Aminotroponiminates as tunable, redox-active ligands: reversible single electron transfer and reductive dimerisation

2016 ◽  
Vol 52 (65) ◽  
pp. 10044-10047 ◽  
Author(s):  
C. Lichtenberg ◽  
I. Krummenacher
Keyword(s):  
Electron Transfer ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Redox Active Ligands ◽  
Redox Active

Aminotroponiminates are shown to be redox-active ligands with their properties being tunable by choice of the ligand-bound metal.

scholarly journals Intramolecular Redox-Active Ligand-to-Substrate Single-Electron Transfer: Radical Reactivity with a Palladium(II) Complex

2014 ◽  
Vol 136 (33) ◽  
pp. 11574-11577 ◽  
Author(s):  
Daniël L. J. Broere ◽  
Bas de Bruin ◽  
Joost N. H. Reek ◽  
Martin Lutz ◽  
Sebastian Dechert ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Radical Reactivity ◽  
Redox Active Ligand ◽  
Active Ligand ◽  
Redox Active

Reversal of Polarity by Catalytic SET Oxidation: Synthesis of Azabicyclo[m.n.o]alkanes via Chemoselective Reduction of Amidines

2021 ◽  
Author(s):  
Sundarababu Baskaran ◽  
Kirana D V ◽  
Kanak Kanti Das
Keyword(s):  
Electron Transfer ◽  
Stereoselective Synthesis ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Catalytic Method ◽  
One Pot ◽  
Oxidative System ◽  
Oxidation Synthesis

A one-pot catalytic method has been developed for the stereoselective synthesis of cyclopropane-fused cyclic amidines using CuBr2/K2S2O8 as an efficient single electron transfer (SET) oxidative system. The generality of this...

Evidence for single electron transfer in the reaction of alkoxides with alkyl halides

1984 ◽  
Vol 25 (45) ◽  
pp. 5107-5110 ◽  
Author(s):  
E.C. Ashby ◽  
Dong-Hak Bae ◽  
Won-Suh Park ◽  
Robert N. Depriest ◽  
Wei-Yang Su
Keyword(s):  
Electron Transfer ◽  
Alkyl Halides ◽  
Single Electron ◽  
Single Electron Transfer
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