Tuning cation-binding selectivity and capacity via side chain-dependent molecular packing in the solid state

2016 ◽  
Vol 52 (68) ◽  
pp. 10361-10364 ◽  
Author(s):  
Jie Shen ◽  
Changliang Ren ◽  
Huaqiang Zeng
Keyword(s):  
Solid State ◽  
Molecular Packing ◽  
Cation Binding ◽  
Side Chain ◽  
Binding Selectivity ◽  
Selectivity And Capacity

Cavity-containing macrocycles assemble, via side chain-dependent molecular packing, into various nanostructures able to bind cations in varying selectivities and capacities.

Synthesis and solid state structures of macromolecular cylindrical brushes with varying side chain length

Polymer ◽  
2004 ◽  
Vol 45 (12) ◽  
pp. 4009-4015 ◽  
Author(s):  
Bin Zhang ◽  
Shanju Zhang ◽  
Lidia Okrasa ◽  
Tadeusz Pakula ◽  
Tim Stephan ◽  
...  
Keyword(s):  
Solid State ◽  
Chain Length ◽  
Side Chain ◽  
Side Chain Length ◽  
Solid State Structures

Thermosetting Mechanism Study of Organosilicon Polymer Containing Carborane by Solid-State NMR Spectroscopy

1999 ◽  
Vol 576 ◽  
Author(s):  
H. Kimura ◽  
K. Okita ◽  
M. Ichitani ◽  
M. Yonezawa ◽  
T. Sugimoto
Keyword(s):  
Solid State ◽  
Solid State Nmr ◽  
Nmr Spectra ◽  
Main Chain ◽  
Addition Reaction ◽  
Side Chain ◽  
Mechanism Study ◽  
Nmr Method ◽  
Organosilicon Polymer ◽  
Thermal Stable

ABSTRACTThe thermosetting mechanism of an organosilicon polymer containing carborane has been studied utilizing the 13and 29Si solid-state NMR method. The polymer having C≡C bonds in the main chain and CH═CH2, Si-H bonds, and carborane in the bulky side chain, shows a very highly thermal stability in air by curing. From 13C and 29Si NMR spectra of the polymer, it was found that the intermolecular cross-linking reactions of the polymer was due to (1) the diene reaction between Ph-C≡C and C≡C and (2) the addition reaction between side chain terminal and Ph-C≡C and between CH═CH2 and Si–H, and a very highly thermal stable structure is formed.

scholarly journals Corrigendum: Solid-State NMR Measurements of Asymmetric Dipolar Couplings Provide Insight into Protein Side-Chain Motion

2012 ◽  
Vol 51 (40) ◽  
pp. 9959-9959
Author(s):  
Paul Schanda ◽  
Matthias Huber ◽  
Jérôme Boisbouvier ◽  
Beat H. Meier ◽  
Matthias Ernst
Keyword(s):  
Solid State ◽  
Solid State Nmr ◽  
Dipolar Couplings ◽  
Side Chain ◽  
Side Chain Motion ◽  
Insight Into

scholarly journals Molecular packing and morphological stability of dihydro-indeno[1,2-b]fluorenes in the context of their substitution pattern

RSC Advances ◽  
2017 ◽  
Vol 7 (75) ◽  
pp. 47183-47189 ◽  
Author(s):  
M. Hempe ◽  
M. Reggelin
Keyword(s):  
Structural Characterization ◽  
Molecular Packing ◽  
Side Chain ◽  
Morphological Stability ◽  
Substitution Pattern

The synthesis and structural characterization of a series of dihydroindeno[1,2-b]fluorene (IF) derivatives with various side chain substituents is reported.

Impact of molecular packing rearrangement on solid-state fluorescence: polyhalogenated N-hetarylamines vs. their co-crystals with 18-crown-6

CrystEngComm ◽  
2019 ◽  
Vol 21 (39) ◽  
pp. 5931-5946 ◽  
Author(s):  
Tamara A. Vaganova ◽  
Yurij V. Gatilov ◽  
Enrico Benassi ◽  
Igor P. Chuikov ◽  
Denis P. Pishchur ◽  
...  
Keyword(s):  
Solid State ◽  
Chemical Structure ◽  
Crystal Packing ◽  
Molecular Packing ◽  
Solid State Fluorescence

Relationship between the hetarylamine chemical structure, crystal packing in homo- and co-crystals, and fluorescence effects (quenching, bathochromic and hypsochromic shifts).

scholarly journals Characterization of leucine side-chain reorientation in collagen-fibrils by solid-state 2H NMR.

1982 ◽  
Vol 79 (2) ◽  
pp. 386-389 ◽  
Author(s):  
L. S. Batchelder ◽  
C. E. Sullivan ◽  
L. W. Jelinski ◽  
D. A. Torchia
Keyword(s):  
Solid State ◽  
Collagen Fibrils ◽  
Side Chain ◽  
2H Nmr

Extractives of Australian timbers. X. Autoxidation and other reactions of the conjugated side-chain of eberlin lactone. Isolation of a new isomer of ebelin lactone

1970 ◽  
Vol 23 (10) ◽  
pp. 2085 ◽  
Author(s):  
RA Eade ◽  
J Ellis ◽  
JS Shannon ◽  
HV Simes ◽  
JJH Simes
Keyword(s):  
Double Bond ◽  
Solid State ◽  
Osmium Tetroxide ◽  
Side Chain ◽  
Methyl Groups ◽  
Stepwise Manner ◽  
Terminal Double Bond ◽  
Conjugated Triene

The conjugated triene side-chain of ebelin lactone has been degraded in a stepwise manner using osmium tetroxide. A new isomer of ebelin lactone has been isolated from the sapogenin mixture and has been assigned the structure (9) in which the 25(26) double bond has the cis configuration. Autoxidation of ebelin lactone in the solid state yields a mixture from which three compounds have been isolated and identified; all three arise from oxidation of the side-chain at the terminal double bond and methyl groups.

Synthesis and cation binding ability of azacrown ethers with phosphine or phosphine oxide side chain

1999 ◽  
Vol 10 (7) ◽  
pp. 573-576 ◽  
Author(s):  
Gy�rgy Keglevich ◽  
Tibor Nov�k ◽  
T�mea Imre ◽  
P�ter Bak� ◽  
L�szl� T?ke ◽  
...  
Keyword(s):  
Phosphine Oxide ◽  
Cation Binding ◽  
Side Chain ◽  
Binding Ability ◽  
Azacrown Ethers
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