Interfacial charge-transfer transitions and reorganization energies in sulfur-bridged TiO2-x-benzenedithiol complexes (x: o, m, p)

2016 ◽  
Vol 18 (32) ◽  
pp. 22286-22292 ◽  
Author(s):  
Jun-ichi Fujisawa ◽  
Ryuki Muroga ◽  
Minoru Hanaya
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Reorganization Energy ◽  
Interfacial Charge Transfer ◽  
Charge Transfer Transitions ◽  
Reorganization Energies ◽  
Interfacial Charge

Sulfur-bridging atoms strongly induce interfacial charge-transfer absorption and reduce the reorganization energy in the electron-injected excited state.

Large impact of reorganization energy on photovoltaic conversion due to interfacial charge-transfer transitions

2015 ◽  
Vol 17 (18) ◽  
pp. 12228-12237 ◽  
Author(s):  
Jun-ichi Fujisawa
Keyword(s):  
Charge Transfer ◽  
Energy Loss ◽  
Charge Separation ◽  
Reorganization Energy ◽  
Separation Mechanism ◽  
Interfacial Charge Transfer ◽  
Photovoltaic Conversion ◽  
Charge Transfer Transitions ◽  
One Step ◽  
Interfacial Charge

Interfacial charge-transfer (ICT) transitions are expected to be a novel charge-separation mechanism for efficient photovoltaic conversion featuring one-step charge separation without energy loss.

Toward Exceeding the Shockley−Queisser Limit:  Photoinduced Interfacial Charge Transfer Processes that Store Energy in Excess of the Equilibrated Excited State

2006 ◽  
Vol 128 (25) ◽  
pp. 8234-8245 ◽  
Author(s):  
Paul G. Hoertz ◽  
Aaron Staniszewski ◽  
Andras Marton ◽  
Gerard T. Higgins ◽  
Christopher D. Incarvito ◽  
...  
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Interfacial Charge Transfer ◽  
Transfer Processes ◽  
Interfacial Charge

Interfacial charge-transfer transitions in a TiO2-benzenedithiol complex with Ti–S–C linkages

2015 ◽  
Vol 17 (44) ◽  
pp. 29867-29873 ◽  
Author(s):  
Jun-ichi Fujisawa ◽  
Ryuki Muroga ◽  
Minoru Hanaya
Keyword(s):  
Charge Transfer ◽  
Visible Light ◽  
Room Temperature ◽  
Light Response ◽  
Interfacial Charge Transfer ◽  
Visible Light Response ◽  
Charge Transfer Transitions ◽  
Interfacial Charge

A visible light response of TiO2 due to interfacial charge-transfer transitions was obtained by the addition of benzenedithiol at room temperature.

scholarly journals Interfacial charge-transfer transitions in SnO2 functionalized with benzoic acid derivatives

RSC Advances ◽  
2021 ◽  
Vol 11 (34) ◽  
pp. 20725-20729
Author(s):  
Jun-ichi Fujisawa ◽  
Minoru Hanaya
Keyword(s):  
Charge Transfer ◽  
Benzoic Acid ◽  
Interfacial Charge Transfer ◽  
Benzoic Acid Derivatives ◽  
Charge Transfer Transitions ◽  
Interfacial Charge

First observation of interfacial charge-transfer transitions in SnO2.

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