Shock wave and modeling study of the reaction CF4 (+M) ⇔ CF3 + F (+M)

2016 ◽  
Vol 18 (26) ◽  
pp. 17592-17596 ◽  
Author(s):  
Gary Knight ◽  
Lars Sölter ◽  
Elsa Tellbach ◽  
Jürgen Troe
Keyword(s):  
Shock Wave ◽  
Thermal Decomposition ◽  
Shock Waves ◽  
Temperature Range ◽  
Modeling Study

The thermal decomposition of CF4 (+Ar) → CF3 + F (+Ar) was studied in shock waves over the temperature range 2000–3000 K. The experiments were shown to correspond to the central part of the falloff curve.

scholarly journals Shock wave study and theoretical modeling of the thermal decomposition of c-C4F8

2015 ◽  
Vol 17 (48) ◽  
pp. 32219-32224 ◽  
Author(s):  
C. J. Cobos ◽  
K. Hintzer ◽  
L. Sölter ◽  
E. Tellbach ◽  
A. Thaler ◽  
...  
Keyword(s):  
Shock Wave ◽  
Thermal Decomposition ◽  
Shock Waves ◽  
Thermal Dissociation ◽  
Theoretical Modeling ◽  
Uv Absorption

The thermal dissociation of octafluorocyclobutane, c-C4F8, was studied in shock waves over the range 1150–2300 K by recording UV absorption signals of CF2.

Experimental and Modeling Study of the Thermal Decomposition of C3–C5 Ethyl Esters Behind Reflected Shock Waves

2014 ◽  
Vol 118 (10) ◽  
pp. 1785-1798 ◽  
Author(s):  
Wei Ren ◽  
R. Mitchell Spearrin ◽  
David F. Davidson ◽  
Ronald K. Hanson
Keyword(s):  
Thermal Decomposition ◽  
Shock Waves ◽  
Ethyl Esters ◽  
Reflected Shock ◽  
Modeling Study

scholarly journals Shock wave and modelling study of the dissociation pathways of (C2F5)3N

2019 ◽  
Vol 21 (19) ◽  
pp. 9785-9792
Author(s):  
C. J. Cobos ◽  
K. Hintzer ◽  
L. Sölter ◽  
E. Tellbach ◽  
A. Thaler ◽  
...  
Keyword(s):  
Shock Wave ◽  
Thermal Decomposition ◽  
Shock Waves ◽  
Modelling Study

The thermal decomposition of perfluorotriethylamine, (C2F5)3N, was investigated in shock waves by monitoring the formation of CF2.

Shock wave studies of the pyrolysis of fluorocarbon oxygenates. II. The thermal dissociation of C4F8O

2017 ◽  
Vol 19 (4) ◽  
pp. 3159-3164 ◽  
Author(s):  
C. J. Cobos ◽  
K. Hintzer ◽  
L. Sölter ◽  
E. Tellbach ◽  
A. Thaler ◽  
...  
Keyword(s):  
Shock Wave ◽  
Thermal Decomposition ◽  
Shock Waves ◽  
Thermal Dissociation

The thermal decomposition of octafluorooxalane, C4F8O, to C2F4 + CF2 + COF2 has been studied in shock waves in Ar between 1300 and 2200 K. Two pathways were identified.

Shock wave studies of the pyrolysis of fluorocarbon oxygenates. I. The thermal dissociation of C3F6O and CF3COF

2017 ◽  
Vol 19 (4) ◽  
pp. 3151-3158 ◽  
Author(s):  
C. J. Cobos ◽  
K. Hintzer ◽  
L. Sölter ◽  
E. Tellbach ◽  
A. Thaler ◽  
...  
Keyword(s):  
Shock Wave ◽  
Thermal Decomposition ◽  
Shock Waves ◽  
Thermal Dissociation ◽  
Hexafluoropropylene Oxide ◽  
Subsequent Decomposition

The thermal decomposition of hexafluoropropylene oxide, C3F6O, to perfluoroacetyl fluoride, CF3COF, and CF2 has been studied in shock waves in Ar between 630 and 1000 K. The subsequent decomposition of CF3COF has been followed between 1400 and 1900 K.

Experimental and theoretical study on thermal decomposition of methyl butanoate behind reflected shock waves

RSC Advances ◽  
2015 ◽  
Vol 5 (105) ◽  
pp. 86536-86550 ◽  
Author(s):  
A. Parandaman ◽  
M. Balaganesh ◽  
B. Rajakumar
Keyword(s):  
Thermal Decomposition ◽  
Shock Waves ◽  
Theoretical Study ◽  
Rate Coefficients ◽  
Temperature Range ◽  
Reflected Shock ◽  
Methyl Butanoate

The rate coefficients for total decomposition of MB in the temperature range of 1229–1427 K, were reported.

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