Exploring substrate scope and stereoselectivity of P450 peroxygenase OleTJEin olefin-forming oxidative decarboxylation

2016 ◽  
Vol 52 (52) ◽  
pp. 8131-8133 ◽  
Author(s):  
Jian-bo Wang ◽  
Richard Lonsdale ◽  
Manfred T. Reetz
Keyword(s):  
Carboxylic Acids ◽  
Oxidative Decarboxylation ◽  
Straight Chain

The substrate scope of the mild olefin-forming oxidative decarboxylation of straight-chain C4–C22carboxylic acids catalyzed by P450 peroxygenase OleTJEhas been extended to include structurally diverse carboxylic acids.

ChemInform Abstract: Iodosobenzene Diacetate, an Efficient Reagent for the Oxidative Decarboxylation of Carboxylic Acids.

1986 ◽  
Vol 17 (34) ◽  
Author(s):  
J. I. CONCEPCION ◽  
C. G. FRANCISCO ◽  
R. FREIRE ◽  
R. HERNANDEZ ◽  
J. A. SALAZAR ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Oxidative Decarboxylation ◽  
Efficient Reagent

Oxidative decarboxylation of the 3-methyl-2-carboxynorbornanes with lead tetraacetate

1976 ◽  
Vol 54 (8) ◽  
pp. 1222-1225 ◽  
Author(s):  
J. B. Stothers ◽  
K. C. Teo
Keyword(s):  
Carboxylic Acids ◽  
Lead Tetraacetate ◽  
Starting Material ◽  
Oxidative Decarboxylation ◽  
Methyl Group

The mixtures of isomeric acetates produced by oxidative decarboxylation of the four 3-methyl-norbornane-2-carboxylic acids with lead tetraacetate in benzene have been characterized. The composition of these products depends primarily on the configuration of the methyl group in the starting material. The results are compared with those found for the Pb(OAc)4 decarboxylation of the norbornane-, bornane-, and 2,3,3-trimethylnorbornane-2-carboxylic acids. The formation of the products is interpreted in terms of competitive cationic and SNi substitution.

Oxidative decarboxylation of carboxylic acids by pyridine N-oxide

1967 ◽  
Vol 89 (19) ◽  
pp. 4968-4975 ◽  
Author(s):  
Theodore. Cohen ◽  
Il Hwan. Song ◽  
John H. Fager ◽  
Gary L. Deets
Keyword(s):  
Carboxylic Acids ◽  
Oxidative Decarboxylation
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