A new type of surface-enhanced Raman scattering sensor for the enantioselective recognition of d/l-cysteine and d/l-asparagine based on a helically arranged Ag NPs@homochiral MOF

2016 ◽  
Vol 52 (31) ◽  
pp. 5432-5435 ◽  
Author(s):  
Xuan Kuang ◽  
Sujuan Ye ◽  
Xiangyuan Li ◽  
Yu Ma ◽  
Caiyun Zhang ◽  
...  
Keyword(s):  
Raman Scattering ◽  
Helical Structure ◽  
Ag Nps ◽  
Enantioselective Recognition ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
New Type ◽  
Enhanced Raman Scattering ◽  
First Time ◽  
Efficient Recognition

For the first time, we report the synthesis of Ag NPs arranged in a helical structure on a chiral MOF. This material can serve as a new type of SERS sensor for the efficient recognition of enantiomers.

A simple enzyme-free SERS sensor for the rapid and sensitive detection of hydrogen peroxide in food

The Analyst ◽  
2020 ◽  
Vol 145 (2) ◽  
pp. 607-612 ◽  
Author(s):  
Yangyang Li ◽  
Yuqiu Wang ◽  
Cuicui Fu ◽  
Yan Wu ◽  
Haiyan Cao ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Silver Nanoparticles ◽  
Raman Scattering ◽  
Glass Substrate ◽  
Sensitive Detection ◽  
Ag Nps ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering ◽  
First Time

A simple enzyme-free method based on surface-enhanced Raman scattering (SERS) was developed for the first time to detect H2O2 in food by etching a self-assembled film of silver nanoparticles (Ag NPs) on a glass substrate.

scholarly journals Large-Scale Fabrication of Ultrasensitive and Uniform Surface-Enhanced Raman Scattering Substrates for the Trace Detection of Pesticides

Nanomaterials ◽  
2018 ◽  
Vol 8 (7) ◽  
pp. 520 ◽  
Author(s):  
Jia Zhu ◽  
Guanzhou Lin ◽  
Meizhang Wu ◽  
Zhuojie Chen ◽  
Peimin Lu ◽  
...  
Keyword(s):  
Raman Scattering ◽  
Large Scale ◽  
Capillary Flow ◽  
Surface Enhanced Raman Scattering ◽  
Ag Nps ◽  
Uniform Size ◽  
Sers Substrates ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

Technology transfer from laboratory into practical application needs to meet the demands of economic viability and operational simplicity. This paper reports a simple and convenient strategy to fabricate large-scale and ultrasensitive surface-enhanced Raman scattering (SERS) substrates. In this strategy, no toxic chemicals or sophisticated instruments are required to fabricate the SERS substrates. On one hand, Ag nanoparticles (NPs) with relatively uniform size were synthesized using the modified Tollens method, which employs an ultra-low concentration of Ag+ and excessive amounts of glucose as a reducing agent. On the other hand, when a drop of the colloidal Ag NPs dries on a horizontal solid surface, the droplet becomes ropy, turns into a layered structure under gravity, and hardens. During evaporation, capillary flow was burdened by viscidity resistance from the ropy glucose solution. Thus, the coffee-ring effect is eliminated, leading to a uniform deposition of Ag NPs. With this method, flat Ag NPs-based SERS active films were formed in array-well plates defined by hole-shaped polydimethylsiloxane (PDMS) structures bonded on glass substrates, which were made for convenient detection. The strong SERS activity of these substrates allowed us to reach detection limits down to 10−14 M of Rhodamine 6 G and 10−10 M of thiram (pesticide).

scholarly journals Fabrication and Characterization of a Highly-Sensitive Surface-Enhanced Raman Scattering Nanosensor for Detecting Glucose in Urine

Nanomaterials ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 629 ◽  
Author(s):  
Yudong Lu ◽  
Ting Zhou ◽  
Ruiyun You ◽  
Yang Wu ◽  
Huiying Shen ◽  
...  
Keyword(s):  
Raman Scattering ◽  
Internal Standard ◽  
Surface Enhanced Raman Scattering ◽  
Quantitative Detection ◽  
Core Shell ◽  
Ag Nps ◽  
Vis Spectroscopy ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

Herein we utilized coordination interactions to prepare a novel core-shell plasmonic nanosensor for the detection of glucose. Specifically, Au nanoparticles (NPs) were strongly linked with Ag+ ions to form a sacrificial Ag shell by using 4-aminothiophenol (4-PATP) as a mediator, which served as an internal standard to decrease the influence of the surrounding on the detection. The resultant Au-PATP-Ag core-shell systems were characterized by UV-vis spectroscopy, transmission electron microscopy, and surface-enhanced Raman scattering (SERS) techniques. Experiments performed with R6G (rhodamine 6G) and CV (crystal violet) as Raman reporters demonstrated that the Au@Ag nanostructure amplified SERS signals obviously. Subsequently, the Au@Ag NPs were decorated with 4-mercaptophenylboronic acid (4-MPBA) to specifically recognize glucose by esterification, and a detection limit as low as 10−4 M was achieved. Notably, an enhanced linearity for the quantitative detection of glucose (R2 = 0.995) was obtained after the normalization of the spectral peaks using 4-PATP as the internal standard. Finally, the practical applicability of the developed sensing platform was demonstrated by the detection of glucose in urine with acceptable specificity.

Surface-enhanced Raman scattering on organic–inorganic hybrid perovskites

2018 ◽  
Vol 54 (17) ◽  
pp. 2134-2137 ◽  
Author(s):  
Xiaoyue Su ◽  
Hao Ma ◽  
He Wang ◽  
Xueliang Li ◽  
Xiao Xia Han ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Raman Scattering ◽  
Surface Enhanced Raman Scattering ◽  
Inorganic Hybrid ◽  
Enhancement Mechanism ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering ◽  
First Time

For the first time SERS on organic–inorganic hybrid perovskites is explored. The enhancement mechanism is discussed according to charge transfer.

A surface-enhanced Raman scattering active core/shell structure based on enzyme-guided crystal growth for bisphenol A detection

2018 ◽  
Vol 10 (31) ◽  
pp. 3878-3883 ◽  
Author(s):  
Zhou Xu ◽  
Rong Wang ◽  
Bo Mei ◽  
Li Ding ◽  
Libing Wang ◽  
...  
Keyword(s):  
Crystal Growth ◽  
Raman Scattering ◽  
Surface Enhanced Raman Scattering ◽  
Active Core ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Sers Detection ◽  
Enhanced Raman Scattering ◽  
Bisphenol A Detection ◽  
First Time

Herein, a universal surface-enhanced Raman scattering (SERS) detection platform based on enzyme-guided crystal growth has been fabricated for the first time.

Local Electric Field Enhancement of Neighboring Ag Nanoparticles in Surface Enhanced Raman Scattering

2013 ◽  
Vol 760-762 ◽  
pp. 801-805 ◽  
Author(s):  
Chao Yue Deng ◽  
Gu Ling Zhang ◽  
Bin Zou ◽  
Hong Long Shi ◽  
Yu Jie Liang ◽  
...  
Keyword(s):  
Electric Field ◽  
Raman Scattering ◽  
Electric Fields ◽  
Ag Nanoparticles ◽  
Surface Enhanced Raman Scattering ◽  
Ag Nps ◽  
Sers Enhancement ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

We used a simple low-temperature hydrothermal approach to synthesize Ag nanoparticles (NPs) and demonstrated their efficiency as organic molecule detectors in surface enhanced Raman Scattering (SERS). Using finite difference time domain simulation, we described an investigation on the distribution of electric fields amplitude of the neighboring Ag NPs. The enhanced electric field is confined at the interparticle gaps and the enhancement factor can be further increased with reducing the spacing between the NPs. The theoretical simulation demonstrated good consistency with the experimental measurement results, which predicts an electric fields amplitude enhancement of 115 at the center of NPs gap and an electromagnetic SERS enhancement of 108. The evidence of clear correlations between SERS enhancement and morphology distribution offer a route to develop more effective SERS substrates.

Rapid fabrication of self-assembled interfacial film decorated filter paper as an excellent surface-enhanced Raman scattering substrate

2014 ◽  
Vol 6 (24) ◽  
pp. 9547-9553 ◽  
Author(s):  
Wu-Li-Ji Hasi ◽  
Shuang Lin ◽  
Xiang Lin ◽  
Xiu-Tao Lou ◽  
Fang Yang ◽  
...  
Keyword(s):  
Raman Scattering ◽  
Filter Paper ◽  
Surface Enhanced Raman Scattering ◽  
Sers Substrate ◽  
Ag Nps ◽  
Interfacial Film ◽  
Rapid Fabrication ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

The fabrication of this paper-based SERS substrate is facile and rapid (<10 min). The coverage rate of Ag NPs is relatively high.

scholarly journals Bulk plasmon polariton in hyperbolic metamaterials excited by multilayer nanoparticles for surface-enhanced Raman scattering (SERS) sensing

Nanophotonics ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Runcheng Liu ◽  
Zhipeng Zha ◽  
Muhammad Shafi ◽  
Can Li ◽  
Wen Yang ◽  
...  
Keyword(s):  
Raman Scattering ◽  
Resonance Peak ◽  
Ag Nps ◽  
Large Wave ◽  
Hyperbolic Metamaterials ◽  
Bulk Plasmon ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering ◽  
Plasmon Polariton

Abstract The capability to support large wave vector bulk plasmon polariton (BPP) waves enables the application of hyperbolic metamaterials (HMMs) in sensing. However, there is a challenge arising from the excitation of BPP, and the highly confined polarization waves are unable to meet the requirements of practical application. In this study, an HMM/bilayer silver nanoparticles (Ag NPs) platform is proposed that allows the excitation and utilization of BPP for use as a surface-enhanced Raman scattering (SERS) substrate. According to the research results, the bilayer Ag NPs provide stronger plasmonic property and act as a light-matter coupler, so as to generate a large wave vector of scattered light and excite the BPP within the HMM. Besides, Ag NPs provide the nano antenna structure, and decouple the BPP into localized surface plasmon (LSP) that can be used directly to excite the electric fields. In addition, HMM produces a modulating effect on the plasmon resonance peak, which makes it possible to overlap the spectrum of resonance peak with excitation wavelengths, thus leading to a strong absorption peak at the incident laser wavelength region. Experimentally, the platform was applied to achieve SERS detection for adenosine molecules with a concentration of 10−6 M. It is believed that this plasmonic platform has a potential of application in surface-enhanced spectroscopy.

Ultra sensitive surface-enhanced Raman scattering detection based on monolithic column as a new type substrate

2012 ◽  
Vol 43 (10) ◽  
pp. 1392-1396 ◽  
Author(s):  
Qingqing Li ◽  
Yiping Du ◽  
Huirong Tang ◽  
Xuan Wang ◽  
Guiping Chen ◽  
...  
Keyword(s):  
Raman Scattering ◽  
Monolithic Column ◽  
Surface Enhanced Raman Scattering ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
New Type ◽  
Enhanced Raman Scattering
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