Enhanced charge separation of rutile TiO2 nanorods by trapping holes and transferring electrons for efficient cocatalyst-free photocatalytic conversion of CO2 to fuels

2016 ◽  
Vol 52 (28) ◽  
pp. 5027-5029 ◽  
Author(s):  
Jing Wu ◽  
Hongwei Lu ◽  
Xuliang Zhang ◽  
Fazal Raziq ◽  
Yang Qu ◽  
...  

Modification with anions and coupling with CNTs could promote the charge separation of rutile so as to improve the cocatalyst-free photocatalytic conversion of CO2 to fuels.

2015 ◽  
Vol 17 (24) ◽  
pp. 15837-15842 ◽  
Author(s):  
Jing Wu ◽  
Haiqin Cui ◽  
Xuliang Zhang ◽  
Yunbo Luan ◽  
Liqiang Jing

Targeted co-modification promotes the capture of electrons by adsorbed O2, leading to increased charge separation and enhanced photocatalytic activities.


Nanoscale ◽  
2021 ◽  
Author(s):  
Bing Fu ◽  
Zhijiao Wu ◽  
Kai Guo ◽  
Lingyu Piao

Owing to their scientific and technological importance, the development of highly efficient photocatalytic water oxidation systems with rapid photogenerated charge separation and high surface catalytic activity has highly desirable for...


2009 ◽  
Vol 113 (32) ◽  
pp. 14567-14574 ◽  
Author(s):  
M. Vijayakumar ◽  
Sebastien Kerisit ◽  
Chongmin Wang ◽  
Zimin Nie ◽  
Kevin M. Rosso ◽  
...  

2013 ◽  
Vol 59 ◽  
pp. 187-195 ◽  
Author(s):  
Dong-Sheng Li ◽  
Jian-Biao Chen ◽  
Cheng-Wei Wang ◽  
Wei-Dong Zhu ◽  
Ling Zhang ◽  
...  

Nanomaterials ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 683 ◽  
Author(s):  
Cheng Gong ◽  
Jun Du ◽  
Xiuyun Li ◽  
Zhenjie Yu ◽  
Jiansong Ma ◽  
...  

Three-dimensional and dendritic rutile TiO2 nanorods were successfully fabricated on a Ti foil surface using a one-step acidic hydrothermal method. The TiO2 nanorods were characterized using X-ray diffraction (XRD), energy dispersive X-ray spectrometry (EDX), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and optical contact angle testing. The results showed that the nanorods with diameters of 100–500 nm and lengths of 100 nm to 1 μm were obtained on the Ti foil surface. The length and density of the TiO2 nanorods were perfect at the conditions of HCl concentration 0.5 mol/L, temperature 220 °C, and reaction time 12 h. The TiO2 nanorods formed parallel to the consumption of Ti and grew along the (110) direction having a tetragonal rutile crystal. The morphology of the nanorods possessed a three-dimensional structure. The contact angle of the nanorods was only 13 ± 3.1°. Meanwhile, the photocatalytic activities of the TiO2 nanorods were carried out using ultraviolet fluorescence spectrophotometry for the methyl orange detection, and the degradation was found to be about 71.00% ± 2.43%. Thus, TiO2 nanorods can be developed by a one-step acidic hydrothermal method using Ti foil simultaneously as the substrate with a TiO2 source; the TiO2 nanorods exhibited photocatalytic performance while being environment-friendly.


2020 ◽  
Vol 49 (42) ◽  
pp. 15054-15060
Author(s):  
Qimeng Yang ◽  
Heng Zhu ◽  
Yanghui Hou ◽  
Duanduan Liu ◽  
Huang Tang ◽  
...  

Polaron states on single-crystal TiO2 photoanodes provide an important electron transfer pathway at the electrode–electrolyte interface.


Nanoscale ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 5685-5685
Author(s):  
Bing Fu ◽  
Zhijiao Wu ◽  
Shuang Cao ◽  
Kai Guo ◽  
Lingyu Piao

Correction for ‘Effect of aspect ratios of rutile TiO2 nanorods on overall photocatalytic water splitting performance’ by Bing Fu et al., Nanoscale, 2020, DOI: 10.1039/c9nr10870j.


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