scholarly journals Properties modulation of organic semi-conductors based on a donor-spiro-acceptor (D-spiro-A) molecular design: new host materials for efficient sky-blue PhOLEDs

2015 ◽  
Vol 3 (37) ◽  
pp. 9701-9714 ◽  
Author(s):  
Maxime Romain ◽  
Denis Tondelier ◽  
Olivier Jeannin ◽  
Bernard Geffroy ◽  
Joëlle Rault-Berthelot ◽  
...  

Four high triplet organic semi-conductors based on the donor-spiro-acceptor design (D-spiro-A) have been synthesized.

Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4615
Author(s):  
Dovydas Blazevicius ◽  
Daiva Tavgeniene ◽  
Simona Sutkuviene ◽  
Ernestas Zaleckas ◽  
Ming-Ruei Jiang ◽  
...  

Pyridinyl-carbazole fragments containing low molar mass compounds as host derivatives H1 and H2 were synthesized, investigated, and used for the preparation of electro-phosphorescent organic light-emitting devices (PhOLEDs). The materials demonstrated high stability against thermal decomposition with the decomposition temperatures of 361–386 °C and were suitable for the preparation of thin amorphous and homogeneous layers with very high values of glass transition temperatures of 127–139 °C. It was determined that triplet energy values of the derivatives are, correspondingly, 2.82 eV for the derivative H1 and 2.81 eV for the host H2. The new derivatives were tested as hosts of emitting layers in blue, as well as in green phosphorescent OLEDs. The blue device with 15 wt.% of the iridium(III)[bis(4,6-difluorophenyl)-pyridinato-N,C2′]picolinate (FIrpic) emitter doping ratio in host material H2 exhibited the best overall characteristics with a power efficiency of 24.9 lm/W, a current efficiency of 23.9 cd/A, and high value of 10.3% of external quantum efficiency at 100 cd/m2. The most efficient green PhOLED with 10 wt% of Ir(ppy)3 {tris(2-phenylpyridine)iridium(III)} in the H2 host showed a power efficiency of 34.1 lm/W, current efficiency of 33.9 cd/A, and a high value of 9.4% for external quantum efficiency at a high brightness of 1000 cd/m2, which is required for lighting applications. These characteristics were obtained in non-optimized PhOLEDs under an ordinary laboratory atmosphere and could be improved in the optimization process. The results demonstrate that some of the new host materials are very promising components for the development of efficient phosphorescent devices.


Author(s):  
Sivakumar Vaidyanathan ◽  
Jairam Tagare

Considering the imminent global energy crisis and inefficient energy utilization, energy-efficient organic light-emitting diodes (OLEDs) are considered one of the most competitive candidates for displays and particularly for future energy-saving lighting sources. Full color displays require all primary colors: red, green, and blue (RGB). In recent decades, numerous phenanthroimidazole (PI) RGB-emitting materials have been developed for efficient OLEDs. In organic electronics, considerable interest is shown on PI, due to ease in fluorophore modification. This chapter focuses on the design and synthesis of PI-based materials and their applications in OLEDs. At first, some nondoped blue, green, and yellow fluorescent materials are comprehensively studied. Then attention has been paid for typical blue, green, yellow, orange, and red PhOLEDs of PI-based fluorophores as a host materials are briefly presented. The molecular design concept, general synthetic routes for PI materials, and the applications of fluorophores in fluorescent OLEDs and host materials in PhOLEDs are reviewed.


2015 ◽  
Vol 26 ◽  
pp. 218-224 ◽  
Author(s):  
Ju Sik Kang ◽  
Tae Ryang Hong ◽  
Hyung Jong Kim ◽  
Young Hoon Son ◽  
Jong-Kwan Bin ◽  
...  

Batteries ◽  
2021 ◽  
Vol 7 (3) ◽  
pp. 54
Author(s):  
Munseok S. Chae ◽  
Dedy Setiawan ◽  
Hyojeong J. Kim ◽  
Seung-Tae Hong

Calcium-ion batteries represent a promising alternative to the current lithium-ion batteries. Nevertheless, calcium-ion intercalating materials in nonaqueous electrolytes are scarce, probably due to the difficulties in finding suitable host materials. Considering that research into calcium-ion batteries is in its infancy, discovering and characterizing new host materials would be critical to further development. Here, we demonstrate FeV3O9∙1.2H2O as a high-performance calcium-ion battery cathode material that delivers a reversible discharge capacity of 303 mAh g−1 with a good cycling stability and an average discharge voltage of ~2.6 V (vs. Ca/Ca2+). The material was synthesized via a facile co-precipitation method. Its reversible capacity is the highest among calcium-ion battery materials, and it is the first example of a material with a capacity much larger than that of conventional lithium-ion battery cathode materials. Bulk intercalation of calcium into the host lattice contributed predominantly to the total capacity at a lower rate, but became comparable to that due to surface adsorption at a higher rate. This stimulating discovery will lead to the development of new strategies for obtaining high energy density calcium-ion batteries.


2010 ◽  
Vol 53 (11) ◽  
pp. 2329-2336 ◽  
Author(s):  
RunFeng Chen ◽  
Rui Zhu ◽  
Chao Zheng ◽  
QuLi Fan ◽  
Wei Huang

2013 ◽  
Vol 35 (3) ◽  
pp. 604-608 ◽  
Author(s):  
D. Mazetyte ◽  
G. Krucaite ◽  
J.V. Grazulevicius ◽  
C.I. Chiang ◽  
F.C. Yang ◽  
...  

2004 ◽  
Vol 143 (1) ◽  
pp. 89-96 ◽  
Author(s):  
Koichi Suzuki ◽  
Akihiro Seno ◽  
Hiroshi Tanabe ◽  
Kazunori Ueno

2005 ◽  
Vol 36 (1) ◽  
pp. 1756
Author(s):  
Chin-Ti Chen ◽  
Shi-Jay Yeh ◽  
Min-Fei Wu ◽  
Yun Chi ◽  
Yi-Hwa Song ◽  
...  

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