A Cr(salen)-based metal–organic framework as a versatile catalyst for efficient asymmetric transformations

2016 ◽  
Vol 52 (89) ◽  
pp. 13167-13170 ◽  
Author(s):  
Qingchun Xia ◽  
Yan Liu ◽  
Zijian Li ◽  
Wei Gong ◽  
Yong Cui
Keyword(s):  
Heterogeneous Catalyst ◽  
Metal Organic Framework ◽  
Diels Alder ◽  
Cyclization Reaction ◽  
Nazarov Cyclization ◽  
Asymmetric Transformations ◽  
Metal Organic ◽  
Organic Framework

A novel Cr(salen)-based metal–organic framework (MOF) is constructed, which is shown to be a versatile heterogeneous catalyst for a series of important asymmetric transformations including Nazarov cyclization reaction, aminolysis reaction, Diels–Alder and hetero Diels–Alder reactions with the highest ee up to 99%.

A new superacid hafnium-based metal–organic framework as a highly active heterogeneous catalyst for the synthesis of benzoxazoles under solvent-free conditions

2017 ◽  
Vol 7 (19) ◽  
pp. 4346-4350 ◽  
Author(s):  
Linh H. T. Nguyen ◽  
The T. Nguyen ◽  
Ha L. Nguyen ◽  
Tan L. H. Doan ◽  
Phuong Hoang Tran
Keyword(s):  
Heterogeneous Catalyst ◽  
Metal Organic Framework ◽  
Solvent Free ◽  
Highly Active ◽  
Solvent Free Conditions ◽  
Metal Organic ◽  
Efficient Heterogeneous Catalyst ◽  
Organic Framework

A new superacid Hf-based MOF, termed VNU-11-P-SO4, was used as an efficient heterogeneous catalyst for solvent-free 2-arylbenzoxazole synthesis.

Metal–organic framework mediated expeditious synthesis of benzimidazole and benzothiazole derivatives through an oxidative cyclization pathway

2020 ◽  
Vol 44 (3) ◽  
pp. 1021-1027
Author(s):  
Velayudham Sankar ◽  
Peramaiah Karthik ◽  
Bernaurdshaw Neppolian ◽  
Bitragunta Sivakumar
Keyword(s):  
Heterogeneous Catalyst ◽  
Good Yield ◽  
Metal Organic Framework ◽  
Oxidative Cyclization ◽  
Facile Synthesis ◽  
Benzothiazole Derivatives ◽  
Metal Organic ◽  
Organic Framework

Herein, we report facile synthesis of various benzimidazoles and benzothiazoles by using the NH2-MIL-125(Ti) MOF as an efficient oxidant-free heterogeneous catalyst with good yield.

scholarly journals Sulfonic acid functionalized metal–organic framework (S-IRMOF-3): a novel catalyst for sustainable approach towards the synthesis of acrylonitriles

RSC Advances ◽  
2019 ◽  
Vol 9 (28) ◽  
pp. 15749-15762 ◽  
Author(s):  
Ryhan Abdullah Rather ◽  
Zeba N. Siddiqui
Keyword(s):  
Reaction Time ◽  
Heterogeneous Catalyst ◽  
Sulfonic Acid ◽  
Metal Organic Framework ◽  
High Yield ◽  
Time Period ◽  
Metal Organic ◽  
Novel Catalyst ◽  
Efficient Heterogeneous Catalyst ◽  
Organic Framework

Sulfonic acid functionalized metal–organic framework (S-IRMOF-3) as an efficient heterogeneous catalyst has been synthesized and employed for sustainable approach towards the synthesis of acrylonitriles in high yield and shorter reaction time period.

scholarly journals Copper-catalyzed one-pot domino reactions via C–H bond activation: synthesis of 3-aroylquinolines from 2-aminobenzylalcohols and propiophenones under metal–organic framework catalysis

RSC Advances ◽  
2018 ◽  
Vol 8 (55) ◽  
pp. 31455-31464 ◽  
Author(s):  
Ha V. Dang ◽  
Hoang T. B. Le ◽  
Loan T. B. Tran ◽  
Hiep Q. Ha ◽  
Ha V. Le ◽  
...  
Keyword(s):  
Heterogeneous Catalyst ◽  
Bond Activation ◽  
Metal Organic Framework ◽  
Domino Reactions ◽  
One Pot ◽  
Metal Organic ◽  
Organic Framework

Cu2(OBA)2(BPY) metal–organic framework was utilized as a productive heterogeneous catalyst for the synthesis of 3-aroylquinolines via one-pot domino reactions of 2-aminobenzylalcohols with propiophenones.

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