Organic–inorganic interactions of single crystalline organolead halide perovskites studied by Raman spectroscopy

2016 ◽  
Vol 18 (27) ◽  
pp. 18112-18118 ◽  
Author(s):  
Li-Qiang Xie ◽  
Tai-Yang Zhang ◽  
Liang Chen ◽  
Nanjie Guo ◽  
Yu Wang ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Spectroscopic Study ◽  
Single Crystals ◽  
Single Crystalline ◽  
Raman Spectroscopic ◽  
Raman Spectroscopic Study ◽  
Halide Perovskites ◽  
Organolead Halide

Perovskite single crystals with varied cations and halides have been grown for Raman spectroscopic study of their organic–inorganic interactions.

Raman spectroscopic study of structural transition in SrxBa1−xNb2O6 single crystals

2012 ◽  
Vol 62 ◽  
pp. 273-278 ◽  
Author(s):  
K. Samanta ◽  
A.K. Arora ◽  
T.R. Ravindran ◽  
S. Ganesamoorthy ◽  
K. Kitamura ◽  
...  
Keyword(s):  
Spectroscopic Study ◽  
Single Crystals ◽  
Structural Transition ◽  
Raman Spectroscopic ◽  
Raman Spectroscopic Study

Raman Spectroscopic Study Of Ion-Implanted And Annealed Silicon.

1995 ◽  
Vol 406 ◽  
Author(s):  
David. D. Tuschel ◽  
James P. Lavine ◽  
Jeffrey B. Russell
Keyword(s):  
Raman Spectroscopy ◽  
Raman Spectrum ◽  
Spectroscopic Study ◽  
Complete Recovery ◽  
Acoustic Mode ◽  
Raman Intensity ◽  
Optical Mode ◽  
Raman Spectroscopic ◽  
Raman Spectroscopic Study ◽  
Transverse Acoustic

AbstractRaman spectroscopy is used to characterize silicon implanted with arsenic and then annealed. The implant dose ranged from 2 × 1012 to 2 × 1013/cm2. The as-implanted samples show a decreased Raman intensity of the 520 cm−1 optical mode, and increased Raman intensity between 400 and 500 cm−1 with respect to an unimplanted silicon wafer. The higher arsenic doses show an increase in the second-order transverse acoustic-mode (TA) intensity around 300 cm−1 relative to the secondorder transverse optical-mode (TO) intensity near 970 cm−1. Annealing restores the 2TA/2TO relative intensities and sharpens the weak peaks between 600 and 900 cm−1. The Raman spectrum is altered by the lowest dose implant and the annealing steps do not lead to a complete recovery of the pre-implant Raman spectrum. This permits the monitoring of lowdose ion-implant damage recovery with Raman spectroscopy.

Raman spectroscopy of synthetic, geological and biological vaterite: a Raman spectroscopic study

2009 ◽  
Vol 41 (2) ◽  
pp. 193-201 ◽  
Author(s):  
U. Wehrmeister ◽  
A. L. Soldati ◽  
D. E. Jacob ◽  
T. Häger ◽  
W. Hofmeister
Keyword(s):  
Raman Spectroscopy ◽  
Spectroscopic Study ◽  
Raman Spectroscopic ◽  
Raman Spectroscopic Study

RAMAN SPECTROSCOPIC STUDY OF THE DIFFERENT CRYSTALLOGRAPHIC FACES OF YBa2Cu3O6+δ SINGLE CRYSTALS IN THE TETRAGONAL AND ORTHORHOMBIC PHASES

1991 ◽  
Vol 05 (19) ◽  
pp. 1275-1279
Author(s):  
S. M. RAO ◽  
B. H. LOO ◽  
R. E. BREWSTER ◽  
J. M. CHANG
Keyword(s):  
Spectroscopic Study ◽  
Single Crystals ◽  
Raman Spectra ◽  
Raman Spectroscopic ◽  
Raman Spectroscopic Study ◽  
Two Phases

Raman spectra recorded on different crystallographic faces of the YBa 2 Cu 3 O 6+δ crystals in both the tetragonal and orthorhombic phases are presented which show that the spectra differ for the (001) face in the two phases.

Kaolinite hydroxyls in dimethylsulphoxide-intercalated kaolinites at 77 K – a Raman spectroscopic study

Clay Minerals ◽  
2000 ◽  
Vol 35 (2) ◽  
pp. 443-454 ◽  
Author(s):  
R. L. Frost ◽  
J. Kristof ◽  
E. Horvath ◽  
J. T. Kloprogge
Keyword(s):  
Raman Spectroscopy ◽  
Spectroscopic Study ◽  
Dmso Molecule ◽  
Molecular Forms ◽  
Hydroxyl Groups ◽  
Surface Hydroxyl ◽  
Raman Spectroscopic ◽  
Raman Spectroscopic Study ◽  
Surface Hydroxyl Groups ◽  
Inner Surface

AbstractKaolinite hydroxyls in dimethylsulphoxide-intercalated (DMSO-intercalated) kaolinites have been determined using Raman spectroscopy at 298 and 77 K. The inner surface hydroxyl frequencies at 3650, 3670, 3684 and 3693 cm-1 move to higher wavenumbers upon cooling to 77 K and are observed at 3659, 3676, 3692 and 3702 cm-1. The inner hydroxyl frequency is at 3620 cm-1 at 298 K and is at 3615 cm-1 at 77 K. Upon intercalation with DMSO, additional bands are found at 3660, 3536 and 3501 cm-1 for the low-defect kaolinite and at 3664, 3543 and 3509 cm-1 for the high-defect kaolinite at 298 K. The 3660 cm-1 band at 298 K is resolved into two bands at 3658 and 3663 cm-1 at 77 K for the low-defect kaolinite and these bands are assigned to the inner surface hydroxyl groups, hydrogen-bonded to the DMSO molecule. It is proposed that the DMSO molecule exists with two different orientations in the intercalate and these two molecular forms are differentiated by the OH-stretching bands of the inner surface hydroxyl groups. This band for the high-defect kaolinite is found at 3664 cm-1 at 298 K and resolves into two bands at 3664 and 3673 cm-1 at 77 K.

scholarly journals Raman spectroscopic study of Na1/2Bi1/2TiO3-x%BaTiO3 single crystals as a function of temperature and composition

2011 ◽  
Vol 109 (11) ◽  
pp. 113507 ◽  
Author(s):  
Liang Luo ◽  
Wenwei Ge ◽  
Jiefang Li ◽  
D. Viehland ◽  
Charles Farley ◽  
...  
Keyword(s):  
Spectroscopic Study ◽  
Single Crystals ◽  
Raman Spectroscopic ◽  
Raman Spectroscopic Study

A Raman Spectroscopic Study of the Initial Stages of Hydrolysis Oftetraethoxysilane

1992 ◽  
Vol 271 ◽  
Author(s):  
J. D. Barrie ◽  
K. A. Aitchison
Keyword(s):  
Raman Spectroscopy ◽  
Spectroscopic Study ◽  
Catalyst Concentration ◽  
Reaction Rates ◽  
Reaction Products ◽  
Raman Spectroscopic ◽  
Raman Spectroscopic Study ◽  
Condensation Reactions ◽  
Multichannel Detection ◽  
Hydrolysis And Condensation

ABSTRACTMultichannel detection Raman spectroscopy was used to follow the hydrolysis and condensation reactions of TEOS/ethanol solutions. Effects of alkoxide concentration, catalyst concentration, watenTEOS ratios, and temperature were studied. It was found that the initial oligomeric composition of hydrolyzed solution was dependent upon the amount of water added to the solution: not only did reaction rates differ, but so to did the reaction products. Higher water concentrations resulted in formation of an oligomer which may contain a trisiloxane ring.

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