N-Doping of graphene oxide at low temperature for the oxygen reduction reaction

2017 ◽  
Vol 53 (5) ◽  
pp. 873-876 ◽  
Author(s):  
Hengcong Tao ◽  
Chao Yan ◽  
Alex W. Robertson ◽  
Yunnan Gao ◽  
Jingjing Ding ◽  
...  

Nitrogen doping of graphene oxide was demonstrated for the first time at 5 °C in ammonia solution via ultrasonication.

2020 ◽  
Vol 11 ◽  
pp. 1-15 ◽  
Author(s):  
Maximilian Wassner ◽  
Markus Eckardt ◽  
Andreas Reyer ◽  
Thomas Diemant ◽  
Michael S Elsaesser ◽  
...  

Amorphous and graphitized nitrogen-doped (N-doped) carbon spheres are investigated as structurally well-defined model systems to gain a deeper understanding of the relationship between synthesis, structure, and their activity in the oxygen reduction reaction (ORR). N-doped carbon spheres were synthesized by hydrothermal treatment of a glucose solution yielding carbon spheres with sizes of 330 ± 50 nm, followed by nitrogen doping via heat treatment in ammonia atmosphere. The influence of a) varying the nitrogen doping temperature (550–1000 °C) and b) of a catalytic graphitization prior to nitrogen doping on the carbon sphere morphology, structure, elemental composition, N bonding configuration as well as porosity is investigated in detail. For the N-doped carbon spheres, the maximum nitrogen content was found at a doping temperature of 700 °C, with a decrease of the N content for higher temperatures. The overall nitrogen content of the graphitized N-doped carbon spheres is lower than that of the amorphous carbon spheres, however, also the microporosity decreases strongly with graphitization. Comparison with the electrocatalytic behavior in the ORR shows that in addition to the N-doping, the microporosity of the materials is critical for an efficient ORR.


2018 ◽  
Vol 20 (23) ◽  
pp. 15613-15617 ◽  
Author(s):  
Mitsuharu Chisaka

Active sites were created on ORR-active titanium oxynitride by low-temperature annealing without changing the nitrogen doping level to determine their origin.


2021 ◽  
pp. 139410
Author(s):  
Oleg Yu Posudievsky ◽  
Andrey S. Kondratyuk ◽  
Olga A. Kozarenko ◽  
Vsevolod V. Cherepanov ◽  
Volodymyr L. Karbivskiy ◽  
...  

2018 ◽  
Vol 42 (3) ◽  
pp. 2081-2088 ◽  
Author(s):  
Man Zhang ◽  
Wei Hong ◽  
Ruinan Xue ◽  
Lingzhi Li ◽  
Guanbo Huang ◽  
...  

At present, low-cost and efficient electrocatalysts for accelerating the oxygen reduction reaction in fuel cells are highly desired.


2021 ◽  
Vol MA2021-02 (36) ◽  
pp. 1024-1024
Author(s):  
Hassan Shirzadi Jahromi ◽  
Shivi Saxena ◽  
Sudharsan Sridhar ◽  
Muralidhar K Ghantasala ◽  
Ramakrishna Guda ◽  
...  

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