Liquid–liquid extraction and separation of lead(ii) by using N-n-octylcyclohexylamine as an extractant: analysis of real samples

2016 ◽  
Vol 8 (32) ◽  
pp. 6158-6167 ◽  
Author(s):  
Arjun Kokare ◽  
Vishal Suryavanshi ◽  
Sunil Zanje ◽  
Gurupad Kore ◽  
Mansing Anuse

Herein, we have developed a solvent extraction system for lead(ii) with N-n-octylcyclohexylamine from HCl medium.

2017 ◽  
Vol 19 (32) ◽  
pp. 21304-21316 ◽  
Author(s):  
Mark R. Antonio ◽  
Ross J. Ellis ◽  
Shanna L. Estes ◽  
Mrinal K. Bera

Macroscopic phase behaviors in the liquid–liquid extraction are explained by microscopic, reverse micellar fluid structures containing tetranuclear Ce(iv) clusters revealed by use of X-ray spectroscopy and scattering of the light and dense organic phases.


2015 ◽  
Vol 7 (6) ◽  
pp. 2497-2504 ◽  
Author(s):  
Vishal J. Suryavanshi ◽  
Rupali R. Pawar ◽  
Mansing A. Anuse ◽  
Ganpatrao N. Mulik

2-Octylaminopyridine assisted solvent extraction for selective separation and quantification of palladium(ii) ion-pair complexes from synthetic/real samples is developed.


1983 ◽  
Vol 15 (6-7) ◽  
pp. 149-159 ◽  
Author(s):  
V C Blok ◽  
G P Slater ◽  
E M Giblin

Several commercially available adsorbents were compared with solvent extraction methods for their utility in recovering trace organics from water. The adsorbents examined included Amberlite XAD-2, XAD-4 and XAD-8, Ambersorb XE340 and XE348 and Tenax-GC. All were found to produce high artifact levels, even after extensive clean-up, making them unsuitable for the analysis of trace organics in water. Quantitatively, Likens-Nickerson or continuous liquid-liquid extraction with méthylene chloride gave better recoveries than the adsorbents. Qualitatively, extractive methods were preferred as they yielded much lower levels of impurities than the adsorbents. These methods of recovering trace organics were evaluated using a standard mixture of compounds added to the water at a level of 55 µg/l. Likens-Nickerson extraction gave comparable recoveries of this mixture at 55 µg/l and 11 µg/l.


1999 ◽  
Vol 23 (8) ◽  
pp. 518-519
Author(s):  
Francisco Jose Alguacil ◽  
Jaime Simpson ◽  
Patricio Navarro

A previously determined thermodynamic model for extraction equilibrium is used as a basis to predict experimentally measured distribution coefficients for the CuSO4–H2SO4–LIX 984–Escaid 103 solvent extraction system at 25 °C and aqueous copper concentrations in the range 0.01–2.0 gL−1, the copper loading isotherm is also obtained.


2013 ◽  
Vol 10 (3) ◽  
pp. 997-1004
Author(s):  
Baghdad Science Journal

Liquid-Liquid Extraction of Cu(II) ion in aqueous solution by dicyclohexyl-18-crown-6 as extractant in dichloroethane was studied .The extraction efficiency was investigated by a spectrophometric method. The reagent form a coloured complex which has been a quantitatively extracted at pH 6.3. The method obeys Beer`s law over range from (2.5-22.5) ppm with the correlation coefficient of 0.9989. The molar absorptivity the stoichiometry of extracted complex is found to be 1:2. the proposed method is very sensitive and selective.


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