Palladium-atom catalyzed formic acid decomposition and the switch of reaction mechanism with temperature

2016 ◽  
Vol 18 (15) ◽  
pp. 10005-10017 ◽  
Author(s):  
Nan He ◽  
Zhen Hua Li
Keyword(s):  
Reaction Mechanism ◽  
Formic Acid ◽  
Palladium Atom ◽  
Acid Decomposition ◽  
Atom Model ◽  
Formic Acid Decomposition

We carefully calculated the mechanism of one-atom model and its poisoned species, PdCO, as formic acid decomposition catalysts.

scholarly journals Reaction Mechanism of Vapor-Phase Formic Acid Decomposition over Platinum Catalysts: DFT, Reaction Kinetics Experiments, and Microkinetic Modeling

ACS Catalysis ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 4112-4126 ◽  
Author(s):  
Saurabh Bhandari ◽  
Srinivas Rangarajan ◽  
Christos T. Maravelias ◽  
James A. Dumesic ◽  
Manos Mavrikakis
Keyword(s):  
Reaction Mechanism ◽  
Formic Acid ◽  
Reaction Kinetics ◽  
Vapor Phase ◽  
Platinum Catalysts ◽  
Acid Decomposition ◽  
Microkinetic Modeling ◽  
Formic Acid Decomposition

Comparative theoretical study of formic acid decomposition on PtAg(111) and Pt(111) surfaces

RSC Advances ◽  
2015 ◽  
Vol 5 (27) ◽  
pp. 21170-21177 ◽  
Author(s):  
Yuanyuan Qi ◽  
Jun Gao ◽  
Dongju Zhang ◽  
Chengbu Liu
Keyword(s):  
Formic Acid ◽  
Theoretical Study ◽  
Catalytic Decomposition ◽  
Model Catalyst ◽  
Single Atom ◽  
Acid Decomposition ◽  
Atom Model ◽  
Formic Acid Decomposition ◽  
The Ideal

This theoretical study compares the catalytic decomposition pathways of HCOOH on pure Pt surface with the ideal single-atom model catalyst of PtAg nanostructures.

scholarly journals Strategic examination of the classical catalysis of formic acid decomposition for intermittent hydrogen production, storage and supply: A review

2021 ◽  
Vol 45 ◽  
pp. 101078
Author(s):  
Samuel Eshorame Sanni ◽  
Peter Adeniyi Alaba ◽  
Emeka Okoro ◽  
Moses Emetere ◽  
Babalola Oni ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Formic Acid ◽  
Acid Decomposition ◽  
Formic Acid Decomposition

scholarly journals UV-A light-assisted gas-phase formic acid decomposition on photo-thermo Ru/TiO2 catalyst

2021 ◽  
Author(s):  
Javier Ivanez ◽  
Patricia Garcia-Munoz ◽  
Agnieszka M. Ruppert ◽  
Nicolas Keller
Keyword(s):  
Formic Acid ◽  
Gas Phase ◽  
Acid Decomposition ◽  
Tio2 Catalyst ◽  
Formic Acid Decomposition

Disclosing the role of Gold on Palladium ‐ Gold alloyed supported catalysts in formic acid decomposition

ChemCatChem ◽  
2021 ◽  
Author(s):  
Alberto Villa ◽  
Ilaria Barlocco ◽  
Sofia Capelli ◽  
Xiuyuan Lu ◽  
Silvio Bellomi ◽  
...  
Keyword(s):  
Formic Acid ◽  
Supported Catalysts ◽  
Acid Decomposition ◽  
Formic Acid Decomposition

Promotion of Ammonium Formate and Formic Acid Decomposition over Au/TiO2 by Support Basicity under SCR-Relevant Conditions

ACS Catalysis ◽  
2015 ◽  
Vol 5 (8) ◽  
pp. 4772-4782 ◽  
Author(s):  
Manasa Sridhar ◽  
Davide Ferri ◽  
Martin Elsener ◽  
Jeroen Anton van Bokhoven ◽  
Oliver Kröcher
Keyword(s):  
Formic Acid ◽  
Ammonium Formate ◽  
Acid Decomposition ◽  
Formic Acid Decomposition

Enhancing the Feasibility of Pd/C-catalyzed Formic Acid Decomposition for Hydrogen Generation – Catalyst Pretreatment, Deactivation, and Regeneration

2021 ◽  
Author(s):  
Axel Kosider ◽  
Dominik Blaumeiser ◽  
Simon Schoetz ◽  
Patrick Preuster ◽  
Andreas Bösmann ◽  
...  
Keyword(s):  
Formic Acid ◽  
Low Temperatures ◽  
Hydrogen Generation ◽  
Side Reactions ◽  
Acid Decomposition ◽  
Catalyst Pretreatment ◽  
Formic Acid Decomposition ◽  
Catalyst Systems

Formic acid decomposition (FAD) generates H2 at low temperatures. However, many known catalyst systems suffer from deactivation due to competing side reactions during FAD. In this work, we focus on...

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