Molecular engineering of starburst triarylamine donor with selenophene containing π-linker for dye-sensitized solar cells

2016 ◽  
Vol 4 (4) ◽  
pp. 713-726 ◽  
Author(s):  
Po-Yu Ho ◽  
Chi-Ho Siu ◽  
Wai-Hong Yu ◽  
Panwang Zhou ◽  
Tao Chen ◽  
...  

New starburst triarylamine donor with selenophene containing π-linker were synthesized. Such donor can minimize dye aggregation on TiO2 and slow down charge recombination kinetics in dye-sensitized solar cells.

2017 ◽  
Vol 50 ◽  
pp. 25-32 ◽  
Author(s):  
Telugu Bhim Raju ◽  
Jayraj V. Vaghasiya ◽  
Mohammad Adil Afroz ◽  
Saurabh S. Soni ◽  
Parameswar Krishnan Iyer

2017 ◽  
Vol 2 (2) ◽  
pp. 98-122 ◽  
Author(s):  
Xing Li ◽  
Xiaoyu Zhang ◽  
Jianli Hua ◽  
He Tian

The sensitizers witho,p-dialkoxyphenyl-based bulky donors can reduce the charge recombination and improve the performance of dye-sensitized solar cells (DSSCs).


Molecules ◽  
2020 ◽  
Vol 25 (19) ◽  
pp. 4478 ◽  
Author(s):  
Fang Xu ◽  
Thomas T. Testoff ◽  
Lichang Wang ◽  
Xueqin Zhou

As an important member of third generation solar cell, dye-sensitized solar cells (DSSCs) have the advantages of being low cost, having an easy fabrication process, utilizing rich raw materials and a high-power conversion efficiency (PCE), prompting nearly three decades as a research hotspot. Recently, increasing the photoelectric conversion efficiency of DSSCs has proven troublesome. Sensitizers, as the most important part, are no longer limited to molecular engineering, and the regulation of dye aggregation has become a widely held concern, especially in liquid DSSCs. This review first presents the operational mechanism of liquid and solid-state dye-sensitized solar cells, including the influencing factors of various parameters on device efficiency. Secondly, the mechanism of dye aggregation was explained by molecular exciton theory, and the influence of various factors on dye aggregation was summarized. We focused on a review of several methods for regulating dye aggregation in liquid and solid-state dye-sensitized solar cells, and the advantages and disadvantages of these methods were analyzed. In addition, the important application of quantum computational chemistry in the study of dye aggregation was introduced. Finally, an outlook was proposed that utilizing the advantages of dye aggregation by combining molecular engineering with dye aggregation regulation is a research direction to improve the performance of liquid DSSCs in the future. For solid-state dye-sensitized solar cells (ssDSSCs), the effects of solid electrolytes also need to be taken into account.


2019 ◽  
Vol 43 (17) ◽  
pp. 6480-6491 ◽  
Author(s):  
Narendra Nath Ghosh ◽  
Md. Habib ◽  
Anup Pramanik ◽  
Pranab Sarkar ◽  
Sougata Pal

Triazatruxene with designed anchoring groups provides better photovoltaic activities.


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