Asymmetric dual catalysis via fragmentation of a single rhodium precursor complex

2016 ◽  
Vol 52 (49) ◽  
pp. 7699-7702 ◽  
Author(s):  
Liangliang Song ◽  
Lei Gong ◽  
Eric Meggers
Keyword(s):  
Transition Metal ◽  
Transition Metal Catalysis ◽  
Rhodium Complex ◽  
Metal Catalysis ◽  
Precursor Complex ◽  
Dual Catalysis

A strategy for dual transition metal catalysis and organocatalysis is reported via disintegration of a single rhodium complex. Conveniently, the chiral-at-metal rhodium precatalyst can be synthesized in just two steps starting from rhodium trichloride without the need for any chromatography.

1.2.1 General Principles of Transition-Metal/Photocatalyst Dual Catalysis

2020 ◽  
Author(s):  
J. C. Tellis
Keyword(s):  
Transition Metal ◽  
Visible Light ◽  
Transition Metal Catalysis ◽  
Specific Role ◽  
Visible Light Photocatalysis ◽  
Metal Catalysis ◽  
Catalytic Transformations ◽  
Dual Catalysis

AbstractThe combination of transition-metal catalysis and visible-light photocatalysis offers opportunities for the development of unique new forms of reactivity. Presented in this chapter is an overview of the various strategies that can be used to design these dual catalytic transformations. Emphasis is placed on understanding the specific role that a photocatalyst can play in augmenting the reactivity of a substrate or cocatalyst to achieve otherwise challenging transformations.

ChemInform Abstract: Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis

ChemInform ◽  
2014 ◽  
Vol 45 (26) ◽  
pp. no-no
Author(s):  
Matthew N. Hopkinson ◽  
Basudev Sahoo ◽  
Jun-Long Li ◽  
Frank Glorius
Keyword(s):  
Transition Metal ◽  
Transition Metal Catalysis ◽  
Metal Catalysis ◽  
Dual Catalysis

C-H Bond Functionalization by Dual Catalysis: Merging of High-Valent Cobalt and Photoredox Catalysis

2021 ◽  
Author(s):  
Priyanka Chakraborty ◽  
Rajib Mandal ◽  
Soumen Paira ◽  
Basker Sundararaju
Keyword(s):  
Transition Metal ◽  
Transition Metal Catalysis ◽  
Low Energy ◽  
The Other ◽  
Photoredox Catalysis ◽  
Metal Catalysis ◽  
Bond Functionalization ◽  
Dual Catalysis ◽  
High Valent ◽  
Energy Pathways

The merger of transition metal catalysis and photocatalysis has emerged as a versatile platform which opened the gateway to diverse low energy pathways for several synthetic transformations. On the other...

Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis

2014 ◽  
Vol 20 (14) ◽  
pp. 3874-3886 ◽  
Author(s):  
Matthew N. Hopkinson ◽  
Basudev Sahoo ◽  
Jun-Long Li ◽  
Frank Glorius
Keyword(s):  
Transition Metal ◽  
Transition Metal Catalysis ◽  
Metal Catalysis ◽  
Dual Catalysis

Carbon‐Sulfur Bond Constructions: From Transition‐Metal Catalysis to Sustainable Catalysis

2021 ◽  
Author(s):  
Pratheepkumar Annamalai ◽  
Ke‐Chien Liu ◽  
Satpal Singh Badsara ◽  
Chin‐Fa Lee
Keyword(s):  
Transition Metal ◽  
Transition Metal Catalysis ◽  
Metal Catalysis ◽  
Sulfur Bond

An electrochemical perspective on the roles of ligands in the merger of transition-metal catalysis and electrochemistry

2020 ◽  
Author(s):  
Ke-Yin Ye ◽  
Jun-Song Zhong ◽  
Yi Yu ◽  
Zhaojiang Shi
Keyword(s):  
Transition Metal ◽  
Organic Synthesis ◽  
Transition Metal Catalysis ◽  
Metal Catalysis

The merger of transition-metal catalysis and electrochemistry has been emerging as a very versatile and robust synthetic tool in organic synthesis. Like in their non-electrochemical variants, ligands also play crucial...

Insertion Reaction of 2-Halo-N-allylanilines with K2S Involving Trisulfur Radical Anion: Synthesis of Benzothiazole Derivatives under Transition-Metal-Free Conditions

Synthesis ◽  
2020 ◽  
Author(s):  
Yan-Wei Zhao ◽  
Shun-Yi Wang ◽  
Xin-Yu Liu ◽  
Tian Jiang ◽  
Weidong Rao
Keyword(s):  
Transition Metal ◽  
Radical Anion ◽  
Radical Cyclization ◽  
Transition Metal Catalysis ◽  
Insertion Reaction ◽  
Metal Catalysis ◽  
Metal Free ◽  
Benzothiazole Derivatives

AbstractA synthesis of benzothiazole derivatives through the reaction of 2-halo-N-allylanilines with K2S in DMF is developed. The trisulfur radical anion S3·–, which is generated in situ from K2S in DMF, initiates the reaction without transition-metal catalysis or other additives. In addition, two C–S bonds are formed and heteroaromatization of benzothiazole is triggered by radical cyclization and H-shift.

scholarly journals Enamine/Transition Metal Combined Catalysis: Catalytic Transformations Involving Organometallic Electrophilic Intermediates

2019 ◽  
Vol 377 (6) ◽  
Author(s):  
Samson Afewerki ◽  
Armando Córdova
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Carbonyl Compounds ◽  
Transition Metal Catalysis ◽  
Chemical Transformations ◽  
Considerable Effort ◽  
Metal Catalysis ◽  
First Report ◽  
Wide Range ◽  
Selective Chemical

AbstractThe concept of merging enamine activation catalysis with transition metal catalysis is an important strategy, which allows for selective chemical transformations not accessible without this combination. The amine catalyst activates the carbonyl compounds through the formation of a reactive nucleophilic enamine intermediate and, in parallel, the transition metal activates a wide range of functionalities such as allylic substrates through the formation of reactive electrophilic π-allyl-metal complex. Since the first report of this strategy in 2006, considerable effort has been devoted to the successful advancement of this technology. In this chapter, these findings are highlighted and discussed.

Sign in / Sign up

Export Citation Format

Share Document