scholarly journals Efficient preparation of carbamates by Rh-catalysed oxidative carbonylation: unveiling the role of the oxidant

2017 ◽  
Vol 53 (2) ◽  
pp. 404-407 ◽  
Author(s):  
Amaia Iturmendi ◽  
Manuel Iglesias ◽  
Julen Munárriz ◽  
Victor Polo ◽  
Jesús J. Pérez-Torrente ◽  
...  

A Rh(i)-catalysed three-component reaction allows access to carbamates from amines or imines under mild conditions in the presence of Oxone, which plays a dual role as a base and an oxidant.

2021 ◽  
Vol 19 (1) ◽  
pp. 156-161
Author(s):  
Silvia Anselmi ◽  
Siyu Liu ◽  
Seong-Heun Kim ◽  
Sarah M. Barry ◽  
Thomas S. Moody ◽  
...  

Sulfoxides have been synthesised from various sulfide substrates under mild conditions exploiting CALB biocatalyst in the presence of urea hydrogen peroxide and AcOEt which acts with the dual role of solvent and reagent.


2014 ◽  
Vol 122 (03) ◽  
Author(s):  
A Chatzigeorgiou ◽  
R Garcia-Martin ◽  
KJ Chung ◽  
I Alexaki ◽  
A Klotzsche-von Ameln ◽  
...  

2008 ◽  
Vol 3 (S 1) ◽  
Author(s):  
U Bernhardt ◽  
HG Joost ◽  
H Al-Hasani
Keyword(s):  

Author(s):  
Huihui Tang ◽  
Sungdae Park ◽  
Kam C. Yeung
Keyword(s):  

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