The first nucleophilic C–H perfluoroalkylation of aromatic compounds via (arene)tricarbonylchromium complexes

2017 ◽  
Vol 53 (13) ◽  
pp. 2146-2149 ◽  
Author(s):  
Natalia V. Kirij ◽  
Andrey A. Filatov ◽  
Gleb Yu. Khrapach ◽  
Yurii L. Yagupolskii
Keyword(s):  
Aromatic Compounds ◽  
Mild Conditions ◽  
Tricarbonylchromium Complexes

Complexed and reversibly activated arenes selectively react with a perfluoroalkyl anion under mild conditions, forming cyclohexadienyl adducts that readily undergo oxidation to perfluoroalkyl arenes.

Visible-Light-Induced Radical Polynitration of Arylboronic Acids: Synthesis of Polynitrophenols

Synthesis ◽  
2018 ◽  
Vol 50 (15) ◽  
pp. 2891-2896 ◽  
Author(s):  
Jinna Song ◽  
Xihe Bi ◽  
Qi Zhang ◽  
Kaki Raveendra Babu ◽  
Zhouliang Huang
Keyword(s):  
Visible Light ◽  
Aromatic Compounds ◽  
Functional Group ◽  
Simple Procedure ◽  
One Pot ◽  
Arylboronic Acids ◽  
Mild Conditions ◽  
Conventional Methods ◽  
Straightforward Approach

We report a visible light-assisted one-pot method for the synthesis of polynitrophenols through radical tandem hydroxylation and nitration of arylboronic acids by utilizing copper(II) nitrate tri­hydrate as the nitro source. This method features mild conditions, a simple procedure, and good functional group tolerance. Compared to conventional methods, this work provides a straightforward approach for the polynitration of aromatic compounds.

Palladium(II) Catalyzed Carboxylation of Aromatic Compounds with CO under Very Mild Conditions

1995 ◽  
Vol 24 (5) ◽  
pp. 345-346 ◽  
Author(s):  
Yuki Taniguchi ◽  
Yoshinori Yamaoka ◽  
Kazuyuki Nakata ◽  
Ken Takaki ◽  
Yuzo Fujiwara
Keyword(s):  
Aromatic Compounds ◽  
Mild Conditions

Synthesis of Methyl 1-Aryl-2-oxo-cycloalkanecarboxylatesvia tricarbonylchromium complexes under mild conditions

1997 ◽  
Vol 339 (1) ◽  
pp. 171-175 ◽  
Author(s):  
J. Deutsch ◽  
M. Bartoszek ◽  
M. Schneider ◽  
V. Zabel ◽  
H.-J. Niclas
Keyword(s):  
Mild Conditions ◽  
Tricarbonylchromium Complexes

ChemInform Abstract: Palladium(II) Catalyzed Carboxylation of Aromatic Compounds with CO under Very Mild Conditions.

ChemInform ◽  
2010 ◽  
Vol 26 (41) ◽  
pp. no-no
Author(s):  
Y. TANIGUCHI ◽  
Y. YAMAOKA ◽  
K. NAKATA ◽  
K. TAKAKI ◽  
Y. FUJIWARA
Keyword(s):  
Aromatic Compounds ◽  
Mild Conditions
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