Solvation dependence observed in the electronic dissymmetry factor spectra: how much information are we missing by analyzing the circular dichroism spectra alone?

2016 ◽  
Vol 18 (20) ◽  
pp. 13912-13917 ◽  
Author(s):  
Cody L. Covington ◽  
Prasad L. Polavarapu
Keyword(s):  
Circular Dichroism ◽  
Absorption Spectra ◽  
Solvent Polarity ◽  
Circular Dichroism Spectra ◽  
Electronic Circular Dichroism ◽  
Circular Dichroïsm

The electronic dissymmetry factor (EDF) spectra reveal that for [1,1′-binaphthalene]-2,2′-diol the experimental EDF spectra show solvent polarity dependent effects that are not apparent in the electronic circular dichroism or absorption spectra.

Theoretical and experimental investigations of the electronic circular dichroism and absorption spectra of bicyclic ketones

1997 ◽  
Vol 224 (2-3) ◽  
pp. 143-155 ◽  
Author(s):  
Friedhelm Pulm ◽  
Jörg Schramm ◽  
Josef Hormes ◽  
Stefan Grimme ◽  
Sigrid D. Peyerimhoff
Keyword(s):  
Circular Dichroism ◽  
Absorption Spectra ◽  
Experimental Investigations ◽  
Electronic Circular Dichroism ◽  
Bicyclic Ketones ◽  
Circular Dichroïsm
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