Ion transport in polycarbonate based solid polymer electrolytes: experimental and computational investigations

2016 ◽  
Vol 18 (14) ◽  
pp. 9504-9513 ◽  
Author(s):  
Bing Sun ◽  
Jonas Mindemark ◽  
Evgeny V. Morozov ◽  
Luciano T. Costa ◽  
Martin Bergman ◽  
...  
Keyword(s):  
Solid State ◽  
Ion Transport ◽  
Lithium Batteries ◽  
Polymer Electrolytes ◽  
Elevated Temperatures ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Alternative Host ◽  
Host Materials

Among the alternative host materials for solid polymer electrolytes (SPEs), polycarbonates have recently shown promising functionality in all-solid-state lithium batteries from ambient to elevated temperatures.

Probing the Fast Lithium-Ion Transport in Small-Molecule Solid Polymer Electrolytes by Solid-State NMR

2020 ◽  
Vol 53 (22) ◽  
pp. 10078-10085
Author(s):  
Xiaobin Fu ◽  
Yiyang Liu ◽  
Wei Wang ◽  
Ling Han ◽  
Jing Yang ◽  
...  
Keyword(s):  
Solid State ◽  
Ion Transport ◽  
Small Molecule ◽  
Polymer Electrolytes ◽  
Solid State Nmr ◽  
Lithium Ion ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer

Morphology control in semicrystalline solid polymer electrolytes for lithium batteries

2019 ◽  
Vol 4 (4) ◽  
pp. 793-803 ◽  
Author(s):  
Xiaowei Li ◽  
Shan Cheng ◽  
Yongwei Zheng ◽  
Christopher Y. Li
Keyword(s):  
Ion Transport ◽  
Transport Properties ◽  
Lithium Batteries ◽  
Polymer Electrolytes ◽  
Morphology Control ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Morphological Control

The significance of morphological control on the ion transport properties of semicrystalline solid polymer electrolytes is illustrated.

Formation of Stable Interphase of Polymer-in-Salt Electrolyte in All-Solid-State Lithium Batteries

2020 ◽  
Vol 2020 ◽  
pp. 1-10
Author(s):  
Hongcai Gao ◽  
Nicholas S. Grundish ◽  
Yongjie Zhao ◽  
Aijun Zhou ◽  
John B. Goodenough
Keyword(s):  
Solid State ◽  
Ionic Conductivity ◽  
Lithium Batteries ◽  
Polymer Electrolytes ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Lithium Metal ◽  
Practical Utilization ◽  
Metal Anode ◽  
Lithium Metal Anode

The integration of solid-polymer electrolytes into all-solid-state lithium batteries is highly desirable to overcome the limitations of current battery configurations that have a low energy density and severe safety concerns. Polyacrylonitrile is an appealing matrix for solid-polymer electrolytes; however, the practical utilization of such polymer electrolytes in all-solid-state cells is impeded by inferior ionic conductivity and instability against a lithium-metal anode. In this work, we show that a polymer-in-salt electrolyte based on polyacrylonitrile with a lithium salt as the major component exhibits a wide electrochemically stable window, a high ionic conductivity, and an increased lithium-ion transference number. The growth of dendrites from the lithium-metal anode was suppressed effectively by the polymer-in-salt electrolyte to increase the safety features of the batteries. In addition, we found that a stable interphase was formed between the lithium-metal anode and the polymer-in-salt electrolyte to restrain the uncontrolled parasitic reactions, and we demonstrated an all-solid-state battery configuration with a LiFePO4 cathode and the polymer-in-salt electrolyte, which exhibited a superior cycling stability and rate capability.

The pursuit of solid-state electrolytes for lithium batteries: from comprehensive insight to emerging horizons

2016 ◽  
Vol 3 (6) ◽  
pp. 487-516 ◽  
Author(s):  
Renjie Chen ◽  
Wenjie Qu ◽  
Xing Guo ◽  
Li Li ◽  
Feng Wu
Keyword(s):  
Solid State ◽  
Lithium Batteries ◽  
Polymer Electrolytes ◽  
Solid Electrolytes ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Composite Solid Electrolytes ◽  
Solid State Electrolytes ◽  
Composite Solid

This review systematically summarizes the limitations of solid electrolytes including inorganic solid electrolytes, solid polymer electrolytes, and composite solid electrolytes.

scholarly journals The Impact of Absorbed Solvent on the Performance of Solid Polymer Electrolytes for Use in Solid-State Lithium Batteries

iScience ◽  
2020 ◽  
Vol 23 (10) ◽  
pp. 101597
Author(s):  
Gabrielle Foran ◽  
Denis Mankovsky ◽  
Nina Verdier ◽  
David Lepage ◽  
Arnaud Prébé ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Batteries ◽  
Polymer Electrolytes ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
The Impact
Sign in / Sign up

Export Citation Format

Share Document