Novel synthesis of chitosan protected platinum nanoparticles based on gas–liquid interfacial reactions and their application for electrochemical sensing of hydrogen peroxide

2016 ◽  
Vol 8 (44) ◽  
pp. 7903-7909 ◽  
Author(s):  
Jianbo Liu ◽  
Wushuang Bai ◽  
Juncai Zhang ◽  
Jianbin Zheng

A gas–liquid reaction was proposed for the controllable synthesis of Pt nanoparticles, which exhibited uniform morphology without any aggregation.

RSC Advances ◽  
2016 ◽  
Vol 6 (58) ◽  
pp. 52739-52745 ◽  
Author(s):  
Dongmei Lin ◽  
Yang Li ◽  
Panpan Zhang ◽  
Wensi Zhang ◽  
Junwei Ding ◽  
...  

MoS2 nanoflowers decorated with Pt nanoparticles show enhanced performances for electrochemical H2O2 sensing.


2014 ◽  
Vol 68 (4) ◽  
Author(s):  
Guang Yin ◽  
Ling Xing ◽  
Xiu-Ju Ma ◽  
Jun Wan

AbstractA novel non-enzymatic electrochemical sensor based on a nanoporous gold electrode modified with platinum nanoparticles was constructed for the determination of hydrogen peroxide (H2O2). Platinum nanoparticles exhibit good electrocatalytic activity towards hydrogen peroxide. The nanoporous gold (NPG) increases the effective surface area and has the capacity to promote electron-transfer reactions. With electrodeposition of Pt nanoparticles (NPs) on the surface of the nanoporous gold, the modified Au electrode afforded a fast, sensitive and selective electrochemical method for the determination of H2O2. The linear range for the detection of H2O2 was from 1.0 × 10−7 M to 2.0 × 10−5 M while the calculated limit of detection was 7.2 × 10−8 M on the basis of the 3σ/slope (σ represents the standard deviation of the blank samples). These findings could lead to the widespread use of electrochemical sensors to detect H2O2.


2015 ◽  
Vol 2015 ◽  
pp. 1-7 ◽  
Author(s):  
Chia-Liang Sun ◽  
Jheng-Sin Su ◽  
Shun-Yi Lai ◽  
Yu-Jen Lu

The electrochemical detection of hydrogen peroxide (H2O2) has attracted much attention recently. Meanwhile, the size of nanoparticles which significantly influences electrocatalytic activity is crucial for electrocatalysts. Hence, we prepared five different size-selected Pt/graphene-modified glassy carbon (GC) electrodes to characterize H2O2level via electrochemical measurements. During the preparation of the nanocomposites, size-selected Pt nanoparticles (NPs) with the mean diameter of 1.3, 1.7, 2.9, and 4.3 nm were assembled onto the graphene surfaces. The electrochemical measurement results are size-dependent for Pt NPs when sensing H2O2. When all cyclic voltammogram results from various electrodes are compared, the Pt-1.7 nm/G-modified GC electrode has the highest reduction current, the best detection limit, and the best sensitivity.


RSC Advances ◽  
2014 ◽  
Vol 4 (85) ◽  
pp. 45185-45190 ◽  
Author(s):  
Sijing He ◽  
Zuanguang Chen ◽  
Yanyan Yu ◽  
Lijuan Shi

Author(s):  
Jilin Zheng ◽  
Peng Zhao ◽  
Shiying Zhou ◽  
Sha Chen ◽  
Yi Liang ◽  
...  

Integrating metal-organic frameworks (MOFs) of different components or structures together and exploiting them as electrochemical sensors for electrochemical sensing have aroused great interest. And the incorporation of noble metals with...


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