Rational design and synthesis of an amino-functionalized hydrogen-bonded network with an ACO zeolite-like topology for gas storage

CrystEngComm ◽  
2016 ◽  
Vol 18 (30) ◽  
pp. 5616-5619 ◽  
Author(s):  
Xiao-Qing Guo ◽  
Miao Wang ◽  
Fei Meng ◽  
Yan-Feng Tang ◽  
Shu Tian ◽  
...  
Keyword(s):  
Great Improvement ◽  
Rational Design ◽  
Gas Adsorption ◽  
Gas Storage ◽  
Amino Groups ◽  
Design And Synthesis ◽  
Hydrogen Bonded

The modification of amino groups on the surface of In8 cubic SBUs comprising hydrogen-bonded networks with an ACO zeolite-like topology resulted in a great improvement in gas adsorption.

scholarly journals Playing with covalent triazine framework tiles for improved CO2 adsorption properties and catalytic performance

2019 ◽  
Vol 10 ◽  
pp. 1217-1227 ◽  
Author(s):  
Giulia Tuci ◽  
Andree Iemhoff ◽  
Housseinou Ba ◽  
Lapo Luconi ◽  
Andrea Rossin ◽  
...  
Keyword(s):  
Carbon Capture ◽  
Rational Design ◽  
Gas Adsorption ◽  
Ambient Pressure ◽  
Complex Structure ◽  
Building Blocks ◽  
Catalytic Performance ◽  
High Specific Surface Area ◽  
Morphological Properties ◽  
Design And Synthesis

The rational design and synthesis of covalent triazine frameworks (CTFs) from defined dicyano-aryl building blocks or their binary mixtures is of fundamental importance for a judicious tuning of the chemico-physical and morphological properties of this class of porous organic polymers. In fact, their gas adsorption capacity and their performance in a variety of catalytic transformations can be modulated through an appropriate selection of the building blocks. In this contribution, a set of five CTFs (CTF1–5) have been prepared under classical ionothermal conditions from single dicyano-aryl or heteroaryl systems. The as-prepared samples are highly micro-mesoporous and thermally stable materials featuring high specific surface area (up to 1860 m2·g−1) and N content (up to 29.1 wt %). All these features make them highly attractive samples for carbon capture and sequestration (CCS) applications. Indeed, selected polymers from this series rank among the CTFs with the highest CO2 uptake at ambient pressure reported so far in the literature (up to 5.23 and 3.83 mmol·g−1 at 273 and 298 K, respectively). Moreover, following our recent achievements in the field of steam- and oxygen-free dehydrogenation catalysis using CTFs as metal-free catalysts, the new samples with highest N contents have been scrutinized in the process to provide additional insights to their complex structure–activity relationship.

Advances in the use of MOFs for Cancer Diagnosis and Treatment: An Overview

2020 ◽  
Vol 26 (33) ◽  
pp. 4174-4184
Author(s):  
Marina P. Abuçafy ◽  
Bruna L. da Silva ◽  
João A. Oshiro-Junior ◽  
Eloisa B. Manaia ◽  
Bruna G. Chiari-Andréo ◽  
...  
Keyword(s):  
Drug Delivery ◽  
Drug Delivery Systems ◽  
Rational Design ◽  
Gas Adsorption ◽  
Drug Loading ◽  
Drug Carriers ◽  
Delivery Systems ◽  
Academic Community ◽  
Anticancer Drug Delivery ◽  
Diagnostic Agents

Nanoparticles as drug delivery systems and diagnostic agents have gained much attention in recent years, especially for cancer treatment. Nanocarriers improve the therapeutic efficiency and bioavailability of antitumor drugs, besides providing preferential accumulation at the target site. Among different types of nanocarriers for drug delivery assays, metal-organic frameworks (MOFs) have attracted increasing interest in the academic community. MOFs are an emerging class of coordination polymers constructed of metal nodes or clusters and organic linkers that show the capacity to combine a porous structure with high drug loading through distinct kinds of interactions, overcoming the limitations of traditional drug carriers explored up to date. Despite the rational design and synthesis of MOFs, structural aspects and some applications of these materials like gas adsorption have already been comprehensively described in recent years; it is time to demonstrate their potential applications in biomedicine. In this context, MOFs can be used as drug delivery systems and theranostic platforms due to their ability to release drugs and accommodate imaging agents. This review describes the intrinsic characteristics of nanocarriers used in cancer therapy and highlights the latest advances in MOFs as anticancer drug delivery systems and diagnostic agents.

scholarly journals Rational Design and Synthesis of Right-Handed d-Sulfono-γ-AApeptide Helical Foldamers as Potent Inhibitors of Protein–Protein Interactions

2020 ◽  
Vol 85 (16) ◽  
pp. 10552-10560
Author(s):  
Peng Sang ◽  
Yan Shi ◽  
Pirada Higbee ◽  
Minghui Wang ◽  
Sami Abdulkadir ◽  
...  
Keyword(s):  
Protein Interactions ◽  
Rational Design ◽  
Protein Protein Interactions ◽  
Design And Synthesis

Rational design and synthesis of novel Syk-kinase inhibitors

2012 ◽  
Vol 22 (2) ◽  
pp. 73-74 ◽  
Author(s):  
Alexey A. Zeifman ◽  
Ilya Yu. Titov ◽  
Igor V. Svitanko ◽  
Tatiana V. Rakitina ◽  
Aleksey V. Lipkin ◽  
...  
Keyword(s):  
Rational Design ◽  
Kinase Inhibitors ◽  
Design And Synthesis ◽  
Syk Kinase

Rational design and synthesis of multimorphology mesoporous carbon@silica nanoparticles with tailored structure

Carbon ◽  
2021 ◽  
Author(s):  
Yajuan Zhao ◽  
Haolin Lyu ◽  
Yujie Liu ◽  
Wenjie Liu ◽  
Yong Tian ◽  
...  
Keyword(s):  
Silica Nanoparticles ◽  
Mesoporous Carbon ◽  
Rational Design ◽  
Design And Synthesis

scholarly journals Rational Design and Synthesis of a Novel Anti-leukemic Agent Targeting Bruton′s Tyrosine Kinase (BTK), LFM-A13 [α-Cyano-β-Hydroxy-β-Methyl-N-(2,5-Dibromophenyl)Propenamide]

1999 ◽  
Vol 274 (14) ◽  
pp. 9587-9599 ◽  
Author(s):  
Sandeep Mahajan ◽  
Sutapa Ghosh ◽  
Elise A. Sudbeck ◽  
Yaguo Zheng ◽  
Suzanne Downs ◽  
...  
Keyword(s):  
Tyrosine Kinase ◽  
Rational Design ◽  
Design And Synthesis

3D hierarchically mesoporous Cu-doped NiO nanostructures as high-performance anode materials for lithium ion batteries

CrystEngComm ◽  
2015 ◽  
Vol 17 (48) ◽  
pp. 9336-9347 ◽  
Author(s):  
Jingyun Ma ◽  
Longwei Yin ◽  
Tairu Ge
Keyword(s):  
Porous Structure ◽  
Lithium Ion Batteries ◽  
Surface Area ◽  
Anode Materials ◽  
High Performance ◽  
Rational Design ◽  
Three Dimensional ◽  
Lithium Ion ◽  
Design And Synthesis ◽  
Hierarchically Porous Structure

We report on the rational design and synthesis of three dimensional (3D) Cu-doped NiO architectures with an adjustable chemical component, surface area, and hierarchically porous structure as anodes for lithium ion battery.

Sign in / Sign up

Export Citation Format

Share Document