scholarly journals Mixed-linker approach in designing porous zirconium-based metal–organic frameworks with high hydrogen storage capacity

2016 ◽  
Vol 52 (50) ◽  
pp. 7826-7829 ◽  
Author(s):  
Ayesha Naeem ◽  
Valeska P. Ting ◽  
Ulrich Hintermair ◽  
Mi Tian ◽  
Richard Telford ◽  
...  

New zirconium based metal–organic framework (UBMOF-31) synthesised using mixed-linker strategy showing permanent porosity, excellent hydrogen uptake, and high selectivity for adsorption of CO2 over N2.

2018 ◽  
Vol 30 (22) ◽  
pp. 8179-8189 ◽  
Author(s):  
Matthew T. Kapelewski ◽  
Tomče Runčevski ◽  
Jacob D. Tarver ◽  
Henry Z. H. Jiang ◽  
Katherine E. Hurst ◽  
...  

2020 ◽  
Vol 10 (13) ◽  
pp. 4618
Author(s):  
Sesha Srinivasan ◽  
Dervis Emre Demirocak ◽  
Ajeet Kaushik ◽  
Meenu Sharma ◽  
Ganga Ram Chaudhary ◽  
...  

In the field of energy storage, recently investigated nanocomposites show promise in terms of high hydrogen uptake and release with enhancement in the reaction kinetics. Among several, carbonaceous nanovariants like carbon nanotubes (CNTs), fullerenes, and graphitic nanofibers reveal reversible hydrogen sorption characteristics at 77 K, due to their van der Waals interaction. The spillover mechanism combining Pd nanoparticles on the host metal-organic framework (MOF) show room temperature uptake of hydrogen. Metal or complex hydrides either in the nanocomposite form and its subset, nanocatalyst dispersed alloy phases illustrate the concept of nanoengineering and nanoconfinement of particles with tailor-made properties for reversible hydrogen storage. Another class of materials comprising polymeric nanostructures such as conducting polyaniline and their functionalized nanocomposites are versatile hydrogen storage materials because of their unique size, high specific surface-area, pore-volume, and bulk properties. The salient features of nanocomposite materials for reversible hydrogen storage are reviewed and discussed.


RSC Advances ◽  
2015 ◽  
Vol 5 (31) ◽  
pp. 24758-24768 ◽  
Author(s):  
Saeed Khoshhal ◽  
Ali Asghar Ghoreyshi ◽  
Mohsen Jahanshahi ◽  
Maedeh Mohammadi

A special MOF, Cu–BTC, was synthesized using ultrasonic and reflux condition technique. The effect of synthesis temperature and solvent ratio on the nanostructure and its hydrogen storage capacity was investigated.


2013 ◽  
Vol 13 (4) ◽  
pp. 2549-2556 ◽  
Author(s):  
Kuen-Song Lin ◽  
Abhijit Krishna Adhikari ◽  
Mu-Ting Tu ◽  
Chieh-Hung Wang ◽  
Chao-Lung Chiang

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