Molecular engineering for efficient and selective iron porphyrin catalysts for electrochemical reduction of CO2 to CO

2016 ◽  
Vol 52 (100) ◽  
pp. 14478-14481 ◽  
Author(s):  
Ram B. Ambre ◽  
Quentin Daniel ◽  
Ting Fan ◽  
Hong Chen ◽  
Biaobiao Zhang ◽  
...  
Keyword(s):  
Electrochemical Reduction ◽  
Molecular Engineering ◽  
Iron Porphyrin ◽  
Reduction Of Co2 ◽  
Catalytic Performances

Dramatic effects of ortho, meta and para substituents on the catalytic performances of Fe-porphyrin for CO2 reduction to CO have been investigated.

Highly ordered mesoporous carbon/iron porphyrin nanoreactor for the electrochemical reduction of CO2

2020 ◽  
Vol 8 (30) ◽  
pp. 14966-14974 ◽  
Author(s):  
Jaecheol Choi ◽  
Jeonghun Kim ◽  
Pawel Wagner ◽  
Jongbeom Na ◽  
Gordon G. Wallace ◽  
...  
Keyword(s):  
Electrochemical Reduction ◽  
Surface Area ◽  
Mesoporous Carbon ◽  
Ordered Mesoporous Carbon ◽  
Iron Porphyrin ◽  
Faradaic Efficiency ◽  
Ordered Mesoporous ◽  
Conductive Substrate ◽  
Carbon Iron ◽  
Reduction Of Co2

A highly ordered mesoporous carbon having a large surface area is utilized as a conductive substrate to immobilize iron porphyrin catalysts for electrochemical CO2 reduction, resulting in the selective conversion of aqueous CO2 into CO with 92.1% faradaic efficiency.

Energy efficient electrochemical reduction of CO2 to CO using a three-dimensional porphyrin/graphene hydrogel

2019 ◽  
Vol 12 (2) ◽  
pp. 747-755 ◽  
Author(s):  
Jaecheol Choi ◽  
Jeonghun Kim ◽  
Pawel Wagner ◽  
Sanjeev Gambhir ◽  
Rouhollah Jalili ◽  
...  
Keyword(s):  
Electrochemical Reduction ◽  
Energy Efficient ◽  
Three Dimensional ◽  
Iron Porphyrin ◽  
Highly Efficient ◽  
Low Overpotential ◽  
Reduction Of Co2

A 3D iron porphyrin/graphene hydrogel electrocatalyst affords highly efficient, durable and selective CO2 reduction to CO at a low overpotential.

Graphene Supported Tungsten Carbide as Catalyst for Electrochemical Reduction of CO2

2019 ◽  
Author(s):  
Sahithi Ananthaneni ◽  
Rees Rankin
Keyword(s):  
Tungsten Carbide ◽  
Electrochemical Reduction ◽  
Low Cost ◽  
Co2 Reduction ◽  
Platinum Group Metal ◽  
Reduction Reaction ◽  
Metal Carbides ◽  
Depth Study ◽  
Reduction Of Co2 ◽  
Co2 Reduction Reaction

<div>Electrochemical reduction of CO2 to useful chemical and fuels in an energy efficient way is currently an expensive and inefficient process. Recently, low-cost transition metal-carbides (TMCs) are proven to exhibit similar electronic structure similarities to Platinum-Group-Metal (PGM) catalysts and hence can be good substitutes for some important reduction reactions. In this work, we test graphenesupported WC (Tungsten Carbide) nanocluster as an electrocatalyst for the CO2 reduction reaction. Specifically, we perform DFT studies to understand various possible reaction mechanisms and determine the lowest thermodynamic energy landscape of CO2 reduction to various products such as CO, HCOOH, CH3OH, and CH4. This in-depth study of reaction energetics could lead to improvements and develop more efficient electrocatalysts for CO2 reduction.<br></div>

Electrochemical Reduction of CO2 to CO in Organic Electrolyte with HCl Oxidized to Cl2 on Anode for Phosgene Synthesis

2021 ◽  
pp. 138728
Author(s):  
Chaojuan Li ◽  
Jin Shi ◽  
Jianxiong Liu ◽  
Yajian Duan ◽  
Yaxin Hua ◽  
...  
Keyword(s):  
Electrochemical Reduction ◽  
Organic Electrolyte ◽  
Reduction Of Co2
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