◽  
Fakhra Aziz ◽  
Mohamad Izzat Azmer ◽  
Wageh Swelm ◽  
...  

A hybrid solar cell (HSC) based on a ZnSe and CdSe QDs-composite with improved power conversion efficiency has been demonstrated.


Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1380
Author(s):  
Marwa M. Tharwat ◽  
Ashwag Almalki ◽  
Amr M. Mahros

In this paper, a randomly distributed plasmonic aluminum nanoparticle array is introduced on the top surface of conventional GaAs thin-film solar cells to improve sunlight harvesting. The performance of such photovoltaic structures is determined through monitoring the modification of its absorbance due to changing its structural parameters. A single Al nanoparticle array is integrated over the antireflective layer to boost the absorption spectra in both visible and near-infra-red regimes. Furthermore, the planar density of the plasmonic layer is presented as a crucial parameter in studying and investigating the performance of the solar cells. Then, we have introduced a double Al nanoparticle array as an imperfection from the regular uniform single array as it has different size particles and various spatial distributions. The comparison of performances was established using the enhancement percentage in the absorption. The findings illustrate that the structural parameters of the reported solar cell, especially the planar density of the plasmonic layer, have significant impacts on tuning solar energy harvesting. Additionally, increasing the plasmonic planar density enhances the absorption in the visible region. On the other hand, the absorption in the near-infrared regime becomes worse, and vice versa.


Author(s):  
Jie Lv ◽  
Hua Tang ◽  
Jiaming Huang ◽  
Cenqi Yan ◽  
Kuan Liu ◽  
...  

Due to the barrierless free charge generation, low charge trapping, and high charge mobilities, the PM6:Y6 organic solar cell (OSC) achieves excellent power conversion efficiency (PCE) of 15.7%. However, the...


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