Photodimerisation of the α′-polymorph of ortho-ethoxy-trans-cinnamic acid occurs via a two-stage mechanism at 343 K yielding 100% α-truxillic acid

M. A. Fernandes; D. C. Levendis

doi:10.1039/c6ce00809g

Photodimerisation of the α′-polymorph of ortho-ethoxy-trans-cinnamic acid occurs via a two-stage mechanism at 343 K yielding 100% α-truxillic acid

CrystEngComm ◽

10.1039/c6ce00809g ◽

2016 ◽

Vol 18 (38) ◽

pp. 7363-7376 ◽

Cited By ~ 9

Author(s):

M. A. Fernandes ◽

D. C. Levendis

Keyword(s):

Cinnamic Acid ◽

Two Stage ◽

Truxillic Acid

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Topochemical studies. X. Structures of 4-methyl-trans-cinnamic acid and 4,4'-dimethyl-α-truxillic acid

Acta Crystallographica Section C Crystal Structure Communications ◽

10.1107/s0108270188010649 ◽

1989 ◽

Vol 45 (1) ◽

pp. 154-157 ◽

Cited By ~ 5

Author(s):

S. Kashino ◽

H. Oka ◽

M. Haisa

Keyword(s):

Cinnamic Acid ◽

Truxillic Acid

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Kinetics of the Single-Crystal to Single-Crystal Two-Photon Photodimerization of α-trans-Cinnamic Acid to α-Truxillic Acid

The Journal of Physical Chemistry A ◽

10.1021/jp809170t ◽

2009 ◽

Vol 113 (13) ◽

pp. 3116-3120 ◽

Cited By ~ 64

Author(s):

Jason B. Benedict ◽

Philip Coppens

Keyword(s):

Single Crystal ◽

Cinnamic Acid ◽

Two Photon ◽

Truxillic Acid ◽

Kinetics Of

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Solid-State Photodimerization Kinetics of α-trans-Cinnamic Acid to α-Truxillic Acid Studied via Solid-State NMR

The Journal of Physical Chemistry B ◽

10.1021/jp057417h ◽

2006 ◽

Vol 110 (12) ◽

pp. 6270-6273 ◽

Cited By ~ 69

Author(s):

Marko Bertmer ◽

Ryan C. Nieuwendaal ◽

Alexander B. Barnes ◽

Sophia E. Hayes

Keyword(s):

Solid State ◽

Cinnamic Acid ◽

Solid State Nmr ◽

Truxillic Acid ◽

Kinetics Of

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An Unexpected Phase Transition during the [2 + 2] Photocycloaddition Reaction of Cinnamic Acid to Truxillic Acid: Changes in Polymorphism Monitored by Solid-State NMR

The Journal of Physical Chemistry B ◽

10.1021/jp806218u ◽

2008 ◽

Vol 112 (41) ◽

pp. 12920-12926 ◽

Cited By ~ 22

Author(s):

Ryan C. Nieuwendaal ◽

Marko Bertmer ◽

Sophia E. Hayes

Keyword(s):

Phase Transition ◽

Solid State ◽

Cinnamic Acid ◽

Solid State Nmr ◽

Truxillic Acid

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Two-stage self-seeding method for preparation of single crystals of poly(phenylene sulfide)

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100153816 ◽

1989 ◽

Vol 47 ◽

pp. 368-369

Author(s):

Sengshiu Chung ◽

Peggy Cebe

Keyword(s):

Single Crystals ◽

High Performance ◽

Dilute Solution ◽

Two Stage ◽

Annealing Behavior ◽

High Performance Polymers ◽

Seeding Method ◽

Phenylene Sulfide

We are studying the crystallization and annealing behavior of high performance polymers, like poly(p-pheny1ene sulfide) PPS, and poly-(etheretherketone), PEEK. Our purpose is to determine whether PPS, which is similar in many ways to PEEK, undergoes reorganization during annealing. In an effort to address the issue of reorganization, we are studying solution grown single crystals of PPS as model materials.Observation of solution grown PPS crystals has been reported. Even from dilute solution, embrionic spherulites and aggregates were formed. We observe that these morphologies result when solutions containing uncrystallized polymer are cooled. To obtain samples of uniform single crystals, we have used two-stage self seeding and solution replacement techniques.

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