Long wavelength AIEgen of quinoline-malononitrile

2016 ◽  
Vol 4 (14) ◽  
pp. 2640-2646 ◽  
Author(s):  
Zhiqian Guo ◽  
Andong Shao ◽  
Wei-Hong Zhu

In this Highlight, we summarize some recent advances in the area of red to near-infrared fluorescent AIE-active organic materials via tailoring the building block of quinoline-malononitrile (QM), and its application in bioimaging.

Author(s):  
Dorian Bader ◽  
Johannes Fröhlich ◽  
Paul Kautny

The facile preparation of three regioisomeric thienopyrrolocarbazoles applying a convenient C-H activation approach is presented. Derived from indolo[3,2,1-<i>jk</i>]carbazole, the incorporation of thiophene into the triarylamine framework significantly impacted the molecular properties of the parent scaffold. The developed thienopyrrolocarbazoles enrich the family of triarylamine donors and constitute a novel building block for functional organic materials.


2019 ◽  
Author(s):  
Dorian Bader ◽  
Johannes Fröhlich ◽  
Paul Kautny

The facile preparation of three regioisomeric thienopyrrolocarbazoles applying a convenient C-H activation approach is presented. Derived from indolo[3,2,1-<i>jk</i>]carbazole, the incorporation of thiophene into the triarylamine framework significantly impacted the molecular properties of the parent scaffold. The developed thienopyrrolocarbazoles enrich the family of triarylamine donors and constitute a novel building block for functional organic materials.


Author(s):  
Meng-Meng Su ◽  
Jia-Jia Kang ◽  
Shu-Qin Liu ◽  
Chang-Gong Meng ◽  
Yan-Qin Li ◽  
...  

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 58
Author(s):  
Sylwia Kostera ◽  
Maurizio Peruzzini ◽  
Luca Gonsalvi

The use of CO2 as a C1 building block for chemical synthesis is receiving growing attention, due to the potential of this simple molecule as an abundant and cheap renewable feedstock. Among the possible reductants used in the literature to bring about CO2 reduction to C1 derivatives, hydroboranes have found various applications, in the presence of suitable homogenous catalysts. The current minireview article summarizes the main results obtained since 2016 in the synthetic design of main group, first and second row transition metals for use as catalysts for CO2 hydroboration.


2018 ◽  
Vol 14 (S343) ◽  
pp. 456-457
Author(s):  
Foteini Lykou ◽  
Josef Hron ◽  
Daniela Klotz

AbstractRecent advances in high-angular resolution instruments (VLT and VLTI, ALMA) have enabled us to delve deep into the circumstellar envelopes of AGB stars from the optical to the sub-mm wavelengths, thus allowing us to study in detail the gas and dust formation zones (e.g., their geometry, chemistry and kinematics). This work focuses on four (4) C-rich AGB stars observed with a high-angular resolution technique in the near-infrared: a multi-wavelength tomographic study of the dusty layers of the circumstellar envelopes of these C-rich stars, i.e. the variations in the morphology and temperature distribution.


2018 ◽  
Vol 2018 ◽  
pp. 1-16 ◽  
Author(s):  
Claudia Invernizzi ◽  
Tommaso Rovetta ◽  
Maurizio Licchelli ◽  
Marco Malagodi

This study presents mid and near-infrared (7500-375 cm−1) total reflection mode spectra of several natural organic materials used in artworks as binding media, consolidants, adhesives, or protective coatings. A novel approach to describe and interpret reflectance bands as well as calculated absorbance after Kramers-Kronig transformation (KKT) is proposed. Transflection mode spectra have represented a valuable support both to study the distorted reflectance bands and to validate the applicability and usefulness of the KK correction. The aim of this paper is to make available to scientists and conservators a comprehensive infrared reflection spectral database, together with its detailed interpretation, as a tool for the noninvasive identification of proteins, lipids, polysaccharides, and resins by means of portable noncontact FTIR spectrometers.


Author(s):  
Jonathan B. Grimm ◽  
Ariana N. Tkachuk ◽  
Heejun Choi ◽  
Boaz Mohar ◽  
Natalie Falco ◽  
...  

ABSTRACTExpanding the palette of fluorescent dyes is vital for pushing the frontier of biological imaging. Although rhodamine dyes remain the premier type of small-molecule fluorophore due to their bioavailability and brightness, variants excited with far-red or near-infrared light suffer from poor performance due to their propensity to adopt a lipophilic, nonfluorescent form. We report a general chemical modification for rhodamines that optimizes long-wavelength variants and enables facile functionalization with different chemical groups.


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