scholarly journals High viscosity to highly dispersed PtPd bimetallic nanocrystals for enhanced catalytic activity and stability

2016 ◽  
Vol 52 (53) ◽  
pp. 8219-8222 ◽  
Author(s):  
Jie Ying ◽  
Zhi-Yi Hu ◽  
Xiao-Yu Yang ◽  
Hao Wei ◽  
Yu-Xuan Xiao ◽  
...  

A facile high-viscosity-solvent method is developed to synthesize highly dispersed bimetallic PtPd nanocrystals with high activity, stability and durability.

2018 ◽  
Vol 2 (7) ◽  
pp. 1561-1573 ◽  
Author(s):  
Manjunath Chatti ◽  
Alexey M. Glushenkov ◽  
Thomas Gengenbach ◽  
Gregory P. Knowles ◽  
Tiago C. Mendes ◽  
...  

A rapid low-temperature microwave-assisted synthesis of nickel(iron) layered hydroxides and sulphides that exhibit robust catalytic activity for electrooxidation of alkaline water is introduced.


Nanoscale ◽  
2018 ◽  
Vol 10 (48) ◽  
pp. 22775-22786 ◽  
Author(s):  
Wenge Li ◽  
Yanjie Hu ◽  
Hao Jiang ◽  
Nan Jiang ◽  
Wei Bi ◽  
...  

Litchi-peel-like hierarchical hollow copper-ceria microspheres with highly dispersed CuOx and steps exhibit remarkable catalytic activity and stability for CO oxidation.


RSC Advances ◽  
2016 ◽  
Vol 6 (39) ◽  
pp. 32430-32433 ◽  
Author(s):  
Yuwen Yang ◽  
Yongyun Mao ◽  
Bin Wang ◽  
Xianwei Meng ◽  
Jiao Han ◽  
...  

A facile impregnation method has been successfully applied for synthesis of a cubical Co3O4 supported Au nanocomposites, which leads to the excellent catalytic activity for the reduction of 4-nitrophenol with a high turn over frequency of 9.83 min−1.


2008 ◽  
Vol 112 (32) ◽  
pp. 12092-12095 ◽  
Author(s):  
Yawen Zhang ◽  
Wenyu Huang ◽  
Susan E. Habas ◽  
John N. Kuhn ◽  
Michael E. Grass ◽  
...  

Nanoscale ◽  
2018 ◽  
Vol 10 (26) ◽  
pp. 12487-12496 ◽  
Author(s):  
Haichao Duan ◽  
Yu Yang ◽  
Jianhua Lü ◽  
Changli Lü

We report a facile, mussel-inspired construction of a thermo-responsive diblock copolymer-anchored rGO support for superfine PdNPs with high catalytic activity.


Catalysts ◽  
2018 ◽  
Vol 8 (4) ◽  
pp. 141 ◽  
Author(s):  
Vladimir Mikhaylov ◽  
Viktor Sorokoumov ◽  
Denis Liakhov ◽  
Alexander Tskhovrebov ◽  
Irina Balova

Two types of immobilized on the amino-functionalized polystyrene-supported acyclic diaminocarbene palladium complexes (ADC-PdII) are investigated under Sonogashira cross-coupling conditions. Depending on substituents in the diaminocarbene fragment immobilized ADC-PdII, systems are found to have different catalytic activity and stability regarding Pd-leaching. PdII-diaminocarbenes possessing protons at both nitrogen atoms smoothly decompose into Pd0-containing species providing a catalytic “cocktail system” with high activity and ability to reuse within nine runs. Polymer-supported palladium (II) complex bearing NBn–Ccarbene–NH-moiety exhibits greater stability while noticeably lower activity under Sonogashira cross-coupling. Four molecular ADC-PdII complexes are also synthesized and investigated with the aim of confirming proposed base-promoted pathway of ADC-PdII conversion through carbodiimide into an active Pd0 forms.


2021 ◽  
Author(s):  
Zhanke Wang ◽  
Lei Ge ◽  
Guangxu Zhang ◽  
Rongrong Gao ◽  
Hao Wang ◽  
...  

A novel dissolution-crystallization strategy was developed to synthesize urchin-like superstructure metal-organic frameworks (MOFs) with self-assembled 1D nanorods. The superstructure MOFs not only inherit the high activity of nano-sized MOFs but...


2021 ◽  
Author(s):  
Cui Wang ◽  
Shuguang Shen ◽  
Yehui Li ◽  
Huajie Pan ◽  
Zijian Zhou ◽  
...  

High activity hyper-crosslinked polymer solid acids (HCPSAs) were prepared from different aromatic monomers, the structure of which was regulated by selecting the type and size of aromatic monomers. The results...


2020 ◽  
Vol 8 (2) ◽  
pp. 632-638 ◽  
Author(s):  
Xi Lin ◽  
He Wen ◽  
Deng-Xue Zhang ◽  
Guo-Xuan Cao ◽  
Ping Wang

Tiny Ni3N nanoparticles dispersed on Ni nanosheets exhibit an impressively high activity towards N2H4 electrooxidation.


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