scholarly journals Ag+ coordination polymers of a chiral thiol ligand bearing an AIE fluorophore

2017 ◽  
Vol 53 (1) ◽  
pp. 255-258 ◽  
Author(s):  
Dan-Dan Tao ◽  
Qian Wang ◽  
Xiao-Sheng Yan ◽  
Na Chen ◽  
Zhao Li ◽  
...  

The Ag+ coordination polymers of a chiral thiol ligand containing an AIE fluorophore differ very much in their supramolecular structures compared to the aggregates of the thiol ligand itself. The differences in the extent of fluorescence enhancement are detailed for the first time.

RSC Advances ◽  
2019 ◽  
Vol 9 (48) ◽  
pp. 28135-28145
Author(s):  
Ahmed I. A. Abd El-Mageed ◽  
Takuji Ogawa

For the first time, using scanning probe microscopy, the supramolecular structures of terbium porphyrin double-decker complexes were observed on single-walled carbon nanotubes surfaces, where the molecules formed a well-ordered self-assembled array.


2019 ◽  
Vol 43 (34) ◽  
pp. 13371-13380 ◽  
Author(s):  
Sheikdawood Parveen ◽  
Thathan Premkumar ◽  
Hung Huy Nguyen ◽  
Subbiah Govindarajan

For the first time, a new hydrazone Schiff base ligand and its Co(ii), Ni(ii), and Cu(ii) complexes were synthesised and characterised. Their antioxidant and binding activities towards CT-DNA and BSA were evaluated.


2020 ◽  
Vol 44 (14) ◽  
pp. 5285-5292 ◽  
Author(s):  
Jinfang Zhang ◽  
Hongchen Xia ◽  
Simeng Ren ◽  
Wen Jia ◽  
Chi Zhang

Cu(i) CPs were constructed for the first time with the AIE ligand DPMF; they exhibited distinct architectures and efficient detection of TNP.


RSC Advances ◽  
2016 ◽  
Vol 6 (11) ◽  
pp. 9270-9277 ◽  
Author(s):  
Guoqi Zhang ◽  
Jiawen Tan ◽  
Tonya Phoenix ◽  
David R. Manke ◽  
James A. Golen ◽  
...  

HgII-mediated self-assembly of metal–organic coordination polymers based on 4,2′:6′,4′′-terpyridine derivatives is for the first time presented and the structural diversity dependent upon the use of 4′-substituents of ligand is revealed.


2017 ◽  
Vol 15 (28) ◽  
pp. 6006-6013 ◽  
Author(s):  
Liangbin Lin ◽  
Xiaoru Lin ◽  
Hongyu Guo ◽  
Fafu Yang

Diphenylacrylonitrile-connected BODIPY dyes were reported for the first time, and they exhibited remarkable fluorescence enhancement based on both dark and AIE resonance energy transfers.


2019 ◽  
Vol 126 (5) ◽  
pp. 636
Author(s):  
А.А. Намыкин ◽  
А.П. Хороводов ◽  
О.В. Семячкина-Глушковская ◽  
В.В. Тучин ◽  
И.В. Федосов

AbstractThe effect of photoinduced enhancement of Evans blue (EB) dye fluorescence in blood plasma and albumin solution has been considered. Manifestations of the dye fluorescence enhancement in the albumin solution and rat blood plasma have been compared. Saturation of photoinduced fluorescence, the effect of enhanced fluorescence delay, and divergence in fluorescence spectra of the solutions have been found for the first time. Based on the obtained results, a hypothesis about the presence of nonfluorescent complexes with the EB participation in blood plasma is proposed.


Molecules ◽  
2019 ◽  
Vol 24 (15) ◽  
pp. 2717 ◽  
Author(s):  
Dmitry Pavlov ◽  
Taisiya Sukhikh ◽  
Evgeny Filatov ◽  
Andrei Potapov

For the first time, orthogonally substituted azole-carboxylate adamantane ligands were synthesized and used for preparation of coordination polymers. The angle-shaped ligands were prepared by the reaction of 1-adamantanecarboxylic acid and azoles (1H-1,2,4-triazole, 3-methyl-1H-1,2,4-triazole, 3,5-dimethyl-1H-1,2,4-triazole, 1H-tetrazole, 5-methyl-1H-tetrazole) in concentrated sulfuric acid. Variation of the solvent and substituents in azole rings allowed to prepare both 1D and 2D copper(II) and nickel(II) coordination polymers, [Cu2(trzadc)4(H2O)0.7]∙DMF∙0.3H2O, [Cu(trzadc)2(MeOH)]∙MeOH, [Ni(trzadc)2(MeOH)2] and [Cu2(mtrzadc)3(MeOH)]+NO3– (trzadc-3-(1,2,4-triazol-1-yl)-adamantane-1-carboxylic acid; mtrzadc-3-(3-methyl-1,2,4-triazol-1-yl)-adamantane-1-carboxylic acid) which were structurally characterized by single crystal X-ray diffraction. Complex [Cu(trzadc)2(MeOH)]∙MeOH was shown to act as a catalyst in the Chan-Evans-Lam arylation reaction.


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